Methods and systems for treating wastewater from induced hydraulic fracturing
US-2016176741-A1 · Jun 23, 2016 · US
US10532298B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10532298-B2 |
| Application number | US-201515532251-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 2, 2015 |
| Priority date | Dec 2, 2014 |
| Publication date | Jan 14, 2020 |
| Grant date | Jan 14, 2020 |
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The present disclosure relates to a method for separation of solid particles from a waterbody. Preferably, the present disclosure relates to a method, wherein a combination of chemicals including coagulant(s) and flocculant(s) are employed for said separation of solid particles, wherein suitable examples of solid particles are living organisms and non-living matter, wherein living organisms include autotrophs such as phototrophs, which are either microscopic or macroscopic in nature (algae). The disclosure thus particularly relates to method of chemical coagulation and flocculation for separating solid particles, preferably either algae or bacteria or both from a waterbody. The present disclosure also provides for an alternate method, wherein the aforesaid method of coagulation and flocculation is combined with electro-coagulation and/or pH modulation strategies for separation of said solid particles in any sequence.
Opening claim text (preview).
We claim: 1. A method for separation of algae from a waterbody, said method comprising contacting the waterbody with an electric current to cause electrocoagulation, followed by contacting the waterbody with at least one coagulant and at least one flocculant to cause coagulation and flocculation, to separate the algae. 2. The method of claim 1 , wherein the the algae is selected from the group consisting of Scenedesmus sp, Cyanobacterium aponium, Nannochloropsis sp, Pseudooneochloris sp, Picochlorum sp, Nanochloropsis oceanica, Chlorella vulgaris, Chlorella sorokiniana , and any combination of two or more thereof. 3. The method of claim 1 , wherein the waterbody is selected from the group consisting of ocean water, sea water, lake water, pond water, wetland water, puddle water, and any combination thereof, and wherein the salinity of the waterbody is from about 0.1% to 14%. 4. The method of claim 1 , wherein the at least one coagulant is at a concentration from about 5 ppm to 500 ppm for about 500 ppm to 5000 ppm of the algae in the waterbody; and the at least one flocculant is at a concentration from about 0.5 ppm to 4 ppm for about 500 ppm to 5000 ppm of the algae in the waterbody. 5. The method of claim 1 , wherein a percentage separation or recovery of the algae from the waterbody is at least 95%. 6. The method of claim 1 , wherein the combination of the at least one coagulant and the at least one flocculant causes coagulation and flocculation, respectively, of the algae in the waterbody. 7. The method of claim 1 , wherein the electric current is contacted with the waterbody having the algae for a time duration of about 15 seconds to 720 seconds. 8. The method of claim 1 , further comprising modulating the pH of the waterbody having the algae by adding a base selected from the group consisting of sodium hydroxide, potassium hydroxide, and a combination thereof, or by adding an acid selected from the group consisting of hydrochloric acid, nitric acid, sulphuric acid, and any combination thereof, prior to contacting the waterbody with the electric current. 9. The method of claim 8 , wherein the pH of the waterbody upon addition of the base or the acid is from about 9.0 to 10.0. 10. The method of claim 1 further comprising a process selected from the group consisting of dissolved air flotation, froth flotation, and filtration for separation of the algae from the waterbody. 11. The method of claim 1 , wherein the method is configured to reduce coagulant and flocculant dosage within the combination of the at least one coagulant and the at least one flocculant during the separation of the algae from the waterbody when compared to a method employing coagulant and flocculant, independently for separation of the algae. 12. The method of claim 1 , wherein the at least one coagulant is selected from the group consisting of aluminum chlorohydrate polyamines, aluminum chlorohydrate-polyaluminum chloride-polyacrylamide-polyamines, ferric chloride, aluminum hydroxide chloride, a blend of cationic polymer with poly aluminum hydroxide, and any combination thereof, and the at least one flocculant is selected from the group consisting of copolymer of acrylamide and sodium acrylate, polyaluminum chloride, and any combination of two or more thereof.
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