Toughened poly(aryl ether sulfone)/poly(aryl ether ketone) blends

Patent metadata

Field	Value
Publication number	US-10538667-B2
Application number	US-201615757942-A
Country	US
Kind code	B2
Filing date	Sep 9, 2016
Priority date	Sep 9, 2015
Publication date	Jan 21, 2020
Grant date	Jan 21, 2020

Abstract

Toughened poly(aryl ether sulfone)/poly(aryl ether ketone) blends. The present invention relates to polymer compositions including at least one poly(aryl ether sulfone) (PASS) polymer, at least one poly(aryletherketone) (PAEK) polymer, and at least one impact modifier (IM). The polymer composition may optionally include at least one aromatic polycarbonate (PC) and/or titanium dioxide (TiO2), The polymer composition is particularly suitable for use in mobile electronic devices.

First claim

The invention claimed is:

1. A polymer composition comprising:
at least one poly(aryl ether sulfone) (PAES) polymer,
at least one poly(aryl ether ketone) (PAEK) polymer, and
at least one impact modifier (IM).

2. The polymer composition of claim 1 , wherein the poly(aryl ether sulfone) (PAES) polymer comprises repeat units represented by formula (A):
—Ar 1 -(T′-Ar 2 ) n —O—Ar 3 —SO 2 —[Ar 4 -(T-Ar 2 ) n —SO 2 ] m —Ar 5 —O—  (A)

wherein:
Ar 1 , Ar 2 , Ar 3 , Ar 4 , and Ar 5 , equal to or different from each other and at each occurrence, are independently an aromatic mono- or polynuclear group;
T and T′, equal to or different from each other and at each occurrence, are independently a bond or a divalent group optionally including one or more than one heteroatom; and
n and m, equal to or different from each other, are independently zero or an integer from 1 to 5.

3. The polymer composition of claim 2 , wherein Ar 1 , Ar 2 , Ar 3 , Ar 4 and Ar 5 are equal or different from each other and are represented by a formula selected from following group of formulae:

wherein each R is independently selected from the group consisting of hydrogen, halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium and where j, k and l, equal or different from each other, are independently 0, 1, 2, 3 or 4.

4. The polymer composition of claim 1 , wherein the poly(aryl ether sulfone) (PAES) polymer comprises repeat units selected from the group of formulae:

wherein,
each of R′, equal to or different from each other, is selected from the group consisting of halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium;
j′ is zero or is an integer from 0 to 4; and
T and T′, equal to or different from each other, is selected from the group consisting of a bond, —CH 2 —; —O—; —SO 2 —; —S—; —C(O)—; —C(CH 3 ) 2 —;—C(CF 3 ) 2 —;
—C(═CCl 2 )—; —C(CH 3 )(CH 2 CH 2 COOH)—; —N═N—; —R a C═CR b —, where each R a and R b , independently of one another, is a hydrogen or a C 1 -C 12 -alkyl, C 1 -C 12 -alkoxy, or C 6 -C 18 -aryl group; —(CH 2 ) n — and —(CF 2 ) n — with n being an integer from 1 to 6; an aliphatic divalent group, linear or branched, of up to 6 carbon atoms; and combinations thereof.

5. The polymer composition of claim 1 , wherein the poly(aryl ether sulfone) (PAES) polymer comprises repeat units selected from the group consisting of those of formulae:

6. The polymer composition of claim 1 , wherein more than 50 mol. % of repeat units of the poly(aryl ether sulfone) (PAES) polymer are recurring units of formula:

7. The polymer composition of claim 1 , wherein more than 50% by moles of recurring units of the at least one poly(aryl ether ketone) (PAEK) polymer are recurring units (R PAEK ) selected from group consisting of formulae (J-A) to (J-P):

wherein:
each of R′, equal to or different from each other, is selected from the group consisting of a halogen, an alkyl, an alkenyl, an alkynyl, an aryl, an ether, a thioether, a carboxylic acid, an ester, an amide, an imide, an alkali or alkaline earth metal sulfonate, an alkyl sulfonate, an alkali or alkaline earth metal phosphonate, an alkyl phosphonate, an amine, and a quaternary ammonium, and
j is zero or an integer ranging from 1 to 4.

8. The polymer composition of claim 7 , wherein the recurring units (R PAEK ) are selected from the group consisting of those of formulae (J′-A) to (J′-P):

9. The polymer composition of claim 1 , wherein the at least one poly(aryl ether ketone) (PAEK) polymer is polyetheretherketone (PEEK).

10. The polymer composition of claim 1 , wherein the at least one impact modifier (IM) comprises an acrylic elastomeric copolymer.

11. The polymer composition of claim 1 , wherein the impact modifier (IM) is selected from the following copolymers:
(i) elastomeric copolymers having glass transition temperature below 25° C., when measured according to according to ASTM D 3418, and comprising recurring units derived from one or more than one acrylic monomer selected from the group consisting of alkyl(meth)acrylates and acrylonitrile; and
(ii) core-shell elastomers, including a central core and a shell at least partially surrounding the core, said core and said shell having different monomeric composition, and at least one of the core and/or shell being of elastomeric nature with a glass transition temperature below 25° C., when measured according to according to ASTM D 3418, and at least one of them comprising recurring units derived from one or more than one acrylic monomer selected from the group consisting of alkyl(meth)acrylates and acrylonitrile.

12. The polymer composition of claim 1 , further comprising a polycarbonate polymer comprising recurring units (R pc ) represented by the following formula (IX):

wherein Ar 1 is represented by the following formula (XII)

and
wherein:
each R t (n) is independently selected from a halogen, an alkyl, a perhalogenated alkyl, an alkenyl, a perhalogenated alkynyl, an aryl, a perhalogenated aryl, an ether, a thioether, an ester, an amide, an imide, an alkali or alkaline earth metal sulfonate, an alkyl sulfonate, an alkali or alkaline earth metal phosphonate, an alkyl phosphonate, an amine, an quaternary ammonium, or any combination thereof;
n″ is an integer ranging from 1 to 20; and
t is an integer ranging from 0 to 2.

13. The polymer composition of claim 1 , wherein the at least one poly(aryl ether sulfone) (PAES) polymer is present in an amount ranging from about 40 wt. % to about 99 wt. % of the combined weight of the PAES and the PAEK.

14. A mobile electronic device comprising at least one structural part comprising the polymer composition of claim 1 .

15. The polymer composition of claim 1 , wherein said polymer composition exhibits a combination of a notched-Izod impact not less than about 200 J/m, a Sunscreen Test critical strain greater than or equal to 2.0%, and a CIE color L* of at least 91.0.

Assignees

• Solvay Specialty Polymers Usa

Inventors

• Bushelman Corinne
• Desio Glenn P
• Sattich William E

Classifications

• C08L2201/08

  Stabilised against heat, light or radiation or oxydation · CPC title

• C08G65/4012

  Other compound (II) containing a ketone group, e.g. X-Ar-C(=O)-Ar-X for polyetherketones · CPC title

• C08L2203/20

  use in electrical or conductive gadgets · CPC title

• C08L81/06 Primary

  Polysulfones; Polyethersulfones · CPC title

• C08G75/23

  Polyethersulfones · CPC title