Water splitting method and system

Patent metadata

Field	Value
Publication number	US-10519554-B2
Application number	US-201515517738-A
Country	US
Kind code	B2
Filing date	Oct 7, 2015
Priority date	Oct 7, 2014
Publication date	Dec 31, 2019
Grant date	Dec 31, 2019

Abstract

An electrode is presented for use in an oxidation process. The electrode comprises a substrate having an electrically conductive surface carrying a chiral system. The chiral system is configured for controlling spin of electrons transferred between the substrate and electrolyte during the oxidation process.

First claim

The invention claimed is:

1. A water splitting system comprising at least one electrochemical cell comprising an anode electrode and a cathode electrode, connectable to each other, to be immersed in an electrolyte for use in an oxidation process;
said cathode electrode being configured and operable to cause reduction of hydrogen ions by electrons;
wherein said anode electrode comprises a substrate having an electrically conductive surface carrying a chiral system, wherein, upon application of a potential difference between said anode electrode and said cathode electrode, said anode electrode is configured and operable to create electrons and electron holes causing oxidation of water and transfer to electrons between the electrolyte and the substrate;
wherein said chiral system causes alignment of the spin of transferred electrons released by oxygen during the oxidation of water to thereby create a spin specificity of the electrons transferred through said chiral system and decrease over potential for the oxidation process;
wherein the water splitting system is configured to cause a potential difference to be applied between the anode electrode and the cathode electrode in which the over-potential for the oxidation process is reduced due to the alignment of the spin of the electrons transferred through said chiral system.

2. The water splitting system of claim 1 , wherein said chiral system comprises at least one of organic and inorganic matter having chiral properties.

3. The water splitting system of claim 1 , wherein said chiral system comprises at least one of chiral molecules and chiral polymer.

4. The water splitting system of claim 1 , wherein said chiral system is configured as a single- or multi-layer structure.

5. The water splitting system of claim 4 , wherein said chiral system comprises a self-assembled monolayer of the chiral molecules.

6. The water splitting system of claim 1 , wherein said chiral system includes at least one of the following: oligopeptides, amino acids, DNA, helicenes, and chiral conductive polymer.

7. The water splitting system of claim 1 , wherein said chiral system is either chemically bound to said electrically conductive surface of the substrate or physically adsorbed on it.

8. The water splitting system of claim 1 , wherein said substrate is made of at least one metal or semiconductor.

9. The water splitting system of claim 1 , wherein said anode electrode is configured as a photoabsorber.

10. The water splitting system of claim 9 , wherein said substrate is configured as a photoabsorber.

11. The water splitting system of claim 9 , further comprising at least one layer of photoabsorber carried by the substrate.

12. The water splitting system of claim 9 , wherein said chiral system comprises at least one layer of photoabsorber having chiral properties.

13. The water splitting system of claim 9 , comprising photoabsorbing nanoparticles bound to the substrate via said chiral system.

14. A water splitting method comprising: operating the electrochemical cell of the water splitting system of claim 1 to cause oxidation of water at the anode electrode of the electrochemical cell, while aligning spins of electrons released by oxygen during said oxidation.

15. The method of claim 14 , wherein said aligning of the spins of electrons is performed by using the chiral system in the electrochemical cell.

16. The method of claim 15 , wherein said operating of the electrochemical cell comprises: excitation of the anode resulting in the formation of electrons and electron holes causing the oxidation of water at the anode by holes and alignment of the spins of electrons by the chiral system at the anode.

17. The method of claim 16 , wherein said anode is configured as a photoabsorber, said excitation being light-induced excitation.

18. The method of claim 14 , wherein said operating of the electrochemical cell comprises application of a potential difference between the anode and cathode electrodes; transport of H+ ions from the anode to a cathode through an electrolyte and transport of electrons from the anode to the cathode through an external circuit; and reduction of hydrogen ions at the cathode by electrons to thereby produce hydrogen.

Assignees

• Yeda Res & Dev

Inventors

• Naaman Ron
• Fontanesi Claudio
• Mtangi Wilbert

Classifications

• C25B1/04 Primary

  by electrolysis of water · CPC title

• H01G9/2054

  comprising a semiconductor electrode comprising AII-BVI compounds, e.g. CdTe, CdSe, ZnTe, ZnSe, with or without impurities, e.g. doping materials (H01G9/2027 takes precedence) · CPC title

• H01G9/2031

  comprising titanium oxide, e.g. TiO2 (H01G9/2036 takes precedence) · CPC title

• Y02E60/366

  Cross-Sectional Technologies · mapped topic

• C25B11/0442

  Chemistry & Metallurgy · mapped topic