Use of C4 absorber overhead for stripping aldehydes

Patent metadata

Field	Value
Publication number	US-10538466-B2
Application number	US-201815968909-A
Country	US
Kind code	B2
Filing date	May 2, 2018
Priority date	Nov 6, 2015
Publication date	Jan 21, 2020
Grant date	Jan 21, 2020

Abstract

A process is presented for the production of butadienes. The process includes the separation of oxygenates from the product stream from an oxidative dehydrogenation reactor. The process includes quenching the product stream and solvent and oxygenates from the product stream. The oxygenates are stripped from the solvent with an inert gas to reduce the energy consumption of the process, and the solvent is recycled and reused in the process.

First claim

What is claimed is:

1. A process for the removal of oxygenates from a butadiene reactor effluent stream comprising:
passing the butadiene reactor effluent stream to a quench tower;
cooling and quenching the butadiene reactor effluent stream to generate an overhead stream comprising C4 hydrocarbons, and a bottoms stream comprising solvent and oxygenates;
passing the bottoms stream to an oxygenate stripper; and
passing an inert gas to the oxygenate stripper, and generating a stripper overhead stream comprising oxygenates and the inert gas, and a stripper bottoms stream comprising solvent, wherein the inert gas is not steam.

2. The process of claim 1 wherein the solvent is water.

3. The process of claim 1 further comprising passing the butadiene reactor effluent stream to a heat exchanger to generate steam, and a cooled butadiene reactor effluent, before passing the butadiene reactor effluent to the quench tower.

4. The process of claim 1 further comprising passing the overhead stream to a compression unit to generate a compressed C4 stream.

5. The process of claim 4 further comprising passing the compressed C4 stream to an oxygenate scrubber to generate a scrubbed C4 stream and a scrubber bottoms stream.

6. The process of claim 5 further comprising passing the scrubber bottoms stream to the oxygenate stripper.

7. The process of claim 5 further comprising passing the scrubbed C4 stream to a C4 absorber to generate an absorber overhead stream comprising the inert gas, and an absorber bottoms stream comprising C4 compounds and solvent, wherein the inert gas in the absorber overhead stream is the inert gas passed to the oxygenate stripper.

8. The process of claim 7 further comprising passing the absorber bottoms stream to a degasser to generate a degasser overhead stream and a degasser bottoms stream comprising solvent and C4 compounds.

9. The process of claim 8 further comprising passing the degasser bottoms stream to a C4 stripper to generate a C4 product stream and a C4 stripper bottoms stream comprising solvent.

10. The process of claim 9 further comprising passing the C4 stripper bottoms stream to the C4 absorber.

11. The process of claim 1 further comprising passing a butene stream to an oxidative dehydrogenation reactor, to generate the butadiene reactor effluent stream.

12. The process of claim 11 wherein the oxidative dehydrogenation reactor comprises a two stage reactor system, with the two reactors connected in series and wherein an effluent from the first reactor is passed as feed to the second reactor, and with an oxidizing agent and steam passed to both reactors.

13. A process for the production of butadienes, comprising:
passing a butene stream to a oxidative dehydrogenation reactor;
passing superheated steam and compressed air to the oxidative dehydrogenation reactor, to generate an effluent stream comprising butadienes;
passing the effluent stream, and water through a heat exchanger to generate a cooled effluent stream and a steam stream;
passing the cooled effluent stream to a quench tower to generate a quenched C4 stream and a quench bottoms stream;
passing the quenched C4 stream to a compressor to generate a compressed C4 stream;
passing the compressed C4 stream to an aldehyde scrubber to generate a C4 product stream, and a scrubber bottoms stream;
passing the scrubber bottoms stream to an aldehyde stripper; and
passing an inert gas stream to the aldehyde stripper to generate a stripper overhead stream and a bottoms water stream, wherein the inert gas is not steam.

14. The process of claim 13 wherein the quench bottoms stream is passed along with the scrubber bottoms stream to the aldehyde stripper.

15. The process of claim 13 further comprising passing the steam stream to a steam superheater to generate the superheated steam passed to the oxidative dehydrogenation reactor.

16. The process of claim 14 further comprising passing a portion of the bottoms water stream to the heat exchanger to generate the steam stream.

17. The process of claim 13 further comprising passing the C4 product stream to a C4 absorber to generate a C4 absorber bottoms stream and a C4 absorber overhead stream, comprising the inert gas.

18. The process of claim 17 further comprising passing the C4 absorber overhead stream to the aldehyde stripper.

19. The process of claim 17 further comprising:
passing the C4 absorber bottoms stream to a degasser to generate a degasser overhead stream and a degasser bottoms stream;
passing the degasser bottoms stream to a C4 stripper to generate a C4 overhead
stream and a solvent bottoms stream; and
passing the C4 overhead stream to a C4 splitter.

20. The process of claim 19 further comprising passing the solvent bottoms stream to the C4 absorber.

Assignees

• Uop Llc
• Tpc Group Llc

Inventors

• Senetar John J
• Blommel Jeannie M
• Luebke Charles P
• Sullivan Dana K
• Duff Joseph G
• Horn Jillian M
• Maat Clifford A
• Nutt Michael O

Classifications

• C07C7/11 Primary

  by absorption, i.e. purification or separation of gaseous hydrocarbons with the aid of liquids · CPC title

• C07C7/09

  by fractional condensation · CPC title

• C07C7/005 Primary

  Processes comprising at least two steps in series · CPC title

• B01D19/0015

  in contact columns containing plates, grids or other filling elements · CPC title

• C07C5/48

  with oxygen as an acceptor · CPC title