Binder for injection moulding compositions

Patent metadata

Field	Value
Publication number	US-10544294-B2
Application number	US-201816030132-A
Country	US
Kind code	B2
Filing date	Jul 9, 2018
Priority date	May 28, 2013
Publication date	Jan 28, 2020
Grant date	Jan 28, 2020

Abstract

A binder for an injection moulding composition includes: from 35 to 54% by volume of a polymeric base, from 40 to 55% by volume of a mixture of waxes, and approximately 10% by volume of a surfactant, wherein the polymeric base contains copolymers of ethylene and methacrylic or acrylic acid, or copolymers of ethylene and vinyl acetate, or copolymers of ethylene including maleic anhydride or a mixture of these copolymers, as well as polyethylene, polypropylene and acrylic resin.

First claim

The invention claimed is:

1. A binder for injection moulding composition including:
from 35 to 54% by volume of a polymeric base,
from 40 to 55% by volume of a mixture of waxes or a mixture of wax and palm oil,
and approximately 10% by volume of a surfactant,
wherein the polymeric base contains an ethylene and methacrylic or acrylic acid copolymer, or an ethylene copolymers comprising a maleic anhydride, or a mixture of these copolymers, in addition to polyethylene, polypropylene and an acrylic resin, the respective quantities of the binder components being such that added together, they do not exceed 100%.

2. The binder according to claim 1 , including 2 to 7% by volume of one of said copolymers or their mixtures, around 25% by volume of polyethylene, 2 to 15% by volume of polypropylene and 6 to 15% by volume of acrylic resin.

3. A binder for injection moulding composition including:
from 35 to 54% by volume of a polymeric base,
from 40 to 55% by volume of a mixture of waxes or a wax and palm oil mixture,
and approximately 10% by volume of a surfactant,
wherein the polymeric base contains 2 to 7% by volume of an ethylene vinyl acetate copolymer, approximately 25% by volume of polyethylene, from 2 to 15% by volume of polypropylene and 6 to 15% by volume of acrylic resin, the respective quantities of the binder components being such that added together, they do not exceed 100%.

4. The binder according to claim 1 , wherein the ethylene and methacrylic or acrylic acid copolymer contains 3 to 10% by weight of a methacrylic or acrylic comonomer, the copolymer of ethylene and vinyl acetate contains 7 to 18% by weight of vinyl acetate comonomer, and the copolymer of ethylene and anhydride is a random copolymer of ethylene and maleic anhydride with a melting point of 100 to 110° C. or a copolymer of HD polyethylene and a modified anhydride with a melting point of 130 to 134° C.

5. The binder according to claim 1 , wherein the acrylic resin has a molecular weight of between 50000 and 220000 and an inherent viscosity of between 0.21 and 0.83 and is chosen from the group including copolymers of isobutyl methacrylate, methyl methacrylate, ethyl methacrylate and N-butyl methacrylate, and copolymers of isobutyl methacrylate and N-butyl methacrylate and of methyl methacrylate, N-butyle methacrylate or a mixture of these polymers and/or copolymers.

6. The binder according to claim 1 , wherein the wax mixture includes a Carnauba wax and a paraffin wax or the wax mixture includes a Carnauba wax and a palm oil.

7. The binder according to claim 1 , wherein the surfactant is an N,N′-ethylene bis(stearamide) or a mixture of stearic and palmitic acids (stearin), or a mixture of these elements.

8. The binder according to claim 1 , wherein that the surfactant and the acrylic resins are soluble in isopropyl alcohol and/or terebenthine essence.

9. An injection moulding composition (feedstock) for a manufacture of shaped metallic or ceramic parts including 76 to 96% by weight of an inorganic powder and 4-24% by weight of a binder according to claim 1 .

10. The injection moulding composition according to claim 9 , wherein the inorganic powder is selected from the group including an oxide, nitride, carbide, metal powder or a mixture thereof.

11. The injection moulding composition according to claim 9 , wherein said inorganic powder is chosen from the group including an alumina powder, a zirconium oxide powder, a chromium carbide powder, a titanium carbide powder or a tungsten carbide powder, a tungsten metal or silicon nitride powder, a stainless steel powder, a titanium metal powder or a mixture of said powders.

