Scratch-resistant coatings with improved cleanability, substrates with scratch-resistant coatings with improved cleanability, and methods for producing same

Patent metadata

Field	Value
Publication number	US-10526241-B2
Application number	US-201615283053-A
Country	US
Kind code	B2
Filing date	Sep 30, 2016
Priority date	Oct 1, 2015
Publication date	Jan 7, 2020
Grant date	Jan 7, 2020

Abstract

A substrate having a scratch resistance enhancing coating with improved cleanability and methods for producing such a coating are provided. The coating includes at least one high refractive index transparent hard material layer and includes aluminum nitride. The coating exhibits a contact angle for water of greater than 75°.

First claim

What is claimed is:

1. A coated substrate comprising:
a substrate; and
a coating on the substrate, the coating being a coating, the coating comprising a transparent hard material layer having a refractive index in a range from 1.8 to 2.3 at a wavelength of 550 nm, wherein the hard material layer includes aluminum nitride and a material selected from a group consisting of nitrides, carbides, carbonitrides, and any combinations thereof, and wherein the coating has a contact angle for water of greater 75°.

2. The coated substrate as claimed in claim 1 , wherein the hard material layer comprises crystalline aluminum nitride with a hexagonal crystal structure exhibiting a predominantly (001) preferred orientation.

3. The coated substrate as claimed in claim 2 , wherein the hexagonal crystal structure exhibiting the (001) preferred orientation has a proportion of:
x (001) =I (001) /( I (001) +I (100) )
and/or
y (001) =I (001) /( I (001) +I (101) )

as determined by an XRD measurement of the coating, that is greater than 0.5.

4. The coated substrate as claimed in claim 2 , wherein the hexagonal crystal structure has an average crystallite size is at most 25 nm.

5. The coated substrate as claimed in claim 1 , wherein the coating has a mean roughness of less than 1.3 nm and/or a RMS roughness of less than 2 nm.

6. The coated substrate as claimed in claim 1 , wherein the coating has a coefficient of static friction of less than 0.3 and/or a coefficient of sliding friction of less than 0.2.

7. The coated substrate as claimed in claim 1 , wherein the coating exhibits a contact angle for water of ≥80° and/or a contact angle for ethylene glycol of ≥70°, and/or a contact angle for diiodomethane of ≥55°.

8. The coated substrate as claimed in claim 1 , wherein the coating exhibits polar and/or dispersive surface energy of less than 50 mN/m.

9. The coated substrate as claimed in claim 1 , wherein the coating exhibits a modulus of elasticity at a test load of 10 mN from 80 to 250 GPa and/or wherein the coating has a ratio of hardness to the modulus of elasticity of at least 0.08.

10. The coated substrate as claimed in claim 1 , wherein the aluminum nitride of the hard material layer is doped with one or more nitrides and/or carbides and/or carbonitrides of elements selected from the group consisting of silicon, boron, zirconium, titanium, nickel, chromium, and carbon.

11. The coated substrate as claimed in claim 10 , wherein the aluminum content in the hard material layer, based on the dopant material, is greater than 50 wt %.

12. The coated substrate as claimed in claim 1 , wherein the hard material layer has a proportion of oxygen in that is at most 10 at %.

13. The coated substrate as claimed in claim 1 , wherein the hard material layer has a thickness from 1 to 2000 nm.

14. The coated substrate as claimed in claim 1 , wherein the substrate selected from the group consisting of a glass ceramic, a LAS glass ceramic, a glass, a sapphire glass, a borosilicate glass, an aluminosilicate glass, a soda-lime glass, a synthetic quartz glass, a lithium aluminosilicate glass, an optical glass, and an optical crystal.

15. The coated substrate as claimed in claim 1 , wherein the substrate is a glass ceramic having a coefficient of thermal expansion α 2 0-300 of less than 2*10 −6 K −1 .

16. The coated substrate as claimed in claim 1 , wherein the substrate further comprises decorated areas, at least in sections thereof, and wherein the decorated areas are disposed between the substrate and the coating.

17. The coated substrate as claimed in claim 1 , further comprising an adhesion promoting layer arranged between the substrate and the coating.

18. The coated substrate as claimed in claim 1 , wherein the hard material layer has a degree of crystallization of at least 50%.

19. A coated substrate comprising:
a substrate; and
a coating on the substrate, the coating comprising a transparent hard material layer with a refractive index in a range from 1.8 to 2.3 at a wavelength of 550 nm, wherein the coating has a contact angle for water of greater 75°, wherein the hard material layer comprises aluminum nitride, and wherein the coating has a mean roughness of less than 1.3 nm and/or a RMS roughness of less than 2 nm.

20. A coated substrate comprising:
a substrate, the substrate comprising a glass ceramic having a coefficient of thermal expansion α 2 0-300 of less than 2*10 −6 K −1 ; and
a coating on the substrate, the coating comprising a transparent hard material layer with a refractive index in a range from 1.8 to 2.3 at a wavelength of 550 nm, wherein the hard material layer includes aluminum nitride, and wherein the coating has a contact angle for water of greater 75°.

21. A coated substrate comprising:
a substrate;
a coating on the substrate, the coating comprising a transparent hard material layer with a refractive index in a range from 1.8 to 2.3 at a wavelength of 550 nm, wherein the hard material layer includes aluminum nitride, and wherein the coating has a contact angle for water of greater 75°; and
one or more decorated areas on the substrate, the one or more decorated areas being disposed between the substrate and the coating.

Assignees

• Schott Ag

Inventors

• Henn Christian
• Back Franziska
• Herrmann Jochen

Classifications

• C03C2218/156

  by magnetron sputtering · CPC title

• C03C2217/281

  Nitrides · CPC title

• C03C17/225 Primary

  Nitrides · CPC title

• C03C2217/78

  Coatings specially designed to be durable, e.g. scratch-resistant · CPC title

• C03C17/3435 Primary

  comprising a nitride, oxynitride, boronitride or carbonitride · CPC title