Organosilica materials and uses thereof

Patent metadata

Field	Value
Publication number	US-10544239-B2
Application number	US-201514966015-A
Country	US
Kind code	B2
Filing date	Dec 11, 2015
Priority date	Dec 12, 2014
Publication date	Jan 28, 2020
Grant date	Jan 28, 2020

Abstract

Organosilica materials, which are a polymer of at least one independent monomer of Formula [Z 1 OZ 2 OSiCH 2 ] 3 (I), wherein each Z 1 and Z 2 independently represent a hydrogen atom, a C 1 -C 4 alkyl group or a bond to a silicon atom of another monomer and at least one other trivalent metal oxide monomer are provided herein. Methods of preparing and processes of using the organosilica materials, e.g., for catalysis etc., are also provided herein.

First claim

What is claimed is:

1. An organosilica material, which is a polymer of at least one trivalent metal oxide monomer and at least one independent monomer of Formula [Z 1 OZ 2 OSiCH 2 ] 3 (I), wherein Z 1 represents a hydrogen atom, a C 1 -C 4 alkyl group, a bond to a silicon atom of another monomer, or a combination thereof, and Z 2 represents a hydrogen atom, a C 1 -C 4 alkyl group, a bond to a silicon atom of another monomer, or a combination thereof, wherein the organosilica material has an X-ray diffraction pattern with one peak between 1 and 3 degrees 2θ and no peaks in the range of from 3 to 20 degrees 2θ.

2. The organosilica material of claim 1 , wherein Z 1 represents a hydrogen atom, a C 1 -C 2 alkyl group, a bond to a silicon atom of another monomer, or a combination thereof, and Z 2 represents a hydrogen atom, a C1-C2 alkyl group, a bond to a silicon atom of another monomer, or a combination thereof.

3. The organosilica material of claim 1 , wherein Z 1 represents a hydrogen atom, ethyl, a bond to a silicon atom of another monomer, or a combination thereof, and Z 2 represents a hydrogen atom, ethyl, a bond to a silicon atom of another monomer, or a combination thereof.

4. The organosilica material of claim 1 , wherein the at least one trivalent metal oxide monomer is
(i) an independent unit of formula M 1 (OZ 3 ) 3 (II), wherein M 1 represents a Group 13 metal and Z 3 represents a hydrogen atom, a C 1 -C 6 alkyl, a bond to a silicon atom of another monomer, or a combination thereof; or
(ii) an independent unit of formula (Z 4 O) 2 M 2 -O—Si(OZ 5 ) 3 (III), wherein M 2 represents a Group 13 metal and Z 4 represents a hydrogen atom, a C 1 -C 6 alkyl group, a bond to a silicon atom of another monomer, or a combination thereof, and Z 5 represents a hydrogen atom, a C 1 -C 6 alkyl group, a bond to a silicon atom of another monomer, or a combination thereof.

5. The organosilica material of claim 4 , wherein at least one unit of formula (II) is present, wherein M 1 is Al or B and Z 3 represents a hydrogen atom, a C 1 -C 4 alkyl group, a bond to a silicon atom or another monomer, or a combination thereof.

6. The organosilica material of claim 4 , wherein at least one unit of formula (III) is present, wherein M 2 is Al or B; and Z 4 represents a hydrogen atom, a C 1 -C 4 alkyl group, a bond to a silicon atom of another monomer, or a combination thereof.

7. The organosilica material of claim 4 , wherein the at least one other trivalent metal oxide monomer is the independent unit of formula M 1 (OZ 3 ) 3 (II), wherein M 1 is a Group 13 metal and Z 3 represents a combination of a hydrogen atom and a bond to a silicon atom of another monomer.

8. The organosilica material of claim 4 , wherein the at least one other trivalent metal oxide monomer is an independent unit of formula M 1 (OZ 3 ) 3 (II), wherein M 1 is Al and Z 3 represents a combination of a hydrogen atom and a bond to a silicon atom of another monomer.

