High performance sealable co-extruded oriented film, methods of manufacture thereof and articles comprising the same

Patent metadata

Field	Value
Publication number	US-10538057-B2
Application number	US-201515119141-A
Country	US
Kind code	B2
Filing date	Feb 19, 2015
Priority date	Feb 19, 2014
Publication date	Jan 21, 2020
Grant date	Jan 21, 2020

Abstract

Disclosed herein is a multilayered film comprising a first layer and a second layer; and a tie layer; where the tie layer comprises a crystalline block composite and where the tie layer is disposed between the first layer and the second layer; the first layer being disposed on a first surface of the tie layer; the second layer being disposed on a second surface of the tie layer; where the second surface is opposedly disposed to the first surface; where the multilayered film is biaxially oriented. Disclosed herein too is a method of manufacturing the aforementioned multilayer film.

First claim

What is claimed is:

1. A multilayer film comprising:
a first layer comprising polyethylene and a second layer comprising polypropylene; where the second layer has a thickness of 10 to 70 μm; and
a tie layer; where the tie layer comprises a crystalline block composite or a block composite;
wherein the crystalline block composite comprises:
a crystalline ethylene based polymer (CEP), a crystalline α-olefin based polymer (CAOP), and a block copolymer comprising a crystalline ethylene block (CEB) and a crystalline α-olefin block (CAOB), wherein the crystalline ethylene block of the block copolymer is the same composition as the crystalline ethylene based polymer in the block composite and the crystalline α-olefin block of the block copolymer is the same composition as the crystalline α-olefin based polymer of the block composite, and wherein a compositional split between the amount of crystalline ethylene based polymer and crystalline α-olefin based polymer is the same as that between the corresponding blocks in the block copolymer; and
wherein the block composite comprises:
(i) a soft ethylene copolymer (EP) having polymerized units in which the comonomer content is greater than 10 mol % and having less than 90 mol % polymerized ethylene,
(ii) a hard or crystalline α-olefin polymer (CAOP), in which the α-olefin monomer is present in an amount of from greater than 90 up to 100 mol %, and
(iii) a diblock block copolymer, having a soft segment and a hard segment, wherein the hard segment of the block copolymer is the same composition as the hard α-olefin polymer in the block composite and the soft segment of the block copolymer is essentially the same composition as the soft ethylene copolymer of the block composite,
and where the tie layer is disposed between the first layer and the second layer; the first layer being disposed on a first surface of the tie layer; the second layer being disposed on a second surface of the tie layer; where the second surface is opposedly disposed to the first surface; where the multilayered film is biaxially oriented.

2. The multilayer film of claim 1 wherein the crystalline block composite in the tie layer comprises a crystalline α-olefin block in an amount of 30 to 70 weight % of the crystalline α-olefin block.

3. The multilayer film of claim 1 wherein the crystalline block composite has a crystalline block composite index of 0.3 to up to 1.0.

4. The multilayer film of claim 1 wherein the ethylene polymer of the block composite in the tie layer comprises at least 80 mol % polymerized ethylene.

5. The multilayer film of claim 1 wherein the crystalline block composite or the block composite has a melt flow rate of from 3 to 30 g/10 min when measured as per ASTM D 1238 at 230° C. and 2.16 kilograms.

6. The multilayer film of claim 1 , where the tie layer further comprises an elastomer; and where the elastomer is a homogeneously branched ethylene-α-olefin copolymer, a polyolefin elastomer, a vinyl aromatic block copolymer, or a combination comprising at least one of the foregoing elastomers.

7. The multilayer film of claim 1 , where the tie layer further comprises polyethylene.

8. The multilayer film of claim 7 , where the polyethylene is selected from the group consisting of ultralow density polyethylene, low density polyethylene, linear low density polyethylene, medium density polyethylene, high density polyethylene, high melt strength high density polyethylene, ultrahigh density polyethylene, or combinations thereof.

9. The multilayer film of claim 1 , where the polyethylene comprises linear low density polyethylene having a density of less than 0.930 grams per cubic centimeter.

10. The multilayer film of claim 1 , where the first layer comprises a propylene-α-olefin interpolymer with a melting point of 90 to 140° C.

11. The multilayer film of claim 8 , where the polypropylene is selected from the groups consisting of random copolymer polypropylene, impact copolymer polypropylene, high impact polypropylene, high melt strength polypropylene, isotactic polypropylene, syndiotactic polypropylene, or a combination comprising at least one of the foregoing polypropylenes.

12. The multilayer film of claim 1 , where the polypropylene in the second layer is a polypropylene homopolymer.

13. The multilayer film of claim 1 , where the film has a total thickness from 10 to 120 μm.

14. The multilayer film of claim 1 , where the biaxial orientation comprises subjecting the multilayered film to a greater extension in the transverse direction than in the machine direction.

15. The multilayer film of claim 14 , where the extension in the transverse direction is at least 50% greater than the extension in the machine direction.

16. An article comprising the multilayer film of claim 1 .

17. A method of manufacturing a multilayer film comprising:
coextruding a multilayer film comprising:
a first layer comprising polyethylene and a second layer comprising polypropylene; where the second layer has a thickness of 10 to 70 μm; and
a tie layer; where the tie layer comprises a crystalline block composite or a block composite;

wherein the crystalline block composite comprises:
a crystalline ethylene based polymer, a crystalline α-olefin based polymer, and a block copolymer comprising a crystalline ethylene block and a crystalline α-olefin block, wherein the crystalline ethylene block of the block copolymer is the same composition as the crystalline ethylene based polymer in the block composite and the crystalline α-olefin block of the block copolymer is the same composition as the crystalline α-olefin based polymer of the block composite, and wherein a compositional split between the amount of crystalline ethylene based polymer and crystalline α-olefin based polymer is the same as that between the corresponding blocks in the block copolymer; and
wherein the block composite comprises:
(i) a soft ethylene copolymer having polymerized units in which the comonomer content is greater than 10 mol % and having less than 90 mol % polymerized ethylene,
(ii) a hard or crystalline α-olefin polymer, in which the α-olefin monomer is present in an amount of from greater than 90 up to 100 mol %, and
(iii) a diblock block copolymer, having a soft segment and a hard segment, wherein the hard segment of the block copolymer is the same composition as the hard α-olefin polymer in the block composite and the soft segment of the block copolymer is essentially the same composition as the soft ethylene copolymer of the block composite, and where the tie layer is disposed between the first layer and the second layer; the first layer being disposed on a first surface of the tie layer; the second layer being disposed on a second surface of the tie layer; where the second surface is opposedly disposed to the first surface;
blowing or casting the multilayered film; and
biaxially orienting the film.

18. The method of claim 17 , further comprising laminating the film in a roll mill.

19. The method of claim 17 , further comprising laminating the film in a compression mold.

Assignees

• Dow Global Technologies Llc
• Rohm & Haas

Inventors

• Su Fengyi
• Pan Jianping
• Yun Xiaobing
• Patel Rajen M
• Hu Yushan
• Chen Yong

Classifications

• B29K2995/0041

  Crystalline · CPC title

• B32B27/08 Primary

  of synthetic resin · CPC title

• B32B2323/04

  Polyethylene · CPC title

• B29C48/0018

  combined with shaping by orienting, stretching or shrinking, e.g. film blowing (B29C48/0017 takes precedence) · CPC title

• B32B2553/00

  Packaging equipment or accessories not otherwise provided for · CPC title