Process for preparing vinyl acetate-ethylene copolymers by emulsion polymerization

Patent metadata

Field	Value
Publication number	US-10519255-B2
Application number	US-201615759114-A
Country	US
Kind code	B2
Filing date	Jun 29, 2016
Priority date	Jun 29, 2016
Publication date	Dec 31, 2019
Grant date	Dec 31, 2019

Abstract

Subjects of the invention are processes for preparing vinyl acetate-ethylene copolymers in the form of their aqueous dispersions or water-redispersible powders by means of radically initiated emulsion polymerization and optional subsequent drying of the resultant polymer dispersions, characterized in that the emulsion polymerization of vinyl acetate, ethylene and optionally one or more further ethylenically unsaturated monomers is carried out in the presence of one or more protective colloids in one or more Taylor reactors.

First claim

The invention claimed is:

1. A process for preparing vinyl acetate-ethylene copolymers in the form of their aqueous dispersions or water-redispersible powders by means of radically initiated emulsion polymerization and optional subsequent drying of the resultant polymer dispersions, the process comprising emulsion polymerization of vinyl acetate, ethylene and optionally one or more further ethylenically unsaturated monomers in the presence of one or more protective colloids in one or more Taylor reactors, the Taylor reactor comprising an external reactor wall, a rotor located within the external reactor wall, a reactor base, and a reactor lid, the wall, rotor, base, and lid defining a toroidal reactor volume, wherein vinyl acetate, ethylene, protective colloids, and oxidation initiators are added via one or more metering devices that are embedded in the reactor base, and reduction initiators are added via one or more metering devices embedded in a bearing of the rotor.

2. The process according to claim 1 , wherein the external reactor wall has an inner wall and the rotor has an outer wall, the inner wall of the external reactor wall and the outer wall of the rotor each having a cylindrical geometry.

3. The process according to claim 1 , wherein the Taylor reactor is equipped with at least three metering devices.

4. The process according to claim 2 , wherein at least one metering device is mounted on the reactor base and/or at least one metering device ( 6 ) is mounted on a bearing of the rotor and/or at least one metering device is mounted in the external reactor wall.

5. The process according to claim 4 , wherein a plurality of metering devices ( 6 ) are mounted locally in succession in the external reactor wall in a flow direction.

6. The process according to claim 1 , wherein initiators and/or monomers comprising vinyl acetate and/or ethylene are added via one or more metering devices embedded in the external reactor wall.

7. The process according to claim 1 , having a pressure in the toroidal reactor volume of 10 to 90 bar abs. .

8. The process according to claim 1 , wherein residual monomer is removed by post-polymerization in a stirred tank or in the Taylor reactor.

9. The process according to claim 1 , wherein: vinyl acetate is polymerized with 1 to 50 wt % of ethylene; vinyl acetate is polymerized with 1 to 50 wt % of ethylene and 1 to 50 wt % of one or more vinyl esters having 3 to 12 carbon atoms in the carboxyl radical; vinyl acetate is polymerized with 1 to 50 wt % of ethylene and 1 to 60 wt % of (meth)acrylic esters of unbranched or branched alcohols having 1 to 15 carbon atoms; 30 to 75 wt % of vinyl acetate is polymerized with 1 to 30 wt % of vinyl laurate or vinyl esters of an alpha-branched carboxylic acid having 9 to 11 carbon atoms, and also 1 to 30 wt % of (meth)acrylic esters of unbranched or branched alcohols having 1 to 15 carbon atoms and 1 to 40 wt % of ethylene; or vinyl acetate is polymerized with 1 to 50 wt % of ethylene and 1 to 60 wt % of vinyl chloride; where the figures in wt % add up to 100 wt % in each case.

10. The process according to claim 1 , wherein the protective colloids comprise partially hydrolysed or fully hydrolysed polyvinyl alcohols.

11. The process according to claim 1 , wherein the polymerization is carried out in the absence of emulsifiers.

Assignees

• Wacker Chemie Ag

Inventors

• Babar Muhammad
• Eckl Bernhard
• Hergeth Wolf-Dieter
• Weitzel Hans-Peter

Classifications

• C08F2/01

  characterised by special features of the polymerisation apparatus used · CPC title

• B01J2219/00033

  Continuous processes · CPC title

• B01J2219/1943

  cylindrical · CPC title

• B01J19/1806

  resulting in a turbulent flow of the reactants, such as in centrifugal-type reactors, or having a high Reynolds-number · CPC title

• C08F210/02

  Ethene · CPC title