Zr-based composite ceramic material, preparation method thereof, and shell or decoration

Patent metadata

Field	Value
Publication number	US-10532949-B2
Application number	US-201615775104-A
Country	US
Kind code	B2
Filing date	Nov 23, 2016
Priority date	Nov 30, 2015
Publication date	Jan 14, 2020
Grant date	Jan 14, 2020

Abstract

A Zr-based composite ceramic material, a preparation method thereof and a shell or a decoration are provided. The Zr-based composite ceramic material includes a zirconia matrix and a cubic SrxNbO3 stable phase dispersed within the zirconia matrix, where 0.7≤x≤0.95.

First claim

The invention claimed is:

1. A Zr-based composite ceramic material, comprising:
a zirconia matrix; and
a cubic Sr x NbO 3 stable phase dispersed within the zirconia matrix, where 0.7≤x≤0.95.

2. The Zr-based composite ceramic material of claim 1 , wherein 0.72≤x≤0.86.

3. The Zr-based composite ceramic material of claim 1 , wherein the cubic Sr x NbO 3 stable phase has a lattice constant of 3.98 to 4.03 Å.

4. The Zr-based composite ceramic material of claim 1 , wherein the cubic Sr x NbO 3 stable phase is a cubic Sr 0.82 NbO 3 stable phase, a cubic Sr 0.72 NbO 3 stable phase, or a cubic Sr 0.86 NbO 3 stable phase.

5. The Zr-based composite ceramic material of claim 1 , wherein a content of the cubic Sr x NbO 3 stable phase in the Zr-based composite ceramic material is in a range of about 0.2 mol % to about 8 mol %, based on 100 mol % of the zirconia matrix.

6. The Zr-based composite ceramic material of claim 1 , wherein a content of the cubic Sr x NbO 3 stable phase in the Zr-based composite ceramic material is in a range of about 1 mol % to about 6.1 mol %, based on 100 mol % of the zirconia matrix.

7. The Zr-based composite ceramic material of claim 1 , wherein the zirconia matrix is a zirconia matrix stabilized with about 3 mol % of yttrium.

8. The Zr-based composite ceramic material of claim 1 , wherein the cubic Sr x NbO 3 stable phase is formed by sintering SrCO 3 powder and Nb 2 O 5 powder added during preparation of the Zr-based composite ceramic material.

9. A method for preparing a Zr-based composite ceramic material, comprising:
preparing a mixed slurry by mixing a zirconia powder, a SrCO 3 powder, a Nb 2 O 5 powder and a binder; and
obtaining the Zr-based composite ceramic material by drying, molding and sintering the mixed slurry in sequence;
wherein a molar ratio of the SrCO 3 powder to the Nb 2 O 5 powder is 2x:1, where 0.7≤x≤0.95.

10. The method of claim 9 , wherein preparing a mixed slurry by mixing a zirconia powder, a SrCO 3 powder, a Nb 2 O 5 powder and a binder comprises:
preparing a pre-mixture by mixing and milling the zirconia powder, the SrCO 3 powder, and the Nb 2 O 5 powder; and
preparing the mixed slurry by mixing and milling the pre-mixture and the binder.

11. The method of claim 9 , wherein a molar ratio of the zirconia powder to the SrCO 3 powder is 100:(0.2-8)x.

12. The method of claim 11 , wherein the molar ratio of the zirconia powder to the SrCO 3 powder is 100:(1-6.1)x.

13. The method of claim 9 , wherein the molar ratio of the SrCO 3 powder to the Nb 2 O 5 powder is 2x:1, where 0.72≤x≤0.86.

14. The method of claim 13 , wherein a cubic Sr x NbO 3 stable phase is formed within the Zr-based composite ceramic material by sintering the SrCO 3 powder and the Nb 2 O 5 powder, wherein the cubic Sr x NbO 3 stable phase has a lattice constant of 3.98 to 4.03 Å.

15. The method of claim 13 , wherein x is 0.72, 0.82 or 0.86.

16. The method of claim 9 , wherein the drying step is carried out by a spray drying under conditions of: an air inlet temperature of about 220 Celsius degrees to about 260 Celsius degrees, an air outlet temperature of about 100 Celsius degrees to about 125 Celsius degrees, and a centrifugal rotational speed of about 10 rpm to about 20 rpm.

17. The method of claim 9 , wherein the molding step is carried out by adopting a dry pressing with a press having a tonnage of about 150 tons to about 200 tons under a dry pressure of about 6 MPa to about 12 MPa for about 20 seconds to about 60 seconds.

18. The method of claim 9 , wherein the sintering step is carried out at a temperature of about 1350 Celsius degrees to about 1500 Celsius degrees for about 1 hour to about 2 hours.

19. The method of claim 9 , wherein the sintering step comprises:
heating a preformed part obtained in the molding step from room temperature up to a temperature ranging from about 550 Celsius degrees to about 650 Celsius degrees in about 350 minutes to about 450 minutes, and then holding for about 1.5 hours to about 2.5 hours;
raising the temperature up to about 1100 Celsius degrees to about 1200 Celsius degrees in about 250 minutes to about 350 minutes, and then holding for about 1.5 hours to about 2.5 hours;
raising the temperature up to about 1250 Celsius degrees to about 1350 Celsius degrees in about 120 minutes to about 180 minutes, and then holding for about 1.5 hours to about 2.5 hours;
raising the temperature up to about 1430 Celsius degrees to about 1470 Celsius degrees in about 30 minutes to about 60 minutes, and then holding for about 1 hour to about 2 hours;
dropping the temperature to about 900 Celsius degrees in about 120 minutes to about 180 minutes; and
naturally dropping the temperature to room temperature.

20. The method of claim 19 , wherein the sintering step comprises:
heating the preformed part obtained in the molding step from room temperature up to a temperature of about 600 Celsius degrees in about 400 minutes, and then holding for about 2 hours;
raising the temperature up to about 1150 Celsius degrees in about 300 minutes, and then holding for about 2 hours;
raising the temperature up to about 1300 Celsius degrees in about 150 minutes, and then holding for about 2 hours;
raising the temperature up to about 1450 Celsius degrees in about 50 minutes, and then holding for about 1.5 hours;
dropping the temperature to about 900 Celsius degrees in about 150 minutes; and
naturally dropping the temperature to room temperature.

Assignees

• Byd Co Ltd

Inventors

• Gong Qing
• Lin Xinping
• Chen Ge
• Wu Bo

Classifications

• C04B35/63416

  Polyvinylalcohols [PVA]; Polyvinylacetates · CPC title

• C04B35/63488

  Polyethers, e.g. alkylphenol polyglycolether, polyethylene glycol [PEG], polyethylene oxide [PEO] · CPC title

• C04B2235/762

  Cubic symmetry, e.g. beta-SiC · CPC title

• C04B2235/761

  Unit-cell parameters, e.g. lattice constants · CPC title

• C04B2235/6562

  Heating rate · CPC title