Maintenance liquid for active energy ray-curable inkjet ink

Patent metadata

Field	Value
Publication number	US-10538723-B2
Application number	US-201414784380-A
Country	US
Kind code	B2
Filing date	Apr 16, 2014
Priority date	Apr 17, 2013
Publication date	Jan 21, 2020
Grant date	Jan 21, 2020

Abstract

Provided is a non-aqueous maintenance liquid for an active energy ray-curable inkjet ink which can be used as a cleaning liquid for removing the inkjet ink and as a preserving liquid to fill the head when the printer is not in operation. The non-aqueous maintenance liquid for an active energy ray-curable inkjet ink of the present invention comprises a main liquid component, a pigment dispersant resin, and a surface control agent, wherein the main liquid component is an organic solvent and/or an active energy ray-curable compound, and the amount of the surface control agent is 0.01 to 10% by weight in 100% by weight of the maintenance liquid.

First claim

The invention claimed is:

1. A maintenance liquid comprising
an active energy ray-curable compound in an amount of 70% by weight or more in 100% by weight of the maintenance liquid, wherein the active energy ray-curable compound is dipropylene glycol diacrylate,
a poly ether modified dimethylsiloxane silicone-based surface control agent in an amount of 0.2 to 10% by weight in 100% by weight of the maintenance liquid, and
a polyethyleneimine-based pigment dispersant resin
in an amount of 0.02 to 5% by weight in 100% by weight of the maintenance liquid, and
wherein said maintenance liquid does not comprise a photopolymerization initiator, a coloring agent, a dye, or a pigment.

2. The maintenance liquid according to claim 1 , wherein the amount of the surface control agent is 1 to 10% by weight in 100% by weight of the maintenance liquid.

3. The maintenance liquid according to claim 1 , wherein the amount of the polyethyleneimine-based pigment dispersant resin is 0.05 to 3% by weight in 100% by weight of the maintenance liquid.

4. The maintenance liquid according to claim 1 , further comprising 0.05 to 5% by weight of a polymerization inhibitor in 100% by weight of the maintenance liquid.

5. The maintenance liquid according to claim 1 , wherein the maintenance liquid consists of the active energy ray-curable compound, the pigment dispersant resin, the surface control agent, and optionally a polymerization inhibitor.

6. A maintenance liquid comprising:
an active energy ray-curable compound in an amount of 70% by weight or more in 100% by weight of the maintenance liquid, wherein the active energy ray-curable compound is dipropylene glycol diacrylate,
a polyether modified dimethylsiloxane silicone-based surface control agent in an amount of 0.2 to 10% by weight in 100% by weight of the maintenance liquid, and
a pigment dispersant resin
selected from the group consisting of a basic dispersant resin having a basic functional group, a basic dispersant resin having a urethane skeleton, and a polyalkyleneimine-based pigment dispersant resin in an amount of 0.02 to 5% by weight in 100% by weight of the maintenance liquid, and
wherein said maintenance liquid does not comprise a photopolymerization initiator.

7. A method for removing inkjet ink from a surface comprising;
contacting the surface with an active energy ray-curable inkjet ink, the active energy ray-curable inkjet ink comprising: (a) a polymerizable monomer; (b) a photopolymerization initiator; (c) a coloring agent, a dye, or a pigment; and (d) a pigment dispersant resin;
and then
contacting the surface with the maintenance liquid according to claim 6 to dilute the active energy ray-curable inkjet ink,
wherein the pigment dispersant resin comprised in the maintenance liquid and the pigment dispersant resin comprised in the inkjet ink are identical compounds.

8. The method of claim 7 , wherein the surface is an inkjet head, ink passage, or nozzle.

9. The method of claim 7 , wherein the active energy ray-curable compound comprised in the maintenance liquid and the polymerizable monomer comprised in the inkjet ink are identical compounds.

10. The method of claim 7 , wherein the pigment dispersant resin comprised in the maintenance liquid and in the inkjet ink is a polyethyleneimine-based pigment dispersant resin.

11. The method of claim 7 , wherein the active energy ray-curable inkjet ink comprises dipropylene glycol diacrylate and 2-(2-vinyloxyethoxy)ethyl acrylate.

12. The method of claim 11 , wherein the active energy ray-curable inkjet ink comprises at least 62.5% by combined weight of dipropylene glycol diacrylate and 2-(2-vinyloxyethoxy)ethyl acrylate in 100% by weight of the active energy ray-curable inkjet ink.

13. A method for cleaning, maintaining, or preserving an inkjet printer comprising contacting a component of said printer, which contacts an active energy ray-curable inkjet ink comprising: (a) a polymerizable monomer; (b) a photopolymerization initiator; and (c) a coloring agent, a dye, or a pigment, and (d) a pigment dispersant resin, with the maintenance liquid according to claim 6 to dilute the active energy ray-curable inkjet ink,
wherein the pigment dispersant resin comprised in the maintenance liquid and the pigment dispersant resin comprised in the inkjet ink are identical compounds.

14. The method of claim 13 , wherein the active energy ray-curable compound comprised in the maintenance liquid and the polymerizable monomer comprised in the inkjet ink are identical compounds.

15. The method of claim 13 , wherein the pigment dispersant resin comprised in the maintenance liquid and in the inkjet ink is a polyethyleneimine-based pigment dispersant resin.

16. The method of claim 13 , wherein the active energy ray-curable inkjet ink comprises dipropylene glycol diacrylate and 2-(2-vinyloxyethoxy)ethyl acrylate.

17. The method of claim 16 , wherein the active energy ray-curable inkjet ink comprises at least 62.5% by combined weight of dipropylene glycol diacrylate and 2-(2-vinyloxyethoxy)ethyl acrylate in 100% by weight of the active energy ray-curable inkjet ink.

Assignees

• Toyo Ink Sc Holdings Co Ltd
• Toyo Ink Co Ltd

Inventors

• Kameyama Yuji
• Konda Yohei
• Jonai Kazuhiro

Classifications

• C11D7/5004

  Organic solvents · CPC title

• C11D3/3765

  in liquid compositions · CPC title

• C11D3/373

  containing silicones · CPC title

• C09D11/322

  Pigment inks · CPC title

• C09D11/36

  based on non-aqueous solvents · CPC title