Processing unit for a washing medium contaminated with sulphur oxides and/or nitrogen oxides

Patent metadata

Field	Value
Publication number	US-10532293-B2
Application number	US-201515304599-A
Country	US
Kind code	B2
Filing date	Mar 25, 2015
Priority date	Apr 25, 2014
Publication date	Jan 14, 2020
Grant date	Jan 14, 2020

Abstract

A processing unit for a liquid washing medium contaminated with sulphur oxides and/or nitrogen oxides, has an evaporation stage for concentrating the active components of the washing medium by an evaporator and/or by a heat exchanger, and has a collecting tank connected to the evaporator and/or to the heat exchanger. The collecting tank is configured as a crystallizer for removing sulfur oxides from the washing medium by crystallization of a sulphate, in particular of potassium sulphate. A separating device for carbon dioxide has a corresponding processing unit, and a method for processing a washing medium contaminated with sulphur oxides and/or nitrogen oxides uses a corresponding processing unit.

First claim

The invention claimed is:

1. A processing unit for a liquid scrubbing medium contaminated with sulphur oxides and/or nitrogen oxides, comprising
an evaporation stage for concentrating an active component of the scrubbing medium comprising an evaporator and/or a heat exchanger, and
a collecting tank that is connected to the evaporator and/or to the heat exchanger,
wherein the collecting tank is connected via a first outlet of the collecting tank to a separation unit,
wherein the collecting tank is constructed as a crystallizer for removing sulphur oxides from the scrubbing medium by crystallization of a sulphate,
wherein a first outlet of the separation unit is connected to an additional crystallizer for recovery of the active component of the scrubbing medium,
wherein a second outlet of the separation unit is connected to a first inlet of the collecting tank, and
wherein the first outlet of the separation unit is connected to an inlet of the evaporator.

2. The processing unit as claimed in claim 1 ,
wherein the separation unit is constructed as a hydro cyclone.

3. The processing unit as claimed in claim 1 ,
wherein the collecting tank comprises a classifying appliance for separating the crystallized sulphate particles according to a particle size thereof.

4. The processing unit as claimed in claim 3 ,
wherein the classifying appliance is constructed in the form of a classifying zone comprising a first classifying region and a second classifying region within the crystallizer, wherein the first classifying region is connected via the first outlet of the collecting tank to an inlet of the separation unit.

5. The processing unit as claimed in claim 1 ,
wherein the first outlet of the separation unit is connected to an inlet of an absorber unit of a carbon dioxide separation device.

6. The processing unit as claimed in claim 1 , further comprising
a metering device for adjusting an alkali metal concentration in the scrubbing medium, which metering device is connected to the collecting tank.

7. The processing unit as claimed in claim 4 ,
wherein the second classifying region is connected via a second outlet of the collecting tank to a reclamation appliance for the crystallized sulphate particles.

8. The processing unit as claimed in claim 1 ,
wherein an amino acid salt is used as the active component of the scrubbing medium.

9. The processing unit as claimed in claim 1 , further comprising:
an absorber unit for separating off carbon dioxide from a flue gas by means of a scrubbing medium, and also a desorber unit that is flow-connected downstream of the absorber unit and is for separating off the carbon dioxide from the scrubbing medium, and
wherein the collecting tank is flow-connected downstream of the desorber unit.

10. A method for processing a scrubbing medium contaminated with sulphur oxides and/or nitrogen oxides, the method comprising:
feeding the scrubbing medium, to concentrate an active component thereof, to an evaporation stage comprising an evaporator and/or a heat exchanger, and
a collecting tank that is flow-connected to the evaporator and/or to the heat exchanger,
wherein sulphur oxides present in the scrubbing medium are crystallized out in the collecting tank as sulfate particles that are fed to a separation unit from the collecting tank,
feeding a first substream of an overflow of the separation unit to an additional crystallizer for recovery of the active component of the scrubbing medium, and
feeding a second sub stream of an overflow of the separation unit to the collecting tank, and
feeding a second sub stream of an overflow of the separation unit to the evaporator.

11. The method as claimed in claim 10 , further comprising:
separating sulphate particles in a classifying appliance of the collecting tank according to their particle size.

12. The method as claimed in claim 10 ,
feeding a third sub stream of an overflow of the separation unit to an absorber unit of a separation device.

13. The method as claimed in claim 10 , further comprising:
adjusting an alkali metal concentration in the scrubbing medium via a metering device connected to the collecting tank.

14. The method as claimed in claim 10 , further comprising:
feeding a second sub stream that is enriched with sulphate particles comprising substantially large sulphate particles from the collecting tank to a reclamation appliance.

15. The method as claimed in claim 10 ,
wherein an amino acid salt is used as the active component of the scrubbing medium.

16. The processing unit as claimed in claim 1 ,
wherein the sulphate comprises potassium sulphate.

17. The processing unit as claimed in claim 6 ,
wherein the alkali metal concentration comprises a potassium concentration.

18. The processing unit as claimed in claim 7 ,
wherein the crystallized sulphate particles comprises potassium sulphate.

19. The processing unit as claimed in claim 8 ,
wherein the amino acid salt comprises a potassium-containing amino acid salt.

20. The method as claimed in claim 10 ,
wherein the sulfate particles comprise potassium sulphate particles.

21. The method as claimed in claim 11 , further comprising:
feeding a first substream comprising substantially small and medium sulphate particles from the collecting tank to the separation unit.

22. The method as claimed in claim 21 ,
wherein the substantially small and medium sulphate particles comprise substantially small and medium potassium sulphate particles.

23. The method as claimed in claim 13 ,
wherein the alkali metal concentration comprises a potassium concentration.

24. The method as claimed in claim 15 ,
wherein the amino acid salt comprises a potassium-containing amino acid salt.

25. The processing unit as claimed in claim 6 , wherein the metering device comprises two pumps by means of which additional reactants are fed to the collecting tank to prevent an unwanted concentration of potassium.

26. The processing unit as claimed in claim 7 , wherein the reclamation appliance comprises a collection tank and a solid-liquid separator comprising a filter, decanter, or centrifuge.

27. The processing unit as claimed in claim 9 , wherein the absorber unit comprises a scrubber and the desorber unit comprises a thermal desorber comprising a desorber heat exchanger.

Assignees

• Siemens Ag

Inventors

• Kursawe Ansgar
• Hauke Stefan
• Joh Ralph
• Kinzl Markus
• Schneider Rüdiger

Classifications

• B01D2258/0283

  Flue gases · CPC title

• B01D2251/506

  Sulfuric acid · CPC title

• B01D2251/306

  of potassium · CPC title

• B01D53/62

  Carbon oxides · CPC title

• B01D2252/20494

  Amino acids, their salts or derivatives · CPC title