12. The injection moulding composition according to claim 10 , which contains in weight percentage:
76 to 88% of alumina, and 12 to 24% of binder,
76 to 88% of alumina and 0.1 to 0.6% of magnesium oxide and 12 to 24% of binder,
58 to 86.5% of zirconium oxide and 3.9 to 4.6% of yttrium oxide and 0.18 to 18.5% of alumina and 9 to 22% of binder,
61.5 to 84% of zirconium oxide and 3.9 to 4.6% of yttrium oxide and 0.2 to 9% of alumina and 2 to 5.5% of inorganic pigments from a list including iron oxide, cobalt oxide, chromium oxide, titanium oxide, manganese oxide, zinc oxide or a mixture of said oxides and 9 to 22% of binder,
88 to 91% of chromium or titanium carbide, and 9 to 12% of binder,
93 to 96% of tungsten carbide or tungsten metal and 4 to 7% of binder, or
78 to 85% of silicon nitride, and 15 to 22% of binder.

13. The binder according to claim 3 , wherein the copolymer of ethylene and vinyl acetate contains 7 to 18% by weight of vinyl acetate comonomer.

14. The binder according to claim 3 , wherein the acrylic resin has a molecular weight of between 50000 and 220000 and an inherent viscosity of between 0.21 and 0.83 and is chosen from the group including copolymers of isobutyl methacrylate, methyl methacrylate, ethyl methacrylate and N-butyl methacrylate, and copolymers of isobutyl methacrylate and N-butyl methacrylate and of methyl methacrylate, N-butyle methacrylate or a mixture of these polymers and/or copolymers.

15. The binder according to claim 3 , wherein the wax mixture includes a Carnauba wax and a paraffin wax or the wax mixture includes a Carnauba wax and a palm oil.

16. The binder according to claim 3 , wherein the surfactant is an N,N′-ethylene bis(stearamide) or a mixture of stearic and palmitic acids (stearin), or a mixture of these elements.

17. The binder according to claim 3 , wherein the surfactant and the acrylic resins are soluble in isopropyl alcohol and/or terebenthine essence.

18. An injection moulding composition (feedstock) for a manufacture of shaped metallic or ceramic parts including 76 to 96% by weight of an inorganic powder and 4-24% by weight of the binder according to claim 3 .

19. The injection moulding composition according to claim 18 , wherein the inorganic powder is selected from the group including an oxide, nitride, carbide, metal powder or a mixture thereof.

20. The injection moulding composition according to claim 19 , which contains in weight percentage:
76 to 88% of alumina, and 12 to 24% of binder,
76 to 88% of alumina and 0.1 to 0.6% of magnesium oxide and 12 to 24% of binder,
58 to 86.5% of zirconium oxide and 3.9 to 4.6% of yttrium oxide and 0.18 to 18.5% of alumina and 9 to 22% of binder,
61.5 to 84% of zirconium oxide and 3.9 to 4.6% of yttrium oxide and 0.2 to 9% of alumina and 2 to 5.5% of inorganic pigments from a list including iron oxide, cobalt oxide, chromium oxide, titanium oxide, manganese oxide, zinc oxide or a mixture of said oxides and 9 to 22% of binder,
88 to 91% of chromium or titanium carbide, and 9 to 12% of binder,
93 to 96% of tungsten carbide or tungsten metal and 4 to 7% of binder, or
78 to 85% of silicon nitride, and 15 to 22% of binder.

Assignees

• Comadur Sa

Inventors

• Cartier Damien

Classifications

• C04B2235/9661

  Colour · CPC title

• C04B2235/3284

  Zinc oxides, zincates, cadmium oxides, cadmiates, mercury oxides, mercurates or oxide forming salts thereof · CPC title

• C04B2235/3275

  Cobalt oxides, cobaltates or cobaltites or oxide forming salts thereof, e.g. bismuth cobaltate, zinc cobaltite · CPC title

• C04B2235/3272

  Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite · CPC title

• C04B2235/3262

  Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO · CPC title