Storage battery electrode, manufacturing method thereof, storage battery, electronic device, and graphene

Patent metadata

Field	Value
Publication number	US-10529977-B2
Application number	US-201514836420-A
Country	US
Kind code	B2
Filing date	Aug 26, 2015
Priority date	Aug 27, 2014
Publication date	Jan 7, 2020
Grant date	Jan 7, 2020

Abstract

To provide graphene oxide that has high dispersibility and is easily reduced. To provide graphene with high electron conductivity. To provide a storage battery electrode including an active material layer with high electric conductivity and a manufacturing method thereof. To provide a storage battery with increased discharge capacity. A method for manufacturing a storage battery electrode that is to be provided includes a step of dispersing graphene oxide into a solution containing alcohol or acid, a step of heating the graphene oxide dispersed into the solution, and a step or reducing the graphene oxide.

First claim

The invention claimed is:

1. A method for manufacturing a storage battery electrode, comprising the steps of:
dispersing graphene oxide into a solution, the solution containing alcohol or acid;
heating the graphene oxide in the solution;
forming a mixture of the graphene oxide, an active material, a binder, and a solvent after heating the graphene oxide;
applying the mixture on a current collector;
removing the solvent in the mixture after applying; and
reducing the graphene oxide in the mixture, so that an active material layer containing graphene is formed over the current collector,
wherein the graphene oxide includes an alkoxy group after the heating, and
wherein the step of reducing is performed by immersing the graphene oxide in a polar solvent containing a reducing agent.

2. A method for manufacturing a storage battery electrode, comprising the steps of:
dispersing graphene oxide into a solution, the solution containing alcohol or acid;
heating the graphene oxide in the solution;
forming a first mixture of the graphene oxide and an active material after heating the graphene oxide;
forming a second mixture by reducing the graphene oxide in the first mixture;
forming a third mixture of the second mixture, a binder, a conductive additive, and a solvent,
applying the third mixture on a current collector; and
removing the solvent in the third mixture, so that an active material layer containing graphene is formed over the current collector,
wherein the graphene oxide includes an alkoxy group after the heating, and
wherein the step of reducing is performed by immersing the graphene oxide in a polar solvent containing a reducing agent.

3. The method for manufacturing a storage battery electrode according to claim 1 ,
wherein the step of reducing is performed by heating the graphene oxide, and
wherein a heating temperature is higher than or equal to 60° C. and lower than or equal to 150° C.

4. The method for manufacturing a storage battery electrode according to claim 2 ,
wherein the step of reducing is performed by heating the graphene oxide, and
wherein a heating temperature is higher than or equal to 60° C. and lower than or equal to 150° C.

5. The method for manufacturing a storage battery electrode according to claim 1 , wherein the alcohol is 1-propanol or 2-propanol.

6. The method for manufacturing a storage battery electrode according to claim 2 , wherein the alcohol is 1-propanol or 2-propanol.

7. The method for manufacturing a storage battery electrode according to claim 1 , wherein the acid is carboxylic acid.

8. The method for manufacturing a storage battery electrode according to claim 2 , wherein the acid is carboxylic acid.

Assignees

• Semiconductor Energy Lab

Inventors

• Ikenuma Tatsuya
• Yoneda Yumiko

Classifications

• H01M4/625

  Carbon or graphite · CPC title

• H01M4/1393

  of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• Y02E60/13

  Energy storage using capacitors · CPC title

• C01B32/184

  Preparation · CPC title

• H01M4/049

  Manufacturing of an active layer by chemical means · CPC title