Size-tunable nanoparticle synthesis

Patent metadata

Field	Value
Publication number	US-10532403-B2
Application number	US-201615559534-A
Country	US
Kind code	B2
Filing date	Mar 17, 2016
Priority date	Mar 19, 2015
Publication date	Jan 14, 2020
Grant date	Jan 14, 2020

Abstract

A method for synthesizing nanoparticles with a predetermined size at high or full yield comprises mixing a first precursor material comprising a first compound comprising a halide moiety and a metal or a metalloid, a second precursor material comprising a second compound comprising a polyatomic nonmetal, and a solvent. The method further comprises heating the mixture to colloidally form nanoparticles comprising the polyatomic nonmetal and the metal or metalloid. The halide moiety is selected such as to colloidally form the nanoparticles in a predetermined size range that is at least partially determined by this halide moiety.

First claim

The invention claimed is:

1. A method for synthesizing nanoparticles, the method comprising:
mixing a first precursor material comprising a first compound comprising a halide moiety and a metal or a metalloid, a second precursor material comprising a second compound comprising at least a polyatomic nonmetal, and a solvent to obtain a mixture solution, and
heating said mixture solution such as to colloidally form nanoparticles comprising said polyatomic nonmetal and said metal or comprising said polyatomic nonmetal and said metalloid,
wherein said halide moiety is selected such as to colloidally form said nanoparticles in a predetermined size range that is at least partially determined by said halide moiety and wherein an abundance of at least 2.5, of the polyatomic nonmetal relative to the metal or the metalloid is obtained in said mixture solution.

2. The method for synthesizing according to claim 1 , wherein the second precursor material comprises a second compound comprising said at least a polyatomic nonmetal and an amine.

3. The method according to claim 2 , wherein said amine comprises an aliphatic primary or secondary amine.

4. The method for synthesizing according to claim 1 , wherein an abundance of 4 of the polyatomic nonmetal relative to the metal or the metalloid is obtained in said mixture solution.

5. The method according to claim 1 , wherein said mixing comprises mixing said first precursor material comprising a plurality of different halide moieties, and
wherein the relative abundances of said plurality of different halide moieties is selected such as to colloidally form said nanoparticles in a predetermined size range at least partially determined by said relative abundances of the plurality of different halide moieties.

6. The method according to claim 1 , wherein the metal or the metalloid comprises at least one of cadmium, mercury, zinc, titanium, aluminum, gallium, indium, thallium, silicon, germanium, tin, lead, arsenic, antimony, bismuth, tellurium, polonium or astatine and/or wherein the polyatomic nonmetal comprises phosphorus, sulfur or selenium.

7. The method according to claim 1 , wherein said second precursor material comprises a phosphorous material.

8. The method according to claim 1 , wherein said first precursor material comprises an indium halide and said second precursor material comprises tris(diethylamino)phosphine.

9. The method according to claim 1 , furthermore comprising a step of degassing the mixture solution before or during said heating.

10. The method according to claim 1 , in which said heating is performed under an inert atmosphere.

11. The method according to claim 1 , in which said mixing comprises mixing at least one further precursor material in said mixture solution, wherein the at least one further precursor material comprises at least one further compound comprising a halide moiety and a further metal or metalloid, said further metal or metalloid being different from said metal or said metalloid in the first compound.

12. The method according to claim 11 , wherein said heating comprises heating said mixture solution such as to colloidally form nanoparticles comprising said polyatomic nonmetal and said metal or metalloid of the first compound, said further metal or metalloid of the at least one further compound and said polyatomic nonmetal.

13. The method according to claim 12 , wherein said first precursor material comprises an indium halide, said second precursor material comprises tris(diethylamino)phosphine and said at least one further precursor material comprises a group II metal halide.

14. The method according to claim 1 , wherein mixing of the mixture solution and heating the mixture solution comprise one or both of
heating the solvent and
injecting the first precursor material and the second precursor material at a predetermined temperature of the solvent.

15. The method according to claim 1 , wherein mixing of the mixture solution and heating the mixture solution comprise one or both of
heating the solvent mixed with one of the first precursor material and the second precursor material, and
injecting the other of the first precursor material and the second precursor material at a predetermined temperature.

Assignees

• Univ Gent

Inventors

• Tessier Mickael
• Dupont Dorian
• Hens Zeger

Classifications

• C09K11/0883

  Arsenides; Nitrides; Phosphides · CPC title

• C09K11/70

  containing phosphorus · CPC title

• B22F1/142

  Thermal or thermo-mechanical treatment · CPC title

• C09K11/0827

  Halogenides (C09K11/0805 takes precedence) · CPC title

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title