Flow reactor

Patent metadata

Field	Value
Publication number	US-10543474-B2
Application number	US-201816222261-A
Country	US
Kind code	B2
Filing date	Dec 17, 2018
Priority date	Jun 24, 2016
Publication date	Jan 28, 2020
Grant date	Jan 28, 2020

Abstract

A flow reactor having two or more raw material feeding units, a mixing unit to mix raw materials fed from the raw material feeding units, and a reactor unit in which a mixed solution prepared in the mixing unit flows, wherein at least a part of an inner wall of the reactor unit is formed of a fluororesin containing a conductive filler.

First claim

The invention claimed is:

1. A flow reactor, comprising:
a plurality of raw material feeding units;
a mixing unit configured to mix raw materials fed from the raw material feeding units; and
a reactor unit in which a mixed solution prepared in the mixing unit flows,
wherein at least a part of an inner wall of the reactor unit is formed of a fluororesin comprising a conductive filler, and
wherein the reactor unit comprises a flow channel having an equivalent diameter of from 1.0 mm to 20 mm.

2. The flow reactor according to claim 1 , wherein the reactor unit comprises a single-layer structure comprising the fluororesin.

3. The flow reactor according to claim 1 , wherein a quenching agent capable of quenching the mixed solution is in contact with an outer wall surface of the reactor unit.

4. The flow reactor according to claim 3 , wherein the quenching agent comprises at least one selected from the group consisting of water, hydrochloric acid, sulfuric acid, phosphoric acid, acetic acid, citric acid, sodium hydroxide, potassium carbonate, sodium hydrogen carbonate, hydrogen peroxide, sodium hypochlorite, sodium chlorite, sodium thiosulfate, and sodium sulfite.

5. The flow reactor according to claim 1 , wherein the fluororesin is a homopolymer or a copolymer produced from a fluorine atom-containing monomer.

6. The flow reactor according to claim 1 , wherein the conductive filler is at least one selected from the group consisting of a carbon-based filler, a metal-based filler, a metal oxide-based filler, and a metal alloy-based filler.

7. The flow reactor according to claim 6 ,
wherein
the carbon-based filler comprises at least one selected from the group consisting of carbon black, ketjen black, acetylene black, carbon nanotubes, natural graphite, artificial graphite, and vapor-grown carbon fibers,
the metal-based filler comprises at least one selected from the group consisting of gold, silver, nickel, copper, zinc, aluminum, and stainless steel,
the metal oxide-based filler comprises at least one selected from the group consisting of aluminum-doped zinc oxide, antimony-doped tin oxide (IV), and tin-doped indium oxide (III), and
the metal alloy-based filler comprises at least one selected from the group consisting of AgCu, AgSn, CuZn, CuNiZn, and CuNi.

8. The flow reactor according to claim 1 , wherein the fluororesin has a volume resistivity, measured under the conditions of 50% RH and 23° C. in accordance with JIS K 6911, of 10 6 Ω·m or less.

9. The flow reactor according to claim 1 , further comprising a temperature control unit.

10. The flow reactor according to claim 1 , wherein the reactor unit has a tube shape.

11. The flow reactor according to claim 1 , wherein the fluororesin comprises at least one selected from the group consisting of polytetrafluoroethylene (PTFE), polychlorotrifluoroethylene (PCTFE), perfluoroethylene propene copolymer (FEP), perfluoroalkoxyalkane (PFA), ethylene-chlorotrifluoroethylene copolymer (ECTFE) and ethylene-tetrafluoroethylene copolymer (ETFE).

12. The flow reactor according to claim 1 , wherein the fluororesin comprises at least one selected from the group consisting of polytetrafluoroethylene (PTFE), perfluoroethylene propene copolymer (FEP), and perfluoroalkoxyalkane (PFA).

13. The flow reactor according to claim 1 , wherein the conductive filler has a sphere shape having an average particle size of at least 5 nm, or a needle shape having an aspect ratio of at least 5.

14. The flow reactor according to claim 1 , wherein a content of the conductive filler in the fluororesin is at least 5 parts by weight based on 100% by weight of the fluororesin.

15. The flow reactor according to claim 1 , wherein a content of the conductive filler in the fluororesin is from 7 to 30 parts by weight based on 100% by weight of the fluororesin.

16. The flow reactor according to claim 1 , wherein an outer wall surface of the reactor unit is covered with a second resin.

17. The flow reactor according to claim 1 , wherein an equivalent diameter of a flow channel of the reactor unit changes in the middle of the reactor unit.

18. A method for mixing raw materials comprising a liquid having a conductivity of less than 50 pS/m, the method comprising:
mixing raw materials in the flow reactor of claim 1 .

Assignees

• Kaneka Corp

Inventors

• Ozasa Shiori
• Toyoda Tomoyuki
• Ohishi Takahiro

Classifications

• C08L27/12

  containing fluorine atoms · CPC title

• C08K3/04

  Carbon · CPC title

• B01J2219/00833

  Plastic · CPC title

• C08K3/08

  Metals · CPC title

• B01J19/02 Primary

  Apparatus characterised by being constructed of material selected for its chemically-resistant properties · CPC title