Optimised energy efficiency hydrothermal carbonization method and device

Patent metadata

Field	Value
Publication number	US-10538447-B2
Application number	US-201615325019-A
Country	US
Kind code	B2
Filing date	Jun 3, 2016
Priority date	Jun 5, 2015
Publication date	Jan 21, 2020
Grant date	Jan 21, 2020

Abstract

A method of continuous hydrothermal carbonization of sludge containing organic matter, involving a stage of hydrothermal reaction carried out in a reactor ( 4 ), includes:
a step of introduction of sludge in which the sludge is introduced into the reactor ( 4 ) by a first inlet ( 11 ), a step of endogenous injection of steam in which steam is injected into the reactor ( 4 ) by a second inlet ( 15 ) distinct from the first inlet ( 11 ), a step of extraction in which at least a portion of the sludge contained in the reactor ( 4 ) is extracted continuously by a sludge outlet ( 16 ), a step of preheating in which the temperature of the sludge is raised prior to its introduction into the reactor ( 4 ) up to a temperature of preheating greater than 70° C. Also disclosed is a device making it possible to carry out such a method.

First claim

The invention claimed is:

1. A method of continuous hydrothermal carbonization of sludge containing organic matter, said sludge having a dryness between 10 and 30%, said method involving a stage of hydrothermal reaction carried out in a reactor ( 4 ), the hydrothermal reaction stage involving the following steps:
a step of introduction of sludge in which the sludge is introduced into the reactor ( 4 ) by a first inlet ( 11 ),
a step of endogenous injection of steam in which steam is injected into the reactor ( 4 ) by a second inlet ( 15 ),
a step of extraction in which at least a portion of the sludge contained in the reactor ( 4 ) is extracted continuously by a sludge outlet ( 16 ),

further comprising a step of preheating in which the temperature of the sludge is raised prior to its introduction into the reactor ( 4 ) up to a temperature of preheating greater than 70° C.,
wherein the second inlet ( 15 ) is distinct from the first inlet ( 11 ),
and wherein the step of preheating includes a step of microwave injection in which microwaves are injected into the sludge prior to its introduction into the reactor ( 4 ).

2. The method as claimed in claim 1 , wherein the step of preheating involves a step of exogenous steam injection in which steam is injected into the sludge prior to its introduction into the reactor ( 4 ), and wherein the method furthermore involves a step of additional heating in which the temperature is raised for the sludge having undergone the step of preheating prior to its introduction into the reactor ( 4 ) by transferring to this sludge the heat contained in the sludge extracted from the reactor ( 4 ).

3. The method as claimed in claim 1 , wherein the step of preheating involves a step of recirculation in which a fraction of the sludge contained in the reactor ( 4 ) is removed and in which this fraction is mixed with the sludge prior to its introduction into the reactor ( 4 ).

4. The method as claimed in claim 1 , further comprising a step of circulation in which a mixture consisting of the sludge contained in the reactor ( 4 ) and the steam injected into the reactor ( 4 ) is placed in circulation within the reactor ( 4 ).

5. The method as claimed in claim 1 , further comprising a step of heating of water in which heat contained in the sludge extracted from the reactor ( 4 ) is transferred to water by means of a heat exchanger ( 6 ), and in which the water so heated is used to produce some or all of the steam used during the step of endogenous steam injection.

6. A device for continuous hydrothermal carbonization of sludge containing organic matter, said sludge having a dryness between 10 and 30%, this device comprising a reactor ( 4 ) having:
a first inlet ( 11 ) designed to introduce the sludge into the reactor ( 4 ),
a second inlet ( 15 ) designed to inject steam directly into the reactor ( 4 ),
a sludge outlet ( 16 ) designed to continuously extract at least a portion of the sludge contained in the reactor ( 4 ) from it,

further comprising a means of preheating ( 2 ) upstream from the first inlet ( 11 ), this means of preheating ( 2 ) being designed to receive the sludge prior to its introduction into the reactor ( 4 ) and to raise the temperature of the sludge which it receives up to a temperature of preheating greater than 70° C., the second inlet ( 15 ) being distinct from the first inlet ( 11 ),
and the means of preheating ( 2 ) being designed to inject microwaves into the sludge which it receives.

