Urea production method

Patent metadata

Field	Value
Publication number	US-10519103-B2
Application number	US-201615553527-A
Country	US
Kind code	B2
Filing date	Apr 1, 2016
Priority date	Apr 1, 2015
Publication date	Dec 31, 2019
Grant date	Dec 31, 2019

Abstract

The present invention is a urea production method, including: a first concentration step of concentrating an aqueous urea solution; a granulation step of producing solid urea from the concentrated urea solution generated in the first concentration step; a urea recovery step of treating exhaust gas from the granulation step and recovering urea dust in the exhaust gas to generate a recovered aqueous urea solution, the granulation step being configured so as to treat a concentrated urea solution containing an additive; and a second concentration step of concentrating the recovered aqueous urea solution as an additional concentration step, wherein the concentrated recovered urea solution generated in the second concentration step is joined to the concentrated urea solution in the downstream of the first concentration step, and an additive is added downstream of the first concentration step.

First claim

The invention claimed is:

1. A urea production method, comprising:
a first concentration step of concentrating an aqueous urea solution sent from a urea synthesis step to generate a concentrated urea solution;
a granulation step of producing solid urea from the concentrated urea solution generated in the first concentration step and discharging an exhaust gas containing urea dust;
a urea recovery step of washing the exhaust gas discharged from the granulation step with a circulating aqueous urea solution to recover urea dust in the exhaust gas, generate a recovered aqueous urea solution in which the majority of the urea dust is dissolved or absorbed, and discharge a washed exhaust gas,
an additive addition step whereby a separate additive, not generated in whole or in part by the urea recovery step, is added to the recovered aqueous urea solution, and
a second concentration step of concentrating the recovered aqueous urea solution containing the separate additive by removing at least a part of the water in the recovered aqueous urea solution to generate a concentrated recovered urea solution, wherein
the granulation step is configured to treat a concentrated urea solution containing the additive;
the separate additive is formalin or a condensation product of formaldehyde with urea and does not contain recovered urea dust, and
the concentrated recovered urea solution generated in the second concentration step is joined to the concentrated urea solution downstream of the of the first concentration step.

2. The urea production method according to claim 1 , wherein at least a part of the water removed from the recovered aqueous urea solution in the second concentration step is sent to the urea recovery step.

3. The urea production method according to claim 1 , wherein all the water removed from the recovered aqueous urea solution in the second concentration step is sent to the urea recovery step.

4. The urea production method according to claim 1 , wherein the separate additive is additionally added to the concentrated urea solution downstream of the first concentration step and upstream of the granulation step.

5. The urea production method according to claim 1 , further comprising drawing a part of the concentrated urea solution from downstream of the first concentration step before the concentrated recovered urea solution generated in the second concentration step is joined, and the rest of the concentrated urea solution is sent to the granulation step.

6. The urea production method according to claim 2 , wherein the separate additive is additionally added to the concentrated urea solution downstream of the first concentration step and upstream of the granulation step.

7. The urea production method according to claim 3 , wherein the separate additive is additionally added to the concentrated urea solution downstream of the first concentration step and upstream of the granulation step.

8. The urea production method according to claim 2 , further comprising drawing a part of the concentrated urea solution from downstream of the first concentration step before the concentrated recovered urea solution generated in the second concentration step is joined, and the rest of the concentrated urea solution is sent to the granulation step.

9. The urea production method according to claim 3 , further comprising drawing a part of the concentrated urea solution from downstream of the first concentration step before the concentrated recovered urea solution generated in the second concentration step is joined, and the rest of the concentrated urea solution is sent to the granulation step.

10. The urea production method according to claim 4 , further comprising drawing a part of the concentrated urea solution from downstream of the first concentration step before both the concentrated recovered urea solution generated in the second concentration step is joined and the additional additive is added, and the rest of the concentrated urea solution is sent to the granulation step.

11. The urea production method according to claim 6 , wherein
a part of the concentrated urea solution is drawn downstream of the first concentration step before both the concentrated recovered urea solution generated in the second concentration step is joined to the concentrated urea solution and the additional separate additive is added, and
the remainder of the concentrated urea solution is sent to the granulation step.

12. The urea production method according to claim 7 , wherein
a part of the concentrated urea solution is drawn downstream of the first concentration step before both the concentrated recovered urea solution generated in the second concentration step is joined to the concentrated urea solution and the additional separate additive is added, and
the remainder of the concentrated urea solution is sent to the granulation step.

13. The urea production method according to claim 1 , wherein an acid is added to the circulating aqueous urea solution during the urea recovery step to adjust the pH of the circulating aqueous urea solution to 2 to 6 such that the circulating aqueous urea solution recovers ammonia in a form of a salt.

14. The urea production method according to claim 1 , wherein water is obtained in the first concentration step by concentrating the aqueous urea solution and is reutilized as boiler water.

15. The urea production method according to claim 13 , wherein water is obtained in the first concentration step by concentrating the aqueous urea solution and is reutilized as boiler water.

Assignees

• Toyo Engineering Corp

Inventors

• Nakamura Shuhei
• Sasaki Keigo

Classifications

• B01J2/16

  by suspending the powder material in a gas, e.g. in fluidised beds or as a falling curtain · CPC title

• B01J2/00

  Processes or devices for granulating materials {, e.g. fertilisers} in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic · CPC title

• C07C273/14 Primary

  Separation; Purification; Stabilisation; Use of additives · CPC title

• C07C273/16 Primary

  Separation; Purification · CPC title

• B01J2/30

  using agents to prevent the granules sticking together; Rendering particulate materials free flowing in general, e.g. making them hydrophobic · CPC title