Covering materials for adhesive hot-melt glues

Patent metadata

Field	Value
Publication number	US-10544295-B2
Application number	US-201715701538-A
Country	US
Kind code	B2
Filing date	Sep 12, 2017
Priority date	Mar 12, 2015
Publication date	Jan 28, 2020
Grant date	Jan 28, 2020

Abstract

The invention relates to a nontacky film-forming polymer composition (cover material), and tacky hot melt adhesives in the form of pellets which are coated with the polymer composition and producible by coextruding the hot melt adhesive and the cover material. The film-forming composition comprises 5 to 40% by weight of at least one Fischer-Tropsch wax having a melting point of >95° C. and 30 to 70% by weight of at least one metallocene-catalyzed polyolefin having a softening point of >95° C. and a melt flow index (MFI) (230° C., 2.16 kg) of ≤1000 and ≥300 g/10 minutes. The invention further relates to suitable uses for such hot melt adhesives, methods for their use, and products containing these adhesives.

First claim

The invention claimed is:

1. A hot melt adhesive in the form of a pellet, comprising:
(1) a core made of a hot melt adhesive having a softening point of 65 to 140° C., containing at least one polyolefin and at least one tackifying resin; and
(2) a film made of a polymer composition, which essentially completely coats the core and is nontacky at a temperature of 20° C. to 60° C.,
wherein the polymer composition, based on its total weight, comprises:

a) 13 to 17% by weight, of at least one Fischer-Tropsch wax having a melting point of >95° C.;
b) 55 to 65% by weight, of a first metallocene-catalyzed polypropylene homopolymer, having a softening point → of more than 95° C. to 100° C., a melt flow index (MFI) (230° C., 2.16 kg) of ≤1000 g/10 minutes and ≥300 g/10 minutes and a number average molecular weight of 70,000 to less than 100,000 g/mol;
c) 22 to 27% by weight, of a second metallocene-catalyzed polypropylene homopolymer, having a softening point → of more than 85° C. to 90° C., a melt flow index (MFI) (230° C., 2.16 kg) of → more than 1000 g/10 minutes to 2000 g/10 minutes and a number average molecular weight of less than 50,000 g/mol; and
d) 0.5 to 2% by weight, of an antioxidant agent,
wherein the melting point of the polymer composition is ≤130° C.

2. The hot melt adhesive according to claim 1 , characterized in that the pellets
(1) each have a weight of less than 15 g; and/or
(2) have a diameter of less than 25 mm in any dimension; and/or
(3) have a cylindrical, spherical, or pillow-like shape; and/or
(4) are produced by coextrusion of the core and the film made of the polymer composition.

3. The hot melt adhesive according to claim 1 , characterized in that
a) the film made of the polymer composition has a thickness of 2 to 200 μm; and/or
b) the hot melt adhesive contains the shell material in a quantity of less than 12% by weight, based on the total weight of the hot melt adhesive.

4. The hot melt adhesive according to claim 1 , characterized in that the at least one tackifying resin consists of a completely or partially hydrogenated hydrocarbon resin, a natural resin based on a colophony resin, a tall resin, or a pentaerythrol or a glycerol ester thereof.

5. The hot melt adhesive according to claim 1 , characterized in that
a) the pellets are nontacky at a temperature in the range of 20 to 60° C.; and/or
b) the pellets form a homogeneous mixture in the molten state.

6. The hot melt adhesive in the form of pellets according to claim 1 , which is a contact adhesive.

Assignees

• Henkel Ag & Co Kgaa

Inventors

• Heemann Marcus
• Kostyra Sebastian
• Puerkner Eckhard
• Petry Gerald
• Davis Riju

Classifications

• C09J9/00

  Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks (C09J7/00 takes precedence) · CPC title

• C08L91/06

  Waxes · CPC title

• C08L23/12 Primary

  Polypropene · CPC title

• C08L23/0807

  with unsaturated hydrocarbons only containing four or more carbon atoms · CPC title

• B29C48/04

  Particle-shaped (making granules B29B9/00) · CPC title