Vanadium corrosion inhibitors in gas turbine applications

Patent metadata

Field	Value
Publication number	US-10513665-B2
Application number	US-201815987532-A
Country	US
Kind code	B2
Filing date	May 23, 2018
Priority date	Apr 19, 2016
Publication date	Dec 24, 2019
Grant date	Dec 24, 2019

Abstract

The present embodiments describe a method to reduce vanadium corrosion in a gas turbine by adding an oleophilic corrosion inhibitor into a combustion fuel, in which the oleophilic corrosion inhibitor comprises carbon black support particles and magnesium bonded to the carbon black support particles. The carbon black support particles comprise a particle size less than 40 nanometer (nm), and oxygen content less than 1 weight percent (wt %), and a surface area of at least 50 square meters per gram (m2/gram).

First claim

I claim:

1. A method of reducing vanadium corrosion in a gas turbine comprising:
adding an oleophilic corrosion inhibitor into a combustion fuel, in which the oleophilic corrosion inhibitor comprises magnesium chemically bonded to carbon black support particles;
allowing the combustion fuel to combust in the gas turbine; and
reducing vanadium corrosion in the gas turbine.

2. The method of claim 1 , further comprising mixing the oleophilic corrosion inhibitor and the combustion fuel.

3. The method of claim 1 , further comprising mixing the oleophilic corrosion inhibitor with liquid fuel solvent.

4. The method of claim 1 , in which:
the magnesium comprises magnesium oxide; and
the oleophilic corrosion inhibitor is added in an amount such that an amount of magnesium oxide is greater than an amount of vanadium in the gas turbine.

5. The method of claim 1 , in which the combustion fuel comprises liquid oil.

6. The method of claim 1 , in which the magnesium comprises at least one of magnesium oxide and elemental magnesium.

7. The method of claim 1 , in which the magnesium comprises from 0.05 to 20 weight percent magnesium oxide.

8. The method of claim 1 , in which the carbon black support particles comprise acetylene black.

9. The method of claim 1 , in which the carbon black support particles comprise a particle size of less than 20 nm.

10. The method of claim 1 , in which the carbon black support particles comprise an ash content of less than 0.5 weight percent.

11. The method of claim 1 , in which the carbon black support particles comprise a surface area of from 50 m 2 /gram to 100 m 2 /gram.

12. The method of claim 1 , in which the magnesium is attached to the carbon black support particles.

13. The method of claim 1 , in which the carbon black support particles comprise:
a particle size of less than 40 nm;
an oxygen content of less than 1 weight percent; and
a surface area of at least 50 m 2 /gram.

Assignees

• Saudi Arabian Oil Co

Inventors

• Choi Ki-Hyouk

Classifications

• C10L1/12

  Inorganic compounds · CPC title

• F05D2260/95

  Preventing corrosion · CPC title

• C08K2003/222

  Magnesia, i.e. magnesium oxide · CPC title

• C10L2290/24

  Mixing, stirring of fuel components · CPC title

• F02C3/30

  Adding water, steam or other fluids {for influencing combustion, e.g. to obtain cleaner exhaust gases (F02C7/141, F02C7/30, F01D21/00, F01K21/04, F23D11/10 take precedence)} · CPC title