Composite electrode active material, lithium battery including the same, and preparation method thereof

Patent metadata

Field	Value
Publication number	US-10535871-B2
Application number	US-201615227869-A
Country	US
Kind code	B2
Filing date	Aug 3, 2016
Priority date	Oct 12, 2015
Publication date	Jan 14, 2020
Grant date	Jan 14, 2020

Abstract

A composite electrode active material includes: a core portion including a silicon-based alloy; and a shell portion disposed on the core portion and including a coating layer, wherein the coating layer includes an amorphous carbon material and a lithium titanium oxide. A lithium battery including the composite electrode active material and a method of manufacturing the composite electrode active material are also provided.

First claim

What is claimed is:

1. A composite negative electrode active material, comprising:
a core portion comprising a silicon-based alloy;
a continuous carbon coating layer disposed on the core portion; and
lithium titanium oxide particles on an outer surface of the carbon coating layer arranged in a dispersed manner.

2. The composite negative electrode active material of claim 1 , wherein the amorphous carbon material comprises soft carbon, hard carbon, coal-based pitch, petroleum-based pitch, mesophase pitch carbide, calcined cokes, and a combination thereof.

3. The composite negative electrode active material of claim 1 , wherein the amount of the amorphous carbon material is in a range of about 1 part by weight to about 30 parts by weight based on 100 parts by weight of the core portion.

4. The composite negative electrode active material of claim 1 , wherein a thickness of the coating layer is in a range of about 5 nm to about 300 nm.

5. The composite negative electrode active material of claim 1 , wherein the lithium titanium oxide is represented by Formula 1:
Li 4−x−y M y Ti 5+x−z M′ z O 12    Formula 1

wherein, in Formula 1,
0≤x≤1, 0≤y≤1, and 0≤z≤1,
M is at least one element selected from lanthanum (La), terbium (Tb), gadolinium (Gd), cerium (Ce), praseodymium (Pr), neodymium (Nd), samarium (Sm), barium (Ba), strontium (Sr), calcium (Ca), magnesium (Mg), and a combination thereof, and
M′ is at least one element selected from vanadium (V), chrome (Cr), niobium (Nb), iron (Fe), nickel (Ni), cobalt (Co), manganese (Mn), tungsten (W), aluminum (Al), gallium (Ga), copper (Cu), molybdenum (Mo), phosphorus (P), or a combination thereof.

6. The composite negative electrode active material of claim 1 , wherein an average particle diameter of the lithium titanium oxide is in a range of about 0.1 nm to about 500 nm.

7. The composite negative electrode active material of claim 1 , wherein the amount of the lithium titanium oxide is in a range of about 0.1 part by weight to about 10 parts by weight based on 100 parts by weight of the core portion.

8. The composite negative electrode active material of claim 1 , wherein the core portion comprises a Si phase and a SiM phase, wherein M is at least one element selected from Ni, Co, arsenic (As), Cr, Cu, Fe, Mg, Mn, and yttrium (Y).

9. The composite negative electrode active material of claim 1 , wherein the core portion comprises an alloy represented by Formula 2:
Si a Fe b    Formula 2

wherein, in Formula 2,
50≤a≤90, 10≤b≤50, and a+b=100.

10. The composite negative electrode active material of claim 1 , wherein the composite electrode active material serves as a negative active material.

11. A lithium battery comprising:
a positive electrode;
a negative electrode comprising the composite negative electrode active material of claim 1 ; and
an electrolyte disposed between the positive electrode and the negative electrode.

12. A lithium battery of claim 11 comprising the composite negative electrode active material wherein the amount of the amorphous carbon material is in a range of about 1 part by weight to about 30 parts by weight based on 100 parts by weight of the core portion.

13. A lithium battery of claim 11 comprising the composite negative electrode active material wherein a thickness of the coating layer is in a range of about 5 nm to about 300 nm.

14. A lithium battery of claim 11 comprising the composite negative electrode active material wherein the lithium titanium oxide is represented by Formula 1:
Li 4−x−y M y Ti 5+x−z M′ z O 12    Formula 1

wherein, in Formula 1,
0≤x≤1, 0≤y≤1, and 0≤z≤1,
M is at least one element selected from lanthanum (La), terbium (Tb), gadolinium (Gd), cerium (Ce), praseodymium (Pr), neodymium (Nd), samarium (Sm), barium (Ba), strontium (Sr), calcium (Ca), magnesium (Mg), and a combination thereof, and
M′ is at least one element selected from vanadium (V), chrome (Cr), niobium (Nb), iron (Fe), nickel (Ni), cobalt (Co), manganese (Mn), tungsten (W), aluminum (Al), gallium (Ga), copper (Cu), molybdenum (Mo), phosphorus (P), or a combination thereof.

15. A lithium battery of claim 11 comprising the composite negative electrode active material wherein the amount of the lithium titanium oxide is in a range of about 0.1 part by weight to about 10 parts by weight based on 100 parts by weight of the core portion.

Assignees

• Samsung Sdi Co Ltd

Inventors

• Shin Changsu
• Lee Sora
• Jeong Changui
• Eom Hyeri

Classifications

• H01M4/043

  involving compressing or compaction · CPC title

• H01M4/386

  Silicon or alloys based on silicon · CPC title

• H01M4/366 Primary

  as layered products · CPC title

• H01M4/0471

  involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis · CPC title

• H01M4/483

  for non-aqueous cells (H01M4/485 takes precedence) · CPC title