Removal of feed treatment units in aromatics complex designs

Patent metadata

Field	Value
Publication number	US-10519082-B2
Application number	US-201715825015-A
Country	US
Kind code	B2
Filing date	Nov 28, 2017
Priority date	Dec 20, 2016
Publication date	Dec 31, 2019
Grant date	Dec 31, 2019

Abstract

Processes and apparatuses for producing para-xylenes are provided. The processes comprises providing a reformate stream comprising aromatic hydrocarbons to a reformate splitter to provide a reformate bottoms stream and a reformate overhead stream. A portion of the reformate bottoms stream is passed to a para-xylene separation unit for separating para-xylene, wherein the portion of the reformate bottoms stream is passed to the para-xyelene separation unit without an intermediate step for removal of olefins.

First claim

The invention claimed is:

1. A process for the production of para-xylene, wherein the process comprises:
a) introducing a raffinate product stream comprising C 8 aromatic isomers to an isomerization unit to provide an isomerization effluent, wherein the isomerization effluent is produced in the presence of an ethylbenzene (EB) isomerization catalyst;
b) passing a portion of the isomerization effluent to a para-xylene separation unit for separating para-xylene, wherein said portion is contacted with an adsorbent under adsorption conditions to provide a xylene extract stream comprising para-xylene and the raffinate product stream; and,
c) passing the remained portion of the isomerization effluent to the isomerate stripper column to provide an isomerate stripper overhead stream comprising C 6− hydrocarbons and an isomerate stripper bottoms stream; and
d) passing the isomerate stripper bottoms stream to a naphthene splitter column to provide an overhead naphthene splitter stream comprising the C 8 naphthenes and C 7 aromatic hydrocarbons, a naphthene splitter sidedraw stream comprising the portion of the isomerization effluent that is passed to a para-xylene separation unit, and a naphthene splitter bottoms stream comprising C 8+ aromatic hydrocarbons,
wherein the naphthene splitter sidedraw stream is passed to the para-xylene separation unit without an intermediate step for removal of olefins.

2. The process of claim 1 further comprising passing the naphthene splitter bottoms stream to an aromatics rerun column to provide a net overhead rerun column stream, wherein the net overhead rerun column stream is mixed with the naphthene splitter sidedraw stream to provide the portion of the isomerization effluent being passed to the para-xylene separation unit.

3. The process of claim 1 further comprising providing a reformate stream comprising aromatic hydrocarbons to a reformate splitter to provide a reformate bottoms stream comprising C 7+ aromatic hydrocarbons and a reformate overhead stream comprising C 7− aromatic hydrocarbons.

4. The process of claim 3 further comprising passing a portion of the reformate bottom stream to the para-xylene separation unit without an intermediate step for removal of olefins.

5. The process of claim 1 , wherein the intermediate step comprises a clay treater.

6. The process of claim 1 , wherein the intermediate step comprises an olefin reduction process (ORP) unit.

7. The process of claim 1 , wherein the adsorbent is a binderless adsorbent comprising zeolite X having an average crystallite size of less than 1.8 microns.

8. The process of claim 7 , wherein the adsorbent has at least 95% of its ion-exchangeable sites exchanged with barium or a combination of barium and potassium.

9. The process of claim 1 , wherein the para-xylene separation unit is a simulated moving bed adsorption unit.

10. The process of claim 9 , wherein the para-xylene separation unit uses a desorbent with a lower boiling point than the C 8 aromatic isomers.

Assignees

• Uop Llc

Inventors

• Bjorkman Kathryn R
• Whitchurch Patrick C
• Lobo Rodrigo J
• Cheng Linda S
• Somers Susan A

Classifications

• B01D3/009

  in combination with chemical reactions · CPC title

• C07C7/13

  by molecular-sieve technique · CPC title

• C07C5/2708

  with crystalline alumino-silicates, e.g. molecular sieves · CPC title

• C07C15/073

  Ethylbenzene · CPC title

• C10G2300/1088

  Olefins · CPC title