7. The device as claimed in claim 6 , wherein the means of preheating ( 2 ) is designed to inject steam into the sludge which it receives, the device further comprising means of additional heating ( 91 , 92 , 93 , 94 ), designed to transfer heat contained in the sludge extracted from the reactor ( 4 ) to the sludge downstream from the means of preheating ( 2 ) and upstream from the reactor ( 4 ), so as to raise the temperature of the sludge downstream from the means of preheating ( 2 ) and upstream from the reactor ( 4 ).

8. The device as claimed in claim 6 , further comprising a recirculation loop (b) designed to remove a fraction of the sludge contained in the reactor ( 4 ) and to mix this fraction with the sludge received by the means of preheating ( 2 ).

9. The device as claimed in claim 6 , further comprising a heat exchanger ( 6 ) and a boiler ( 22 ), this heat exchanger ( 6 ) being designed to transfer heat contained in the sludge extracted from the reactor ( 4 ) to water circulating between this heat exchanger ( 6 ) and the boiler ( 22 ), the boiler ( 22 ) being designed to furnish some or all of the steam injected into the reactor ( 4 ) by the second inlet ( 15 ).

10. The method as claimed in claim 2 , wherein the step of preheating involves a step of recirculation in which a fraction of the sludge contained in the reactor ( 4 ) is removed and in which this fraction is mixed with the sludge prior to its introduction into the reactor ( 4 ).

11. The method as claimed in claim 2 , further comprising a step of circulation in which a mixture consisting of the sludge contained in the reactor ( 4 ) and the steam injected into the reactor ( 4 ) is placed in circulation within the reactor ( 4 ).

12. The method as claimed in claim 3 , further comprising a step of circulation in which a mixture consisting of the sludge contained in the reactor ( 4 ) and the steam injected into the reactor ( 4 ) is placed in circulation within the reactor ( 4 ).

13. The method as claimed in claim 2 , further comprising a step of heating of water in which heat contained in the sludge extracted from the reactor ( 4 ) is transferred to water by means of a heat exchanger ( 6 ), and in which the water so heated is used to produce some or all of the steam used during the step of endogenous steam injection.

14. The method as claimed in claim 3 , further comprising a step of heating of water in which heat contained in the sludge extracted from the reactor ( 4 ) is transferred to water by means of a heat exchanger ( 6 ), and in which the water so heated is used to produce some or all of the steam used during the step of endogenous steam injection.

15. The method as claimed in claim 4 , further comprising a step of heating of water in which heat contained in the sludge extracted from the reactor ( 4 ) is transferred to water by means of a heat exchanger ( 6 ), and in which the water so heated is used to produce some or all of the steam used during the step of endogenous steam injection.

16. The device as claimed in claim 7 , further comprising a recirculation loop (b) designed to remove a fraction of the sludge contained in the reactor ( 4 ) and to mix this fraction with the sludge received by the means of preheating ( 2 ).

17. The device as claimed in claim 7 , further comprising a heat exchanger ( 6 ) and a boiler ( 22 ) , this heat exchanger ( 6 ) being designed to transfer heat contained in the sludge extracted from the reactor ( 4 ) to water circulating between this heat exchanger ( 6 ) and the boiler ( 22 ), the boiler ( 22 ) being designed to furnish some or all of the steam injected into the reactor ( 4 ) by the second inlet ( 15 ).

18. The device as claimed in claim 8 , further comprising a heat exchanger ( 6 ) and a boiler ( 22 ) , this heat exchanger ( 6 ) being designed to transfer heat contained in the sludge extracted from the reactor ( 4 ) to water circulating between this heat exchanger ( 6 ) and the boiler ( 22 ), the boiler ( 22 ) being designed to furnish some or all of the steam injected into the reactor ( 4 ) by the s

Assignees

• Suez Int

Inventors

• Pardo Pierre Emmanuel
• Bourdais Jean-Louis

Classifications

• C10L2290/148

  of steam · CPC title

• C10L2290/10

  Recycling of a stream within the process or apparatus to reuse elsewhere therein · CPC title

• F23G7/001

  for sludges or waste products from water treatment installations (F23G5/008 takes precedence) · CPC title

• F23G5/0276

  using direct heating · CPC title

• C10L2290/36

  Applying radiation such as microwave, IR, UV · CPC title