Method for fabricating metal nanoparticles

Patent metadata

Field	Value
Publication number	US-10543536-B2
Application number	US-201414892920-A
Country	US
Kind code	B2
Filing date	Jun 3, 2014
Priority date	Jun 7, 2013
Publication date	Jan 28, 2020
Grant date	Jan 28, 2020

Abstract

The present specification relates to a method for fabricating metal nanoparticles.

First claim

The invention claimed is:

1. A method for fabricating metal nanoparticles, the method comprising:
forming a solution comprising: a solvent; a first metal salt which provides a first metal ion or an atomic group ion comprising the first metal ion in the solvent; a second metal salt which provides a second metal ion or an atomic group ion comprising the second metal ion in the solvent; a first surfactant which forms micelles in the solvent; and a second surfactant which forms micelles together with the first surfactant in the solvent; and
forming metal nanoparticles comprising a hollow core by adding a reducing agent to the solution,
wherein the first metal ion or the atomic group ion comprising the first metal ion and the second metal ion or the atomic group ion comprising the second metal ion form a shell portion of the metal nanoparticle.

2. The method of claim 1 , wherein the first metal ion or the atomic group ion comprising the first metal ion has a charge opposite to a charge at an outer end portion of the first surfactant, and
the second metal ion or the atomic group ion comprising the second metal ion has a charge which is the same as the charge at the outer end portion of the first surfactant.

3. The method of claim 1 , wherein the shell portion of the metal nanoparticle is formed in a micelle region which the first surfactant forms, and a cavity of the metal nanoparticle is formed in a micelle region which the second surfactant forms.

4. The method of claim 1 , wherein a cavity is formed in one or two or more regions of the shell portion by adjusting a concentration, a chain length, a size of an outer end portion, or a type of charge of the second surfactant.

5. The method of claim 4 , wherein the adjusting of the chain length of the second surfactant is adjusting the chain length of the second surfactant to be different from a chain length of the first surfactant.

6. The method of claim 4 , wherein the adjusting of the type of charge of the second surfactant is adjusting the charge of the second surfactant to be different from a charge of the first surfactant.

7. The method of claim 1 , wherein a concentration of the first surfactant is 1 time to 5 times a critical micelle concentration to the solvent.

8. The method of claim 1 , wherein a molar concentration of the second surfactant is 0.01 time to 1 time a molar concentration of the first surfactant.

9. The method of claim 1 , wherein the chain length of the second surfactant is 0.5 time to 2 times a chain length of the first surfactant.

10. The method of claim 1 , wherein both the first surfactant and the second surfactant are an anionic or cationic surfactant.

11. The method of claim 1 , wherein one of the first surfactant and the second surfactant is an anionic surfactant, and the other is a cationic surfactant.

12. The method of claim 1 , wherein the first surfactant is an anionic surfactant or cationic surfactant, and the second surfactant is a non-ionic or zwitterionic surfactant.

13. The method of claim 1 , wherein the number of carbon atoms of the chain of the first surfactant is 15 or less.

14. The method of claim 1 , wherein the first surfactant is an anionic surfactant, and comprises NH 4 + , K + , Na + , or Li + as a counter ion.

15. The method of claim 1 , wherein the first surfactant is a cationic surfactant, and comprises I − , Br − , or Cl − as a counter ion.

16. The method of claim 1 , wherein the first metal salt and the second metal salt are each independently a nitrate, a halide, a hydroxide or a sulfate of the metal.

17. The method of claim 1 , wherein the solvent comprises water.

18. The method of claim 1 , wherein the preparation method is carried out at room temperature.

19. The method of claim 1 , wherein a molar ratio of the first metal salt to the second metal salt is 5:1 to 10:1.

20. The method of claim 1 , wherein the metal nanoparticle has a particle diameter of 1 nm to 30 nm.

21. The method of claim 1 , wherein the first metal ion and the second metal ion are each independently an ion of a metal selected from the group consisting of platinum (Pt); ruthenium (Ru); rhodium (Rh); molybdenum (Mo); osmium (Os); iridium (Ir); rhenium (Re); palladium (Pd); vanadium (V); tungsten (W); cobalt (Co); iron (Fe); selenium (Se); nickel (Ni); bismuth (Bi); tin (Sn); chromium (Cr); titanium (Ti); gold (Au); cerium (Ce); silver (Ag); and copper (Cu).

22. The method of claim 1 , wherein the shell portion comprises: a first shell comprising the first metal ion; and a second shell comprising the second metal ion.

23. The method of claim 1 , wherein the metal nanoparticle has a spherical shape or a shape comprising one or more bowl-type particles.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Kwanghyun
• Hwang Gyo Hyun
• Kim Sang Hoon
• Cho Jun Yeon

Classifications

• B22F1/054

  Nanosized particles · CPC title

• B22F1/08

  Metallic powder characterised by particles having an amorphous microstructure · CPC title

• B22F1/065

  Spherical particles · CPC title

• B22F1/105

  containing inorganic lubricating or binding agents, e.g. metal salts · CPC title

• B22F1/0655

  Hollow particles · CPC title