Collection, release, and detection of analytes with polymer composite sampling materials

Patent metadata

Field	Value
Publication number	US-10533968-B2
Application number	US-201916256980-A
Country	US
Kind code	B2
Filing date	Jan 24, 2019
Priority date	Apr 21, 2015
Publication date	Jan 14, 2020
Grant date	Jan 14, 2020

Abstract

A unique fiber core sampler composition, related systems, and techniques for designing, making, and using the same are described. The sampler is used to interface with existing field instrumentation, such as Ion Mobility Spectrometer (IMS) equipment. Desired sampler characteristics include its: stiffness/flexibility; thermal mass and conductivity; specific heat; trace substance collection/release dependability, sensitivity and repeatability; thickness; reusability; durability; stability for thermal cleaning; and the like. In one form the sampler has a glass fiber core with a thickness less than 0.3 millimeter that is coated with a polymer including one or more of: polymeric organofluorine, polyimide, polyamide, PolyBenzImidazole (PBI), PolyDiMethylSiloxane (PDMS), sulfonated tetrafluoroethylene (PFSA) and Poly(2,6-diphenyl-p-phenylene Oxide) (PPPO). Multiple polymer coatings with the same or different polymer types may be included, core/substrate surface functionalization utilized, and/or the core/substrate may be at partially filled with thermally conductive particles.

First claim

What is claimed is:

1. A method of making a sampler, comprising:
providing a sampler fiber core comprised of one or more of: glass, metal, metalloid, inorganic oxide, ceramic, and glass-ceramic;
applying nanoparticles of one or more types of inorganic metallic material to the fiber core to at least partially fill the core; and
after the applying of the nanoparticles to the fiber core, preparing the sampler by depositing a polymer on the fiber core and the nanoparticles.

2. The method of claim 1 , in which the preparing of the sampler includes depositing a polymer on the fiber core and the nanoparticles, the polymer being comprised of one or more of: polymeric organofluorine, polyimide, polyimide, PFSA, PBI, PDMS, and PPPO, and the nanoparticles are comprised of one or more of: metal, metal oxide, and carbon.

3. The method of claim 2 , in which the depositing of the polymer includes providing a first polymer layer on the core and a second polymer layer on the first polymer layer, and composition of the first polymer layer being different from the second polymer layer.

4. The method of claim 2 , in which the depositing of the polymer includes providing a first polymer layer on the core and a second polymer layer on the first polymer layer, composition of the first polymer layer and the second polymer layer both include PTFE, and polymer content of the sampler is in the range of about 20% wt through about 40% wt relative to weight of the sampler with the polymer applied thereto.

5. The method of claim 2 , which includes performing a silanization functionalization of at least a portion of the fiber core and the nanoparticles before the depositing of the polymer.

6. The method of claim 1 , in which the preparing of the sampler includes:
applying a liquid dispersion of polymer particles on the core and the nanoparticles to deposit polymer thereon, the polymer being one or more of: perfluorocarbon, perfluoroether, ETFE, ECTFE, THV copolymer, PVdF, FEP, PCTFE, PVF, PTRFE, poly(vinylidenetetrafluoroethylene) copolymer, poly(vinylidene-trifluroethylene) copolymer, PPBI, PDMS, and PPPO;
removing at least a portion of the liquid from the polymer after the applying of the dispersion to the core; and
performing a heat treatment to prepare the polymer after the applying of the dispersion.

Assignees

• Battelle Memorial Institute

Inventors

• Addleman Raymond S
• Li Xiaohong Shari
• Chouyyok Wilaiwan
• Atkinson David A

Classifications

• G01N2001/024

  passengers or luggage · CPC title

• G01N1/405

  by adsorption or absorption · CPC title

• G01N2001/028

  Sampling from a surface, swabbing, vaporising · CPC title

• G01N2001/027

  field kits / quick test kits · CPC title

• G01N2001/4061

  Solvent extraction · CPC title