Methacrylic resin or methacrylic resin composition

Patent metadata

Field	Value
Publication number	US-10526430-B2
Application number	US-201515323016-A
Country	US
Kind code	B2
Filing date	Jun 30, 2015
Priority date	Jun 30, 2014
Publication date	Jan 7, 2020
Grant date	Jan 7, 2020

Abstract

A methacrylic resin composition comprises not less than 90% by mass and not more than 100% by mass of a methacrylic resin [A] having: the total content of a structural unit derived from methyl methacrylate of not less than 90% by mass; a molecular weight MA of not less than 30000 and not more than 100000 in terms of polystyrene corresponding to the retention time indicating the value of the maximum strength in a chromatogram obtained by gel permeation chromatography; the area SgA of a region enclosed by an approximate curve obtained by fitting the data of a range indicating the strength of not less than 70% relative to the value of the maximum strength to a Gaussian function by the method of nonlinear least squares and the base line of the chromatogram of 45 to 80% of the area SA enclosed by the chromatogram and its base line; and the ratio MwgA/MngA of a weight average molecular weight MwgA to a number average molecular weight MngA of not less than 1.01 and not more than 1.20 in terms of polystyrene computed based on an approximate curve obtained by the above fitting.

First claim

The invention claimed is:

1. A methyl methacrylate-based polymer, comprising a structural unit derived from methyl methacrylate,
wherein a total content of the structural unit derived from methyl methacrylate is not less than 90% by mass, and
wherein the methyl methacrylate-based polymer has:
a molecular weight M A of not less than 30 thousand and not more than 100 thousand wherein the molecular weight M A is a molecular weight in terms of polystyrene corresponding to a peak retention time having a value of the maximum strength in a chromatogram of the methyl methacrylate-based polymer obtained by gel permeation chromatography;
a ratio S gA /S A of area S gA to area S A of 45 to 80% wherein the area S A is area of a region enclosed by the chromatogram and a base line, in which the base line is obtained by connecting a first point at which a slope of the chromatogram on a higher molecular weight side of the peak retention time changes from zero to a positive value and a second point at which a slope of the chromatogram on a lower molecular weight side of the peak retention time changes from a negative value to zero, the area S gA is area of a region enclosed by an approximate curve and the base line of the chromatogram, and the approximate curve is obtained by fitting data in the chromatogram between the first point and the second point to a Gaussian function by a nonlinear least squares method, and the data have a strength of not less than 70% relative to the value of the maximum strength in the chromatogram; and
a ratio Mw gA /Mn gA of a weight average molecular weight Mw gA to a number average molecular weight Mn gA of not less than 1.01 and not more than 1.20 wherein the weight average molecular weight Mw gA and the number average molecular weight Mn gA are a weight average molecular weight and a number average molecular weight, respectively, in terms of polystyrene computed based on the approximate curve obtained by the fitting.

2. The methyl methacrylate-based polymer according to claim 1 , further having a ratio Mw A /Mn A of a weight average molecular weight Mw A to a number average molecular weight Mn A of 1.3 to 3.0 wherein the weight average molecular weight Mw A and the number average molecular weight Mn A are a weight average molecular weight and a number average molecular weight, respectively, in terms of polystyrene computed based on the chromatogram between the first point and the second point.

3. The methyl methacrylate-based polymer according to claim 1 , wherein the total content of the structural unit derived from methyl methacrylate is not less than 99% by mass.

4. The methyl methacrylate-based polymer according to claim 1 , further having a triad syndiotacticity (rr) of not less than 58%.

5. The methyl methacrylate-based polymer according to claim 1 , further having a midpoint glass transition temperature of not less than 120° C. as measured by differential scanning calorimetry.

6. A methacrylic resin composition, comprising
100 parts by mass of the methyl methacrylate-based polymer according to claim 1 and
1 to 10 parts by mass of a polycarbonate resin.

7. A methacrylic resin composition, comprising
100 parts by mass of the methyl methacrylate-based polymer according to claim 1 and
5 to 30 parts by mass of a crosslinked rubber.

