Vinyl chloride resin composition for powder molding and method for producing the same, vinyl chloride resin molded product and method for producing the same, and laminate

Patent metadata

Field	Value
Publication number	US-10533087-B2
Application number	US-201515520960-A
Country	US
Kind code	B2
Filing date	Nov 4, 2015
Priority date	Nov 11, 2014
Publication date	Jan 14, 2020
Grant date	Jan 14, 2020

Abstract

Provided is a vinyl chloride resin composition for powder molding that has excellent meltability in heat forming and high adhesiveness to a foamed polyurethane molded product after heat forming. The vinyl chloride resin composition for powder molding contains vinyl chloride resin particles (a), a plasticizer (b), a fatty acid amide (c), and vinyl chloride resin fine particles (d). The fatty acid amide (c) has a melting point of at least 105° C. and a content of at least 0.15 parts by mass and no greater than 13 parts by mass relative to a total content of 100 parts by mass of the vinyl chloride resin particles (a) and the vinyl chloride resin fine particles (d).

First claim

The invention claimed is:

1. A vinyl chloride resin composition for powder molding comprising
vinyl chloride resin particles (a), a plasticizer (b), a fatty acid amide (c), and vinyl chloride resin fine particles (d), wherein
the fatty acid amide (c) has a melting point of at least 105° C. and a content of at least 4.1 parts by mass and no greater than 10 parts by mass relative to a total content of 100 parts by mass of the vinyl chloride resin particles (a) and the vinyl chloride resin fine particles (d),
the fatty acid amide (c) has an average particle diameter of at least 0.1 μm and less than 20 μm.

2. The vinyl chloride resin composition for powder molding of claim 1 , wherein
the fatty acid amide (c) has a dimer or higher structure.

3. The vinyl chloride resin composition for powder molding of claim 1 , wherein
the vinyl chloride resin particles (a) have an average particle diameter of at least 50 μm and no greater than 500 μm.

4. The vinyl chloride resin composition for powder molding of claim 1 , wherein
the vinyl chloride resin fine particles (d) have an average particle diameter of at least 0.1 μm and no greater than 10 μm.

5. A vinyl chloride resin molded product obtained through powder slush molding of the vinyl chloride resin composition for powder molding of claim 1 .

6. The vinyl chloride resin molded product of claim 5 for a surface skin of an automobile instrument panel.

7. A laminate comprising:
a foamed polyurethane molded product; and
the vinyl chloride resin molded product of claim 5 .

8. The laminate of claim 7 for an automobile instrument panel.

9. A method for producing the vinyl chloride resin composition for powder molding of claim 1 , comprising
mixing the vinyl chloride resin particles (a), the plasticizer (b), the fatty acid amide (c), and the vinyl chloride resin fine particles (d).

10. A method for producing a vinyl chloride resin molded product comprising
powder slush molding the vinyl chloride resin composition for powder molding of claim 1 .

11. The vinyl chloride resin composition for powder molding of claim 1 , further comprising a β-diketone, wherein a content of the β-diketones relative to a total content of 100 parts by mass of the vinyl chloride resin particles (a) and the vinyl chloride resin fine particles (d) is at least 0.1 parts by mass and no greater than 5 parts by mass.

12. The vinyl chloride resin composition for powder molding of claim 1 , wherein the fatty acid amide (c) has the content of at least 4.1 parts by mass and no greater than 8.3 parts by mass relative to a total content of 100 parts by mass of the vinyl chloride resin particles (a) and the vinyl chloride resin fine particles (d).

Assignees

• Zeon Corp

Inventors

• Iwabuchi Satoshi

Classifications

• C08K5/20

  Carboxylic acid amides · CPC title

• B32B27/20

  using fillers, pigments, thixotroping agents · CPC title

• B32B2266/0278

  Polyurethane · CPC title

• C08J3/12

  Powdering or granulating · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title