Molten salt composition, electrolyte, and electric storage device, and method for increasing a viscosity of liquid molten salt

Patent metadata

Field	Value
Publication number	US-10535897-B2
Application number	US-201615552591-A
Country	US
Kind code	B2
Filing date	Feb 26, 2016
Priority date	Feb 26, 2015
Publication date	Jan 14, 2020
Grant date	Jan 14, 2020

Abstract

The object of the present invention is to provide the gelatinous, molten salt having a high ion-conductivity and an excellent heat resistance.
The object of the present invention can be solved by the inorganic nanofibers having a functional group which inter-molecularly interacts with the molten salt on the surface thereof, and the molten salt composition comprising molten salt; or the method for increasing a viscosity of liquid molten salt characterized in that the inorganic nanofibers having a functional group which inter-molecularly interacts with the molten salt in the surface thereof is added to the liquid molten salt.

First claim

The invention claimed is:

1. A molten salt composition characterized by comprising an inorganic nanofiber having a functional group capable of molecularly-interacting with molten salt on a surface, and molten salt, wherein the inorganic nanofiber is selected from the group consisting of SiO 2 nanofiber, TiO 2 nanofiber, ZnO nanofiber, Al 2 O 3 nanofiber, ZrO 2 nanofiber and combinations of two or more thereof.

2. The molten salt composition according to claim 1 , wherein the molten salt comprises at least one cation selected from the group consisting of imidazolium cation, pyridinium cation, piperidinium cation, pyrrolidinium cation, phosphonium cation, morpholinium cation, sulfonium cation, and ammonium cation, and at least one anion selected from the group consisting of carboxylate anion, sulfonate anion, halogen anion, hydroxy anion, imide anion, boron anion, cyano anion, phosphorus anion, and nitrate anion.

3. The molten salt composition according to claim 1 , wherein the molten salt is a deep eutectic solvent.

4. The molten salt composition according to claim 1 , wherein the functional group is selected from the group consisting of an amino group, a hydroxyl group, a carboxyl group, a siloxane group, and combinations of two or more thereof.

5. The molten salt composition according to claim 1 , wherein an amount of the inorganic nanofiber is 0.5 to 10.0% by weight.

6. An electrolyte characterized by comprising the molten salt composition according to claim 1 , and a metal ion.

7. The electrolyte according to claim 6 , wherein the metal ion is selected from the group consisting of lithium ion, calcium ion, sodium ion, and magnesium ion.

8. An electric storage device comprising an electrolyte according to claim 6 , a positive electrode containing a positive electrode active material, and a negative electrode containing a negative electrode active material.

9. The electric storage device according to claim 8 , which is a non-aqueous electrolyte secondary battery, an electric double layer capacitor, or a hybrid capacitor.

10. A method for increasing a viscosity of liquid molten salt, characterized in that an inorganic nanofiber having a functional group capable of molecularly-interacting with molten salt, on a surface, is added to the liquid molten salt, wherein the inorganic nanofiber is selected from the group consisting of SiO 2 nanofiber, TiO 2 nanofiber, ZnO nanofiber, Al 2 O 3 nanofiber, ZrO 2 nanofiber and combinations of two or more thereof.

11. The method for increasing a viscosity of liquid molten salt according to claim 10 , wherein the liquid molten salt comprises at least one cation selected from the group consisting of imidazolium cation, pyridinium cation, piperidinium cation, pyrrolidinium cation, phosphonium cation, morpholinium cation, sulfonium cation, and ammonium cation, and at least one anion selected from the group consisting of carboxylate anion, sulfonate anion, halogen anion, hydroxy anion, imide anion, boron anion, cyano anion, phosphorus anion, and nitrate anion.

12. The method for increasing a viscosity of liquid molten salt according to claim 10 , wherein the functional group is selected from the group consisting of an amino group, a hydroxyl group, a carboxyl group, a siloxane group, and combinations of two or more thereof.

13. The method for increasing a viscosity of liquid molten salt according to claim 10 , wherein an additive amount of the inorganic nanofiber is 0.5 to 10.0% by weight.

Assignees

• Aist

Inventors

• Matsumoto Hidetoshi
• Yuki Takahiro
• Tominaga Yoichi
• Matsumoto Hajime
• Kubota Keigo

Classifications

• C01P2006/40

  Electric properties · CPC title

• H01M10/0567

  characterised by the additives · CPC title

• D01F9/08

  of inorganic material (working or processing of metal wire B21F; from softened glass, minerals or slags C03B37/00) · CPC title

• H01G11/62

  characterised by the solute, e.g. salts, anions or cations therein · CPC title

• C01P2004/16

  Nanowires or nanorods, i.e. solid nanofibres with two nearly equal dimensions between 1-100 nanometer · CPC title