8. A methacrylic resin composition, comprising
100 parts by mass of the methyl methacrylate-based polymer according to claim 1 and
0.1 to 10 parts by mass of a phenoxy resin.

9. A methacrylic resin composition, comprising
not less than 70% by mass of methyl methacrylate-based polymer [A] having a total content of a structural unit derived from methyl methacrylate of not less than 90% by mass,
wherein the methacrylic resin composition has:
a molecular weight M C of not less than 30 thousand and not more than 100 thousand wherein the molecular weight M C is a molecular weight in terms of polystyrene corresponding to a peak retention time having a value of the maximum strength in a chromatogram of the methacrylic resin composition obtained by gel permeation chromatography;
a ratio S gC /S C of area S gC to area S C of 45 to 80% wherein the area S C is area of a region enclosed by the chromatogram and a base line, in which the base line is obtained by connecting a first point at which a slope of the chromatogram on a higher molecular weight side of the peak retention time changes from zero to a positive value and a second point at which a slope of the chromatogram on a lower molecular weight side of the peak retention time changes from a negative value to zero, the area S gC is area of a region enclosed by an approximate curve and the base line of the chromatogram, the approximate curve is obtained by fitting data in the chromatogram between the first point and the second point to a Gaussian function by a nonlinear least squares method and the data have a strength of not less than 70% relative to the value of the maximum strength in the chromatogram; and
a ratio Mw gC /Mn gC of a weight average molecular weight Mw gC to a number average molecular weight Mn gC of not less than 1.01 and not more than 1.20 wherein the weight average molecular weight Mw gC and the number average molecular weight Mn gC are a weight average molecular weight and a number average molecular weight, respectively, in terms of polystyrene computed based on the approximate curve obtained by the fitting.

10. The methacrylic resin composition according to claim 9 , further having a ratio Mw C /Mn C of a weight average molecular weight Mw C to a number average molecular weight Mn C of 1.3 to 3.0 wherein the weight average molecular weight Mw C and the number weight average molecular weight Mn C are a weight average molecular weight and a number average molecular weight, respectively, in terms of polystyrene computed based on the chromatogram between the first point and the second point.

11. The methacrylic resin composition according to claim 9 , wherein the methyl methacrylate-based polymer [A] has the total content of the structural unit derived from methyl methacrylate of not less than 99% by mass.

12. The methacrylic resin composition according to claim 9 , wherein the methyl methacrylate-based polymer [A] has a triad syndiotacticity (rr) of not less than 58%.

13. The methacrylic resin composition according to claim 9 , further having a midpoint glass transition temperature of not less than 120° C. as measured by differential scanning calorimetry.

14. The methacrylic resin composition according to claim 9 , further comprising
1 to 10 parts by mass of a polycarbonate resin relative to 100 parts by mass of the methyl methacrylate-based polymer [A].

15. The methacrylic resin composition according to claim 9 , further comprising
5 to 30 parts by mass of a crosslinked rubber relative to 100 parts by mass of the methyl methacrylate-based polymer [A].

16. The methacrylic resin composition according to claim 9 , further comprising
0.1 to 10 parts by mass of a phenoxy resin relative to 100 parts by mass of the methyl methacrylate-based polymer [A].

17. A formed article, comprising
the methyl methacrylate-based polymer according to claim 1 .

18. A film, comprising
the methyl methacrylate-based polymer according to claim 1 .

19. A stretched film, comprising
the methyl methacrylate-based polymer according to claim 1 .

20. A phase difference film, comprising
the methyl methacrylate-based polymer according to claim 1 .

21. A polariz

Assignees

• Kuraray Co

Inventors

• Nakahara Atsuhiro
• Abe Toru
• Takahashi Toru
• Ozawa Hiroshi

Classifications

• C08F120/14

  Methyl esters {, e.g. methyl (meth)acrylate} · CPC title

• C08F285/00

  Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers · CPC title

• C08F265/06

  Polymerisation of acrylate or methacrylate esters on to polymers thereof · CPC title

• C08L33/12 Primary

  Homopolymers or copolymers of methyl methacrylate · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title