Tire comprising a layer of circumferential reinforcing elements

Patent metadata

Field	Value
Publication number	US-10543718-B2
Application number	US-201515319328-A
Country	US
Kind code	B2
Filing date	May 27, 2015
Priority date	Jun 26, 2014
Publication date	Jan 28, 2020
Grant date	Jan 28, 2020

Abstract

Tire comprising a crown reinforcement formed of at least two working crown layers each formed of reinforcing elements inserted between two skim layers of rubber compound. First layer S of polymer compound is in contact with a working crown layer and the carcass reinforcement. The crown reinforcement comprises a layer of circumferential reinforcing elements. The elastic modulus under tension at 10% elongation of a skim layer of a working crown layer is less than 8.5 MPa, the maximum value of tan(δ) of the skim layer of a working crown layer is <0.100. First layer S comprises a filled elastomer blend having a macro dispersion coefficient Z≥65 and a maximum tan(δ) value <0.100 and its complex dynamic shear modulus G*, measured at 10% and 60° C. on the return cycle is >1.35 MPa.

First claim

The invention claimed is:

1. Tire with a radial carcass reinforcement comprising a crown reinforcement formed of at least two working crown layers each formed of reinforcing elements inserted between two skim layers of rubber compound, which reinforcing elements are crossed from one layer to the other making with the circumferential direction angles comprised between 10° and 45°, a first layer of polymer compound being in contact with at least one working crown layer and in contact with the carcass reinforcement, said first layer of polymer compound extending axially as far as at least the axial end of the tread, said tread radially capping the crown reinforcement and being connected to two beads by two sidewalls, the crown reinforcement comprising at least one layer of circumferential reinforcing elements, wherein the elastic modulus under tension at 10% elongation of at least one skim layer of at least one working crown layer is less than 8.5 MPa, wherein the maximum value of tan(δ), denoted tan(δ) max , of said at least one skim layer of at least one working crown layer is less than 0.100, wherein said first layer of polymer compound is made up of a filled elastomeric compound having a macro dispersion coefficient Z greater than or equal to 65 and a maximum tan (δ) value, denoted tan(δ)max, less than 0.100 and wherein the complex dynamic shear modulus, measured at 10% and 60° C. on the return cycle, of said first layer of polymer compound is greater than 1.35 MPa and less than 2 Mpa.

2. The tire according to claim 1 , wherein the elastomer compound of the first layer of polymer compound comprises, by way of reinforcing filler, at least carbon black used at a content comprised between 10 and 50 phr, and wherein the carbon black has a BET specific surface area greater than 90 m 2 /g.

3. The tire according to claim 1 , wherein the elastomer compound of the first layer of polymer compound comprises a blend of carbon black, of BET specific surface area greater than 90 m 2 /g, and of a white filler, wherein the reinforcing filler is used at a content comprised between 10 and 60 phr, and wherein the ratio of carbon black to white filler is greater than 2.7.

4. The tire according to claim 1 , wherein said at least one skim layer of at least one working crown layer is an elastomer compound based on natural rubber or based on synthetic polyisoprene with a predominance of cis-1,4 chains and possibly at least one other diene elastomer, natural rubber or synthetic polyisoprene in the case of a blend being present at a content that predominates over the content of the other diene elastomer or elastomers used and of a reinforcing filler made up of:
a) either carbon black of BET specific surface area greater than 60 m 2 /g,
i. used at a content of between 20 and 40 phr when the oil absorption number (COAN) of the carbon black is greater than 85,
ii. used at a content of between 20 and 60 phr when the oil absorption number (COAN) of the carbon black is less than 85,

b) or carbon black with BET specific surface area less than 60 m 2 /g whatever its oil absorption number, used at a content of between 20 and 80 phr,
c) or a white filler of the silica and/or alumina type comprising SiOH and/or AlOH functional groups at the surface, selected from the group formed of precipitated or pyrogenated silicas, aluminas or aluminosilicates or alternatively still carbon blacks modified during or after the synthesis with BET specific surface area of between 30 and 260 m 2 /g used at a content of between 20 and 80 phr,
d) or a blend of carbon black described at (a) and/or of carbon black described at (b) and/or a white filler described at (c), in which blend the overall filler content is between 20 and 80 phr.

