Polyolefin compounds for cable coatings

Patent metadata

Field	Value
Publication number	US-10538682-B2
Application number	US-201916280594-A
Country	US
Kind code	B2
Filing date	Feb 20, 2019
Priority date	Feb 25, 2015
Publication date	Jan 21, 2020
Grant date	Jan 21, 2020

Abstract

Polymeric compositions comprising a blend of high-density polyethylene (“HDPE”) with ethylene vinyl acetate (“EVA”), and optionally with a carbon black and/or one or more other additives, where the polymeric compositions have certain melt-index and vinyl-acetate-content ranges to improve melt strength and processability. Such polymeric compositions can be employed in manufacturing coated conductors, such as fiber optic cables.

First claim

The invention claimed is:

1. A coated conductor comprising:
(a) a conductor; and
(b) a polymeric composition surrounding at least a portion of said conductor,
wherein said polymeric composition comprises a high-density polyethylene and an ethylene vinyl acetate,
wherein said polymeric composition has a vinyl acetate content in the range of from 1.5 to 8 weight percent, based on the combined weight of said high-density polyethylene and said ethylene vinyl acetate,
wherein said polymeric composition has a melt index (I 2 ) in the range of from 1.3 to 1.9 g/10 minutes or less.

2. The coated conductor of claim 1 , wherein said polymeric composition has a vinyl acetate content in the range of from 1.9 to 6.0 weight percent, based on the combined weight of said high-density polyethylene and said ethylene vinyl acetate.

3. The coated conductor of claim 1 , wherein said polymeric composition has a melt index (I 2 ) in the range of from 1.4 to 1.88 g/10 minutes.

4. The coated conductor of claim 1 , wherein said polymeric composition has a high-shear viscosity (100 sec −1 ) that is at least 1% lower than the high-shear viscosity of an identical comparative polymeric composition, except that said comparative polymeric composition does not contain ethylene vinyl acetate, wherein said polymeric composition has a low-shear viscosity (0.1 sec −1 ) that is at least 1% higher than the low-shear viscosity of an identical comparative polymeric composition, except that said comparative polymeric composition does not contain ethylene vinyl acetate.

5. The coated conductor of claim 1 , wherein said ethylene vinyl acetate has a vinyl acetate content in the range of from 10 to 40 weight percent based on the total weight of said ethylene vinyl acetate, wherein said ethylene vinyl acetate has a melt index (I 2 ) in the range of from 0.7 to 6 g/10 minutes.

6. The coated conductor of claim 1 , wherein said high-density polyethylene is present in said polymeric composition in an amount ranging from 70 to 95 weight percent based on the combined weight of said high-density polyethylene and said ethylene vinyl acetate, wherein said ethylene vinyl acetate is present in an amount ranging from 5 to 30 weight percent based on the combined weight of said high-density polyethylene and said ethylene vinyl acetate.

7. The coated conductor of claim 1 , wherein said high-density polyethylene is a bimodal high-density polyethylene.

8. The coated conductor of claim 1 , wherein said polymeric composition further comprises one or more additives selected from the group consisting of carbon blacks, carrier resins, flame retardants, processing aids, nucleating agents, foaming agents, crosslinking agents, fillers, pigments or colorants, coupling agents, antioxidants, ultraviolet stabilizers, tackifiers, scorch inhibitors, antistatic agents, slip agents, plasticizers, lubricants, viscosity control agents, anti-blocking agents, surfactants, extender oils, acid scavengers, metal deactivators, and vulcanizing agents.

9. The coated conductor of claim 1 , wherein said polymeric composition is present in the form of a jacket surrounding said conductor, wherein said jacket has a thin-wall construction having a thickness in the range of from 10 to 30 mils.

10. The coated conductor of claim 1 , wherein said coated conductor is a fiber optic cable.

11. A coated conductor comprising:
(a) a conductor; and
(b) a polymeric composition at least partially surrounding said conductor, said polymeric composition consisting of:
(i) a high-density polyethylene,
(ii) an ethylene vinyl acetate, and
(iii) optionally one or more additives selected from the group consisting of carbon blacks, carrier resins, flame retardants, processing aids, nucleating agents, foaming agents, crosslinking agents, fillers, pigments or colorants, coupling agents, antioxidants, ultraviolet stabilizers, tackifiers, scorch inhibitors, antistatic agents, slip agents, plasticizers, lubricants, viscosity control agents, anti-blocking agents, surfactants, extender oils, acid scavengers, metal deactivators, and vulcanizing agents,

wherein said polymeric composition has a vinyl acetate content in the range of from 1.5 to 8 weight percent, based on the combined weight of said high-density polyethylene and said ethylene vinyl acetate,
wherein said polymeric composition has a melt index (I 2 ) in the range of from 1.3 to 1.9 g/10 minutes or less.

12. The coated conductor of claim 11 , wherein said polymeric composition has a vinyl acetate content in the range of from 1.9 to 6.0 weight percent, based on the combined weight of said high-density polyethylene and said ethylene vinyl acetate, wherein said polymeric composition has a melt index (I 2 ) in the range of from 1.4 to 1.88 g/10 minutes.

13. The coated conductor of claim 11 , wherein said polymeric composition has a high-shear viscosity (100 sec −1 ) that is at least 1% lower than the high-shear viscosity of an identical comparative polymeric composition, except that said comparative polymeric composition does not contain ethylene vinyl acetate, wherein said polymeric composition has a low-shear viscosity (0.1 sec −1 ) that is at least 1% higher than the low-shear viscosity of an identical comparative polymeric composition, except that said comparative polymeric composition does not contain ethylene vinyl acetate.

14. The coated conductor of claim 11 , wherein said ethylene vinyl acetate has a vinyl acetate content in the range of from 10 to 40 weight percent based on the total weight of said ethylene vinyl acetate, wherein said ethylene vinyl acetate has a melt index (I 2 ) in the range of from 0.7 to 6 g/10 minutes.

15. The coated conductor of claim 11 , wherein said high-density polyethylene is present in said polymeric composition in an amount ranging from 70 to 90 weight percent based on the combined weight of said high-density polyethylene and said ethylene vinyl acetate, wherein said ethylene vinyl acetate is present in an amount ranging from 10 to 30 weight percent based on the combined weight of said high-density polyethylene and said ethylene vinyl acetate, wherein said high-density polyethylene is a bimodal high-density polyethylene.

Assignees

• Union Carbide Chem Plastic
• Dow Global Technologies Llc

Inventors

• Lee Day-Chyuan

Classifications

• H01B3/441 Primary

  from alkenes · CPC title

• G02B6/02395

  Glass optical fibre with a protective coating, e.g. two layer polymer coating deposited directly on a silica cladding surface during fibre manufacture (G02B6/02052, G02B6/02057, G02B6/024, G02B6/032, G02B6/105, G02B6/14 take precedence; coating on fibre gratings G02B6/02104; multilayer core or cladding G02B6/036; reinforcing splice joints G02B6/2558; optical cables, i.e. comprising protective structures external to the protective coating such as a jacket or plural coated optical fibres G02B6/44; coating of glass to obtain optical fibres C03C25/104) · CPC title

• H01B3/446

  from vinylacetals · CPC title

• C08L23/06 Primary

  Polyethylene · CPC title

• C08L2203/202

  use in electrical wires or wirecoating · CPC title