Poly(butylene terephthalate) method and associated composition and article

Patent metadata

Field	Value
Publication number	US-10544258-B2
Application number	US-201615755783-A
Country	US
Kind code	B2
Filing date	Jul 14, 2016
Priority date	Aug 28, 2015
Publication date	Jan 28, 2020
Grant date	Jan 28, 2020

Abstract

A method for reducing outgassing of a polyester composed of repeat units derived from 1,4-butanediol is melt blending the polyester with 0.2 to 2 weight percent water, based on the weight of the polyester. In addition to water, the polyester can also be blended with 0.01 to 0.5 weight percent of a quencher. The method results in formation of a polyester composition which exhibits reduced outgassing, and is suitable for molding into articles, for example an automotive headlight reflector or bezel.

First claim

The invention claimed is:

1. A method for reducing outgassing of a polyester having repeat units derived from 1,4-butanediol, comprising melt blending a polyester mixture comprising the polyester and 0.2 to 2 weight percent water, based on the weight of the polyester.

2. The method of claim 1 , wherein the polyester mixture further comprises 0.01 to 0.5 weight percent, based on the weight of the polyester, of a quencher.

3. The method of claim 2 , wherein the quencher is a phosphorous compound of structure:

or salt thereof;
wherein Q and R are each independently a direct bond or O;
wherein R 1 and R 2 are independently selected from H, —OH, and substituted or unsubstituted C 1-20 alkyl, C 6-20 aryl, and poly(oxy C 2-4 alkylene);
wherein a substituent, when present, is independently 1 or 2 in number on any of R 1 and R 2 , and are independently selected from —OH, halogen, —COOH, —COOR 3 (wherein R 3 is C 1-4 alkyl) and —NH 2 ;
wherein R 1 and R 2 are optionally linked together by a C 2-20 hydrocarbylene bridge; and
wherein q is 0 or 1.

4. The method of claim 1 , wherein the polyester mixture excludes quenchers, wherein the quenchers are selected from the group consisting of phosphorous compounds, boric acid, aliphatic or aromatic carboxylic acids, carboxylic acid anhydrides, polyols, epoxies, or a combination thereof.

5. The method of claim 3 , wherein the polyester mixture excludes quenchers selected from the group consisting of boric acid, aliphatic or aromatic carboxylic acids, carboxylic acid anhydrides, polyols, epoxies, or a combination thereof.

6. The method of claim 1 , wherein the polyester is selected from a poly(butylene terephthalate), a copolyetherester comprising a poly(butylene terephthalate) block and a polyalkylene oxide block, and a combination thereof.

7. The method of claim 1 , wherein the polyester comprises a poly(butylene terephthalate) having an intrinsic viscosity of 0.6 to 1.5 deciliter per gram measured at 30° C. in 60:40 weight/weight phenol/tetrachloroethane as determined in accordance with ASTM D2857-95 (2007).

8. The method of claim 1 , wherein the polyester mixture further comprises 0.1 to 10 weight percent, based on the weight of the polyester, of an additive selected from the group consisting of flame retardants, fillers, colorants, stabilizers, mold release agents, lubricants, nucleating agents, and a combination thereof.

9. The method of claim 1 , wherein the polyester mixture comprises poly(butylene terephthalate) having an intrinsic viscosity of 0.6 to 1.5 deciliter per gram measured at 30° C. in 60:40 weight/weight phenol/tetrachloroethane; and 0.25 to 1.5 weight percent water as determined in accordance with ASTM D2857-95 (2007).

10. The method of claim 9 , wherein the polyester mixture further comprises 0.05 to 0.2 weight percent, based on the weight of the polyester, of a quencher.

11. A polyester composition made by a method comprising melt blending of a polyester mixture comprising a polyester having repeat units derived from 1,4-butanediol and 0.2 to 2 weight percent water, based on the weight of the polyester.

12. The polyester composition of claim 11 , wherein the polyester mixture further comprises 0.01 to 0.5 weight percent, based on the weight of the polyester, of a quencher.

13. The polyester composition of claim 11 , wherein the polyester mixture comprises poly(butylene terephthalate) having an intrinsic viscosity of 0.6 to 1.5 deciliter per gram measured at 30° C. in 60:40 weight/weight phenol/tetrachloroethane; and 0.25 to 1.5 weight percent water as determined in accordance with ASTM D2857-95 (2007).

14. The polyester composition of claim 13 , further comprising 0.01 to 0.5 weight percent of a quencher selected from a compound of structure:

or salt thereof;
wherein Q and R are each independently a direct bond or O;
wherein R 1 and R 2 are independently selected from H, —OH, and substituted or unsubstituted C 1-20 alkyl, C 6-20 aryl, and poly(oxy C 2-4 alkylene);
wherein a substituent, when present, is independently 1 or 2 in number on any of R 1 and R 2 , and are independently selected from —OH, halogen, —COOH, —COOR 3 (wherein R 3 is C 1-4 alkyl) and —NH 2 ;
wherein R 1 and R 2 are optionally linked together by a C 2-20 hydrocarbylene bridge; and
wherein q is 0 or 1.

15. Article comprising the polyester composition of claim 11 , wherein the article is an automotive headlight reflector or bezel.

16. The method of claim 1 , wherein the polyester exhibits a total headspace carbon weight that is at least 10% less than the headspace carbon weight exhibited by a polyester composition made by the same method, except the water content of the polyester mixture is less than 0.1 weight percent, based on the weight of the polyester, when measured after heat aging at 160° C. for 20 hours.

17. The polyester composition of claim 11 , wherein the polyester composition exhibits a total headspace carbon weight that is at least 10% less than the headspace carbon weight exhibited by a polyester composition made by the same method, except the water content of the polyester mixture is less than 0.1 weight percent, based on the weight of the polyester, when measured after heat aging at 160° C. for 20 hours.

Assignees

• Sabic Global Technologies Bv

Inventors

• Onda Kayoko

Classifications

• F21V7/22

  characterised by materials, surface treatments or coatings, e.g. dichroic reflectors · CPC title

• C08K5/04

  Oxygen-containing compounds {(C08K5/0091 takes precedence)} · CPC title

• C08J2367/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds; (C08J2367/06 takes precedence) · CPC title

• C08J3/203

  Solid polymers with solid and/or liquid additives · CPC title

• C08K5/09

  Carboxylic acids; Metal salts thereof; Anhydrides thereof · CPC title