Porous oil binder and method for the production thereof

Patent metadata

Field	Value
Publication number	US-10519354-B2
Application number	US-201414915198-A
Country	US
Kind code	B2
Filing date	Aug 27, 2014
Priority date	Aug 27, 2013
Publication date	Dec 31, 2019
Grant date	Dec 31, 2019

Abstract

The invention relates to a hydrophobed porous oil binder in the form of a nonwoven fabric composed of lignocellulose-containing raw materials having a biologically functionalized surface for removing mineral-oil-based contaminants in seas, rivers, inland waters, and stormwater basins or wastewater treatment plants, wherein the density of the oil binder is 10 to 900 kg/m3, the oil binder is 1 to 25 mm thick, the broad surface of the oil binder has a dimension of 9 to 200 cm2, the porosity of the oil binder is 30 to 96%, measured with respect to the total fraction of the oil binder, and the flexural strength of the oil binder is at least 1.5 N/mm2.

First claim

What is claimed is:

1. A porous oil sorbent in the form of a nonwoven material, comprising fibres formed from lignocellulosic raw materials, wherein:
a) the density of the oil sorbent is 80 to 300 kg/m 3 ,
b) the oil sorbent is 3 to 6 mm thick, wherein thickness of the oil sorbent refers to the length of the shortest edge of the oil sorbent,
c) the large surface of the oil sorbent has a dimension of 9 to 200 cm 2 ,
d) the pore fraction of the oil sorbent is 30% to 96%, wherein the pore fraction is determined in accordance with DIN EN 310, and
e) the bending strength of the oil sorbent is at least 1.5 N/mm 2 , wherein the bending strength is determined using DIN EN 310.

2. The oil sorbent according to claim 1 , wherein the oil sorbent comprises hydrophobized fibres, wherein the fibres are hydrophobized with natural or nature-identical additives, wherein natural or nature-identical additives are paraffins, waxes, synthetic or natural latex, bark extracts, tannins or mixtures thereof.

3. The oil sorbent according to claim 1 , wherein the lignocellulosic raw materials are obtained from wood, grain, flax, rape, rice or cotton straw, coconut fibres, bagasse, bamboo, cork, seaweed, tree bark or mixtures thereof.

4. The oil sorbent according to claim 1 , wherein the lignocellulosic raw materials contained in the oil sorbent are in the form of partially degraded lignocellulosic raw materials due to thermal modification, wherein the partial degradation due to thermal modification is achieved in the absence of air and/or in a nitrogen atmosphere in an autoclave in a temperature range of 160° C. to 260° C., wherein the lignocellulosic raw materials absorbs less water due to the thermal modification.

5. The oil sorbent according to claim 1 , wherein the oil sorbent further comprises animal-based raw materials in a proportion by weight in the range 5% to 15% by weight, wherein animal-based raw materials are wool, feathers or leather, or mixtures thereof.

6. The oil sorbent according to claim 1 , wherein the fibre surface further comprises a natural or synthetic binder, wherein the natural or synthetic binder are starches, proteins, urea resins, isocyanates or mixtures thereof.

7. The oil sorbent according to claim 1 , wherein the moisture content of the oil sorbent is 5% to 20% by weight, measured as the dry matter content of the fibrous material after it has been dried to constant weight.

8. The oil sorbent according to claim 1 , wherein the surface of the fibres or the oil sorbent further comprises immobilized microorganisms, wherein oil-degrading microorganisms are immobilized by a spraying or dipping method on the surface of the fibres of the nonwoven material which has been hydrophobized.

9. The oil sorbent according to claim 8 , wherein the microorganism community consists of alkanotrophic bacteria of the genera Rhodococcus, Pseudomonas and Sphingomonas as well as phototrophic algae and cyanobacteria from the genera Microcoleus, Phormidium, Lyngbya, Oscillatoria and Anabaena.

10. The oil sorbent according to claim 1 further comprising lyophilised microorganisms or microorganisms in suspension, wherein lyophilised microorganisms or microorganisms in suspension are added during the production of the oil sorbent and/or prior to use of the oil sorbent.

Assignees

• Univ Dresden Tech
• Univ Leipzig

Inventors

• Unbehaun Holger
• Tech Soren
• Konig Swetlana
• Safonova Elena
• Wagenfuhr Andre
• Wilhelm Christian

Classifications

• Y02A20/204

  Keeping clear the surface of open water from oil spills · CPC title

• E02B15/101

  Means floating loosely on the water absorbing the oil (absorbing materials C02F) · CPC title

• C02F1/285

  using synthetic organic sorbents · CPC title

• B01J20/28054

  characterised by their surface properties or porosity · CPC title

• C02F1/681

  by addition of solid materials for removing an oily layer on water · CPC title