Dynamic urea bonds for reversible and self-healing polymers
US-10000608-B2 · Jun 19, 2018 · US
US10526495B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10526495-B2 |
| Application number | US-201615543464-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 14, 2016 |
| Priority date | Jan 16, 2015 |
| Publication date | Jan 7, 2020 |
| Grant date | Jan 7, 2020 |
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Self-healing polymers used to fabricate electrical devices or to coat electrical devices that have a metal or polymer substrate. The self-healing polymers can be made from modified polymers including polyurethanes, polyureas, polyamides and polyesters and, optionally, cross-linking agents and one or more catalysts. The self-healing polymers can be used to make cable ties, tape, conduit fittings and explosion-proof sealant materials.
Opening claim text (preview).
We claim: 1. An electrical device comprising: a substrate made from or a metal or non-metal, the substrate having a first part and a second part, the first part being selectively displaceable relative to the second part; and an outer layer or coating positioned on the substrate, the outer layer or coating comprising a self-healing polymer, a first section of the self-healing polymer being positioned on the first part and a second section of the self-healing polymer being positioned on the second part at a location at which, upon selective displacement of the first part, the first section contacts, and securely self-bonds with, the second section. 2. The electrical device according to claim 1 , wherein the self-healing polymer is modified polyurethanes, polyureas, polyamides or polyesters. 3. The electrical device according to claim 2 , wherein the self-healing polymer is modified polyurea material comprising a first monomer that has isocyanate function groups and a second monomer that has amine function groups. 4. The electrical device according to claim 2 , wherein the modified polyurea material further comprises a cross-linking agent and/or a catalyst. 5. The electrical device according to claim 1 , wherein the modified polyurea material further comprises triethyolamine (TEA) and tetra ethylene glycol (TEG) as cross-linking agents and dibutyl tin diacetate as a catalyst. 6. The electrical device according to claim 5 , wherein the molar ratio of TEA to the first monomer to TEG to the second monomer is 1:12:6.8:4.
Polyurethanes · CPC title
with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds · CPC title
Coating compositions based on polyamides obtained by reactions forming a carboxylic amide link in the main chain (based on polyhydrazides C09D179/06; based on polyamide-imides C09D179/08); Coating compositions based on derivatives of such polymers · CPC title
Polyesters, esterified polyepoxides · CPC title
Housings; Supporting members; Arrangements of terminals · CPC title
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