Process for the hydrothermal treatment of high molar mass biomaterials

Patent metadata

Field	Value
Publication number	US-10518245-B2
Application number	US-201314653275-A
Country	US
Kind code	B2
Filing date	Dec 18, 2013
Priority date	Dec 19, 2012
Publication date	Dec 31, 2019
Grant date	Dec 31, 2019

Abstract

The present invention concerns a process for the conversion of biomaterials into structural carbon products, particularly utilizing a hydrothermal treatment step that is carried out on a high molar mass organic starting material having a carbon content of >40 wt % of the dry matter. The invention also concerns a structural carbon product obtained using such a process, which has well-defined physico-chemical properties, e.g. in terms of surface area, carbon content, density, size and shape.

First claim

The invention claimed is:

1. A process for the conversion of raw biomaterial into structural carbon products or their aggregates, comprising:
prior to a pressurized hydrothermal treatment step, separating an organic starting material having a dry matter carbon content of >40 wt % from the raw biomaterial; and
utilizing solely the organic starting material having a dry matter carbon content of >40 wt % from the separating step, subjecting the organic starting material to the pressurized hydrothermal treatment step to provide the structural carbon products or their aggregates, wherein the pressurized hydrothermal treatment step is done at a temperature of from 80 to 600° C. and at a pressure of >1 bar.

2. The process according to claim 1 , wherein the starting material comprises a dry matter carbon content of from 40 wt % to 60 wt %.

3. The process according to claim 1 , wherein the starting material is extracted from wooden raw materials.

4. The process according to claim 1 , wherein the pressurized hydrothermal treatment step is carried out at a temperature of from 150 to 400° C.

5. The process according to claim 1 , wherein the pressurized hydrothermal treatment step is carried out at a pressure of >10 bar.

6. The process according to claim 1 , wherein the pressurized hydrothermal treatment step is done at a temperature of 80 to 250° C.

7. The process according to claim 1 , wherein the pressurized hydrothermal treatment step converts the starting material into carbon black.

8. The process according to claim 1 , wherein the pressurized hydrothermal treatment step is done at a temperature of 200° C. to 400° C.

9. The process according to claim 1 , wherein the pressurized hydrothermal treatment step converts the starting material into active carbon.

10. The process according to claim 1 , wherein the pressurized hydrothermal treatment step is carried out for a time period of ≥1 h.

11. The process according to claim 1 , wherein the separating step provides a reaction mixture, and further comprising grinding the reaction mixture to provide carbon particles in the organic starting material having a structured surface.

12. The process according to claim 1 , wherein the extracting comprises ultrafiltration of the raw biomaterial to obtain the organic starting material.

13. The process according to claim 1 , wherein a catalyst or a mixture of catalysts is added to the structural carbon products or their aggregates, wherein the catalyst(s) is/are selected from the group of metal nanoparticles.

14. The process according to claim 1 , wherein the separating comprises dissolving or dispersing the raw material into a solution to provide the organic starting material with a dry matter carbon content of >40 wt %.

Assignees

• Teknologian Tutkimuskeskus Vtt Oy
• Valmet Technologies Oy

Inventors

• Grönberg Vidar
• Wikberg Hanne
• Hentze Hans-Peter
• Harlin Ali
• Jääskeläinen Anna-Stiina

Classifications

• C01B32/318

  characterised by the starting materials · CPC title

• C10L5/442

  Wood or forestry waste · CPC title

• C01P2006/80

  Compositional purity · CPC title

• C01P2006/10

  Solid density · CPC title

• C01P2006/14

  Pore volume · CPC title