9. The organosilica material of claim 1 further comprising a monomer selected from the group consisting of:
(i) an independent unit of formula [Z 6 OZ 7 SiCH 2 ] 3 (IV), wherein Z 6 represents a hydrogen atom, a C 1 -C 4 alkyl group, a bond to a silicon atom of another monomer, or a combination thereof, and Z 7 represents a hydroxyl group, a C 1 -C 6 alkyl group, an oxygen atom bonded to a silicon atom of another monomer, or a combination thereof;
(ii) an independent unit of formula Z 8 OZ 9 Z 10 Z 11 Si (V), wherein Z 8 represents a hydrogen atom or a C 1 -C 4 alkyl group, a bond to a silicon atom of another monomer, or a combination thereof; Z 9 is selected from the group consisting of a hydroxyl group, a C 1 -C 4 alkyl group, a C 1 -C 4 alkoxy group, a nitrogen-containing C 1 -C 10 alkyl group, a nitrogen-containing heteroaralkyl group, a nitrogen-containing optionally substituted heterocycloalkyl group, an oxygen atom bonded to a silicon atom of another monomer, or a combination thereof; Z 10 is selected from the group consisting of a hydroxyl group, a C 1 -C 4 alkyl group, a C 1 -C 4 alkoxy group, a nitrogen-containing C 1 -C 10 alkyl group, a nitrogen-containing heteroaralkyl group, a nitrogen-containing optionally substituted heterocycloalkyl group, an oxygen atom bonded to a silicon atom of another monomer, or a combination thereof; and Z 11 is selected from the group consisting of a hydroxyl group, a C 1 -C 4 alkyl group, a C 1 -C 4 alkoxy group, a nitrogen-containing C 1 -C 10 alkyl group, a nitrogen-containing heteroaralkyl group, a nitrogen-containing optionally substituted heterocycloalkyl group, an oxygen atom bonded to a silicon atom of another monomer, or a combination thereof; and
(iii) an independent unit of formula Z 12 Z 13 Z 14 Si—R—SiZ 12 Z 13 Z 14 (VI), wherein Z 12 represents a hydroxyl group, a C 1 -C 4 alkoxy group, an oxygen atom bonded to a silicon atom of another comonomer, or a combination thereof, Z 13 represents a hydroxyl group, a C 1 -C 4 alkoxy group, a C 1 -C 4 alkyl group, an oxygen bonded to a silicon atom of another monomer, or a combination thereof; Z14 represents a hydroxyl group, a C 1 -C 4 alkoxy group, a C 1 -C 4 alkyl group, an oxygen bonded to a silicon atom of another monomer, or a combination thereof; and R is selected from the group consisting of a C 1 -C 8 alkylene group, a C 2 -C 8 alkenylene group, a C 2 -C 8 alkynylene group, a nitrogen-containing C 2 -C 10 alkylene group, an optionally substituted C 6 -C 20 aralkyl and an optionally substituted C 4 -C 20 heterocycloalkyl group; and
(iv) a combination thereof.

10. The organosilica material of claim 1 , wherein the organosilica has an average pore diameter between about 1.5 nm and about 20.0 nm.

11. The organosilica material of claim 1 , wherein the organosilica material has a total surface area of about 200 m 2 /g to about 2500 m 2 /g.

12. The organosilica material of claim 1 , wherein the organosilica material has a pore volume about 0.1 cm 3 /g to about 5.0 cm 3 /g.

13. The organosilica material of claim 1 , further comprising at least one catalytic metal incorporated within the pores of the material.

14. The organosilica material of claim 13 , wherein the catalytic metal is selected from the group consisting of a Group 6 element, a Group 8 element, a Group 9 element, a Group 10 element and a combination thereof.

15. The organosilica material of claim 14 , wherein the catalytic metal is Group 10 element.

16. The organosilica material of claim 14 , wherein the catalytic metal is the Group 10 element of palladium.

17. The organosilica material of claim 1 made using no added structure directing agent or porogen.

18. The organosilica material of claim 1 , wherein Z 1 represents a combination of a hydrogen atom and a bond to a silicon atom of another monomer and Z 2 represents a combination of a hydrogen atom and a bond to a silicon atom of another monomer.

19. The organosilica material of claim 1 , further comprising an independent unit of formula Z 8 OZ 9 Z 10 Z 11 Si (V), wherein Z 8 represents a combination of a hydrogen atom and a bond to a silicon atom of another monomer, Z 9 represents a combination of a hydroxyl group and a bond to an oxygen atom bonded to a silicon atom of another monomer, Z 10 represents a combination of a hydroxyl group and a bond to an oxygen atom bonded to a silicon atom of another monomer, and Z 11 represents a combination of a hydroxyl group and a bond to an oxygen atom bonded to a silicon atom of another monomer.

Assignees

• Exxonmobil Res & Eng Co
• Exxonmobile Res And Engineering Company

Inventors

• Li Quanchang
• Calabro David Charles
• Afeworki Mobae Amin
• Weston Simon Christopher
• Mertens Matcheld Maria Wilfried
• Beutel Tilman Wolfram
• Lai Wenyih Frank
• Podsiadlo Paul
• Beeckman Jean Willem Lodewijk

Classifications

• C10N2070/00

  Specific manufacturing methods for lubricant compositions · CPC title

• B01J20/06

  comprising oxides or hydroxides of metals not provided for in group B01J20/04 · CPC title

• C08F4/65927

  two cyclopentadienyl rings being mutually bridged · CPC title

• B01J20/3204

  Inorganic carriers, supports or substrates · CPC title

• B01J37/036

  to form a gel or a cogel · CPC title