5. The tire according to claim 1 , the tire comprising a second layer of polymer compound axially in contact with the first layer of polymer compound radially between the carcass reinforcement and the radially innermost layer of reinforcing elements of the crown reinforcement, wherein said second layer of polymer compound is made up of a filled elastomer compound having a macro dispersion coefficient greater than or equal to 65 and a maximum tan(δ) value, denoted tan(δ)max, less than 0.100 and wherein the complex dynamic shear modulus, measured at 10% and 60° C. on the return cycle, of said second layer of polymer compound is greater than 1.35 MPa.

6. The tire according to claim 5 , wherein the complex shear modulus, measured at 10% and 60° C. on the return cycle, of the second layer of polymer compound is less than 2 MPa.

7. The tire according to claim 5 , wherein the elastomer compound of the second layer of polymer compound comprises, by way of reinforcing filler, at least carbon black used at a content comprised between 10 and 50 phr, and wherein the carbon black has a BET specific surface area greater than 90 m 2 /g.

8. The tire according to claim 5 , wherein the elastomer compound of the second layer of polymer compound comprises a blend of carbon black, of BET specific surface area greater than 90 m 2 /g, and of a white filler, wherein the reinforcing filler is used at a content comprised between 10 and 60 phr, and wherein the ratio of carbon black to white filler is greater than 2.7.

9. The tire according to claim 5 , wherein the elastomer compound of the second layer of polymer compound comprises, by way of reinforcing filler, at least carbon black used at a content comprised between 10 and 50 phr, and wherein the carbon black has a BET specific surface area greater than or equal to 120 m 2 /g.

10. The tire according to claim 5 , wherein the elastomer compound of the second layer of polymer compound comprises a blend of carbon black, of BET specific surface area greater than or equal to 120 m 2 /g, and of a white filler, wherein the reinforcing filler is used at a content comprised between 10 and 60 phr, and wherein the ratio of carbon black to white filler is greater than 2.7.

11. The tire according to claim 1 , wherein said reinforcing elements of at least one working crown layer are cords with saturated layers, at least one internal layer being sheathed by a layer made of a polymer composition such as a non-crosslinkable, crosslinkable or crosslinked rubber composition.

12. The tire according to claim 1 , wherein the layer of circumferential reinforcing elements is placed radially between two working crown layers.

13. The tire according to claim 1 , wherein the reinforcing elements of at least one layer of circumferential reinforcing elements are metallic reinforcing elements having a secant modulus at 0.7% elongation comprised between 10 and 120 GPa and a maximum tangent modulus less than 150 GPa.

14. The tire according to claim 1 , wherein the reinforcing elements of the working crown layers are inextensible.

15. The tire according to claim 1 , wherein the crown reinforcement is supplemented radially on the outside by at least one additional ply, referred to as a protective ply, of reinforcing elements referred to as elastic elements, which are oriented with respect to the circumferential direction at an angle of between 10° and 45° in the same direction as the angle formed by the inextensible elements of the working ply radially adjacent to it.

16. The tire according to claim 1 , wherein the crown reinforcement further comprises a triangulation layer formed of metallic reinforcing elements making angles greater than 60° with the circumferential direction.

17. The tire according to claim 1 , wherein the elastomer compound of the first layer of polymer compound comprises, by way of reinforcing filler, a

Assignees

• Michelin & Cie

Inventors

• Rehab Hichem
• Salgues Nathalie
• Besson Jacques

Classifications

• B60C9/1835 Primary

  Rubber strips or cushions at the belt edges · CPC title

• B60C2001/0075

  Compositions of belt cushioning layers · CPC title

• B60C2009/2064

  Modulus; Hardness; Loss modulus or "tangens delta" · CPC title

• B60C9/28

  characterised by the belt or breaker dimensions or curvature relative to carcass (B60C9/30 takes precedence) · CPC title

• B60C2009/2019

  comprising cords at an angle of 30 to 60 degrees to the circumferential direction · CPC title