Process for the preparation of a graft copolymer comprising a polyolefin main chain and one or a multiple polymer side chains and the products obtained therefrom

Patent metadata

Field	Value
Publication number	US-10519267-B2
Application number	US-201515537238-A
Country	US
Kind code	B2
Filing date	Dec 17, 2015
Priority date	Dec 17, 2014
Publication date	Dec 31, 2019
Grant date	Dec 31, 2019

Abstract

The present invention relates to a cascade process for the preparation of a graft copolymer comprising a polyolefin main chain and one or a multiple polymer side chains. The process comprising step A) of copolymerizing at least one first type of olefin monomer and at least one second type of metal-pacified functionalized olefin monomer using a catalyst system to obtain a polyolefin main chain having one or multiple metal-pacified functionalized short chain branches, the catalyst system comprising: i) a metal catalyst or metal catalyst precursor comprising a metal from Group 3-10 of the IUPAC Periodic Table of elements; and ii) optionally a co-catalyst; and step B) of forming one or multiple polymer side chains on the polyolefin main chain having one or multiple metal-pacified functionalized short chain branches to obtain the graft copolymer.

First claim

The invention claimed is:

1. A process for the preparation of a graft copolymer comprising a polyolefin main chain and one or multiple polymer side chains, the process comprising the steps of:
A) copolymerizing a first type of olefin monomer and a second type of metal-pacified functionalized olefin monomer using a catalyst system to obtain a polyolefin main chain having a metal-pacified functionalized chain branch, the catalyst system comprising:
i) a metal catalyst or metal catalyst precursor comprising a metal from Group 3-10 of the IUPAC Periodic Table of elements; and
ii) optionally a co-catalyst;

B) forming a polymer side chain on the polyolefin main chain, wherein as catalytic initiators the metal-pacified functionalized chain branch on the polyolefin main chain obtained in step A) is used to obtain the graft copolymer,
wherein step B) of obtaining the graft copolymer is carried out by a combination of ROP using a type of cyclic monomer and a nucleophilic substitution reaction at a carbonyl group-containing functionality of a second polymer.

2. The process according to claim 1 , wherein the process is a single process using a series of reactors.

3. The process according to claim 1 , wherein the first type of olefin monomer is a compound according to Formula I-A:

wherein C is carbon and wherein R 1a , R 1b , R 1c , and R 1d are each independently selected from the group consisting of H or hydrocarbyl with 1 to 16 carbon atoms.

4. The process according to claim 1 , wherein the second type of metal-pacified functionalized olefin monomer is a compound according to Formula I-B:

wherein C is carbon;
wherein R 2 , R 3 , and R 4 are each independently selected from the group consisting of H or hydrocarbyl with 1 to 16 carbon atoms, and
wherein R 5 —X-ML n is a main group metal pacified heteroatom-containing functional group, wherein X is a heteroatom or a heteroatom-containing group, M is a metal, L is a ligand, and n is 0 to 3, wherein the heteroatom that is bonded to M is selected from the group consisting of O, S and N; wherein R 5 is a hydrocarbyl with 1 to 16 carbon atoms.

5. The process according to claim 1 , wherein during step B) no additional catalyst for the ROP, transesterification or nucleophilic substitution reaction is added.

6. The process according to claim 1 , wherein the metal catalyst or metal catalyst precursor used in step A) comprises a metal from Group 3-8 of the IUPAC Periodic Table of elements and/or wherein the metal catalyst or metal catalyst precursor used in step A) comprises a metal selected from the group consisting of Ti, Zr, Hf, V, Cr, Fe, Co, Ni, and Pd.

7. The process according to claim 1 , comprising the co-catalyst and wherein the co-catalyst is selected from the group consisting of MAO, DMAO, MMAO, SMAO, fluorinated aryl borane or fluorinated aryl borate.

