Gas sensor

Patent metadata

Field	Value
Publication number	US-10520466-B2
Application number	US-201715708431-A
Country	US
Kind code	B2
Filing date	Sep 19, 2017
Priority date	Sep 23, 2016
Publication date	Dec 31, 2019
Grant date	Dec 31, 2019

Abstract

A gas sensor that is unlikely to have Au evaporation from an external electrode even when used under a high temperature atmosphere is provided. The gas sensor includes a sensor element mainly made of an oxygen-ion conductive solid electrolyte; an external electrode provided on the sensor element and containing a Pt—Au alloy; and an electrode evaporation preventing film provided on the sensor element while being insulated from the sensor element and separated from the external electrode, and made of Au or a Pt—Au alloy having an Au composition ratio not smaller than an Au composition ratio of the Pt—Au alloy contained in the external electrode. A protection cover is provided so that at least part of the sensor element, at which the external electrode and the electrode evaporation preventing film is positioned, is inside the protection cover, and so that a measurement gas is introduced inside the protection cover.

First claim

What is claimed is:

1. A gas sensor for measuring a concentration of a predetermined gas component in a measurement gas, comprising:
a sensor element mainly made of an oxygen-ion conductive solid electrolyte;
at least one external electrode provided on said sensor element and containing a Pt—Au alloy;
an insulating layer formed on said sensor element and separated from said at least one external electrode;
an electrode evaporation preventing film laminated on said insulating layer and separated from said at least one external electrode, and made of Au or a Pt—Au alloy having an Au composition ratio not smaller than an Au composition ratio of the Pt—Au alloy contained in said at least one external electrode; and
a protection cover provided so that at least part of said sensor element is positioned inside said protection cover and said measurement gas is introduced inside said protection cover, said at least one external electrode and said electrode evaporation preventing film being provided on said at least part of said sensor element.

2. The gas sensor according to claim 1 , wherein said electrode evaporation preventing film is made of Au or a Pt—Au alloy having an Au composition ratio larger than the Au composition ratio of said at least one external electrode by 20 wt. % or more.

3. The gas sensor according to claim 1 , wherein said insulating layer and said at least one external electrode are formed on an identical surface of said sensor element.

4. The gas sensor according to claim 3 , further comprising an insulating porous protective layer covering said electrode evaporation preventing film and said at least one external electrode.

5. The gas sensor according to claim 1 , further comprising a porous protective layer covering said at least one external electrode, wherein said electrode evaporation preventing film is laminated on said protective layer.

6. The gas sensor according to claim 1 , further including:
a reference electrode is formed of a cermet of Pt and an oxygen-ion conductive solid electrolyte,
said at least one external electrode is a sensing electrode formed of a cermet of a Pt—Au alloy and an oxygen-ion conductive solid electrolyte, and
said gas sensor is configured to determine the concentration of said predetermined gas component based on a potential difference between said sensing electrode and said reference electrode.

7. The gas sensor according to claim 2 , further including:
a reference electrode is formed of a cermet of Pt and an oxygen-ion conductive solid electrolyte,
said at least one external electrode is a sensing electrode formed of a cermet of a Pt—Au alloy and an oxygen-ion conductive solid electrolyte, and
said gas sensor is configured to determine the concentration of said predetermined gas component based on a potential difference between said sensing electrode and said reference electrode.

8. The gas sensor according to claim 3 , further including:
a reference electrode is formed of a cermet of Pt and an oxygen-ion conductive solid electrolyte,
said at least one external electrode is a sensing electrode formed of a cermet of a Pt—Au alloy and an oxygen-ion conductive solid electrolyte, and
said gas sensor is configured to determine the concentration of said predetermined gas component based on a potential difference between said sensing electrode and said reference electrode.

9. The gas sensor according to claim 4 , further including:
a reference electrode is formed of a cermet of Pt and an oxygen-ion conductive solid electrolyte,
said at least one external electrode is a sensing electrode formed of a cermet of a Pt—Au alloy and an oxygen-ion conductive solid electrolyte, and
said gas sensor is configured to determine the concentration of said predetermined gas component based on a potential difference between said sensing electrode and said reference electrode.

10. The gas sensor according to claim 5 , further including:
a reference electrode is formed of a cermet of Pt and an oxygen-ion conductive solid electrolyte,
said at least one external electrode is a sensing electrode formed of a cermet of a Pt—Au alloy and an oxygen-ion conductive solid electrolyte, and
said gas sensor is configured to determine the concentration of said predetermined gas component based on a potential difference between said sensing electrode and said reference electrode.

Assignees

• Ngk Insulators Ltd

Inventors

• Okamoto Taku
• Nakayama Yuki
• Hirata Noriko

Classifications

• G01N27/4075 Primary

  Composition or fabrication of the electrodes and coatings thereon, e.g. catalysts · CPC title

• G01N27/4071

  using sensor elements of laminated structure · CPC title

• G01N27/4077 Primary

  Means for protecting the electrolyte or the electrodes · CPC title

• G01N27/4076

  Reference electrodes or reference mixtures · CPC title