8. The process according to claim 1 , wherein the olefin monomer according to Formula I-A is selected from the group consisting of ethylene, propylene, 1-butene, 4-methyl-1-pentene, 1-pentene, 1-hexene, 1-heptene, 1-octene, 1-nonene, 1-decene, 1-undecene, 1-dodecene, 1-tridecene, 1-tetradecene, 1-pentadecene, 1-hexadecene, 1-heptadecene, 1-octadecene, 1-cyclopentene, cyclohexene, norbornene, ethylidene-norbornene, and vinylidene-norbornene and one or more combinations thereof.

9. The process according to claim 1 , wherein the cyclic monomer used during ROP in step B) is a polar monomer, selected from the group consisting of a lactone, a lactide, a cyclic oligoester, an epoxide, an aziridine, a combination of epoxide and/or aziridine and CO 2 , a cyclic anhydride, a combination of epoxide and/or aziridine and a cyclic anhydride, a combination of epoxide and/or aziridine and CO 2 and a cyclic anhydride, a cyclic N-carboxyanhydride, a cyclic carbonate, a lactam and one or more combinations thereof, or wherein the cyclic monomer used during ROP in step B) is a nonpolar cyclic monomer having a ring size of at least 12 atoms.

10. The process according to claim 1 , wherein the polymer added during step B) to form the side chains comprising a carboxylic or carbonic acid ester functionality or a carbonyl group-containing functionality is selected from the group consisting of a polyester, a polycarbonate, a polyamide, a polyurethane, a polyurea, a random or block poly(carbonate-ester), poly(carbonate-ether), poly(ester-ether), poly(carbonate-ether-ester), poly(ester-amide), poly(ester-ether-amide), poly(carbonate-amide), poly(carbonate-ether-amide), poly(ester-urethane), poly(ester-ether-urethane), poly(carbonate-urethane), poly(carbonate-ether-urethane), poly(ester-urea), poly(ester-ether-urea), poly(carbonate-urea), poly(carbonate-ether-urea), poly(ether-amide), poly(amide-urethane), poly(amide-urea), poly(urethane-urea) or one or more combination thereof.

11. The process according to claim 1 , wherein the pacifying metal used to obtain the metal-pacified functionalized olefin monomer is selected from the group consisting of: aluminum, titanium, zinc, gallium, magnesium, calcium and one or more combinations thereof.

12. The process according to claim 9 , wherein the cyclic monomer used during ROP in step B) is a nonpolar cyclic monomer having a ring size of at least 12 atoms, selected from the group consisting of cyclic esters, cyclic carbonates, cyclic amides, cyclic urethanes and cyclic ureas; or one or more combinations thereof.

13. The process according to claim 1 , wherein the metal-pacified functionalized olefin monomer is prepared before the catalyst system is added.

14. The process according to claim 1 , wherein the metal-pacified functionalized olefin monomer is prepared by a deprotonation reaction between a protic functionalized olefin monomer according to Formula I-C below and a metal pacifying agent:

wherein, R 2 , R 3 , and R 4 are each independently selected from the group consisting of H or hydrocarbyl with 1 to 16 carbon atoms; wherein X is a heteroatom or a heteroatom-containing group, wherein the heteroatom is selected from the group consisting of O, S and N; and wherein R 5 is a hydrocarbyl with 1 to 16 carbon atoms.

15. The process according to claim 14 , wherein the metal pacifying agent has a structure of L n MR 7c p , wherein L is a ligand, M is a metal, R 7c is a hydride or hydrocarbyl with 1 to 16 carbon atoms, n is 0 to 3, and p is 1, 2 or 3.

Assignees

• Sabic Global Technologies Bv

Inventors

• Duchateau Robbert
• Bouyahyi Miloud
• Jasinska-Walc Lidia
• Goswami Partha Pratim

Classifications

• C08F2420/01

  Cp or analog bridged to a non-Cp X neutral donor · CPC title

• C08F4/6392

  containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring · CPC title

• C08G64/18

  Block or graft polymers · CPC title

• C08G63/08 Primary

  Lactones or lactides · CPC title

• C08F2410/01

  Additive used together with the catalyst, excluding compounds containing Al or B · CPC title