Non-dusting effect pigment preparation

Patent metadata

Field	Value
Publication number	US-10513615-B2
Application number	US-201916273672-A
Country	US
Kind code	B2
Filing date	Feb 12, 2019
Priority date	Aug 22, 2016
Publication date	Dec 24, 2019
Grant date	Dec 24, 2019

Abstract

A pigment pellet preparation, comprises one or more effect pigment and one or more thermosetting resin. The effect pigment is dispersed in the thermosetting resin. The thermosetting resin has 3 or more reactive terminal groups and has an acid number from about 10 to about 50 mg KOH/g resin. The preparation comprises from about 70% to about 90% by weight of one or more effect pigment and from about 5% to about 35% by weight of one or more thermosetting resin. The pigment and thermosetting resin comprise about 95% or more of the preparation. The pellets have a diameter of about 0.5 mm to about 5 mm and a length of about 1 mm to about 5 cm.

First claim

What is claimed is:

1. A pigment pellet preparation comprising an effect pigment material dispersed in a thermosetting resin material, wherein the effect pigment material comprises one or more effect pigment and the thermosetting resin material comprises one or more thermosetting resin,
wherein the one or more thermosetting resin has 3 or more reactive terminal groups and the thermosetting resin material has an acid number from about 10 to about 50 mg KOH/g resin,
wherein the preparation comprises from about 70% to about 90% by weight of the one or more effect pigment,
wherein the preparation comprises from about 5% to about 30% by weight of the one or more thermosetting resin,
wherein the preparation comprises the effect pigment material and thermosetting resin material in a combined amount of about 95% or more by weight, and
wherein the pellets have a diameter of about 0.5 mm to about 5 mm and a length of about 1 mm to about 5 cm.

2. The preparation of claim 1 , wherein the thermosetting resin material has a T g of about 55° C. or higher.

3. The preparation of claim 1 , wherein the thermosetting resin material comprises at least one oligomer selected from polyesters, epoxies, acrylics, polyurethane, polyester/epoxy hybrids, and combinations thereof.

4. The preparation of claim 1 , wherein the pigment pellet preparation is friable.

5. The preparation of claim 1 , wherein the effect pigment material is selected from metallic pigments, pearlescent pigments, and combinations thereof.

6. The preparation of claim 5 , wherein the pearlescent pigment comprises at least one transparent, non-metallic, platelet-shaped substrate that is at least partially coated with one or more layers comprising a metal oxide having refractive indices.

7. The preparation of claim 6 , wherein the pearlescent pigment comprises a layer selected from the group of silicon dioxide, titanium dioxide, zinc oxide, zirconium dioxide, tin oxide, cerium dioxide, vanadium (IV) oxide, manganese oxide, lead oxide, chromium oxide, iron oxide, aluminum oxide, tungsten oxide, hydrated oxides of any one of the aforementioned oxides, doped oxides of any one of the aforementioned oxides, and mixtures and alloys thereof.

8. The preparation of claim 5 , wherein the metallic pigment is selected from aluminum, zinc, copper, zinc-copper alloy, magnesium, chromium, silver, iron, gold, platinum, copper-silver alloy, silver coated copper, copper coated silver, silver coated aluminum, and mixtures and alloys thereof.

9. The preparation of claim 8 , wherein the metallic pigment further comprises a lubricant selected from saturated or unsaturated fatty acids, fatty amines, fatty-alcohols, fatty thiols, and combinations thereof.

10. The preparation of claim 8 , wherein the metallic pigment comprises a coating of metal oxide selected from silicon dioxide, titanium dioxide, zinc oxide, zirconium dioxide, tin oxide, cerium dioxide, vanadium (IV) oxide, manganese oxide, lead oxide, chromium oxide, iron oxide, aluminum oxide, tungsten oxide, hydrated oxides of any one of the aforementioned oxides, and combinations thereof.

11. The preparation of claim 1 , wherein the effect pigment material is at least partially coated with a bonding agent that comprises at least two reactive groups.

12. The preparation of claim 11 , wherein the bonding agent comprises at least one of acrylic acid, phosphate ester, and silane.

13. The preparation of claim 1 , further comprising one or more additives.

14. A method for making the pigment pellet preparation of claim 1 comprising forming a paste by mixing the effect pigment material with the thermosetting resin material at a temperature of about 100° C. or higher and pressing the resulting paste through a screen to form pellets.

15. A powder coating composition comprising the preparation of claim 1 and one or more crosslinker.

16. The powder coating of claim 15 , additionally comprising one or more flow agent, degassing agent, light stabilizer, anti-oxidants, dispersant, charge control agents, antistatic, anti-caking additive, mar-resistance additive, texturizing additive, gloss control additive, catalyst, pigment, filler, and combinations thereof.

17. A method for making a powder coating comprising the steps of:
a) extruding a mixture of a crosslinker and resin to produce an extruded ribbon,
b) grinding the extruded ribbon, and
c) bond or dryblend,
wherein the pigment pellet preparation of claim 1 is added at step b), c), or both.

18. The method of claim 17 , wherein the mixture of step a) further comprises one or more additive selected from crosslinking agents, flow control additives, antioxidants, degassing additives, light stabilizers, UV absorbers, dispersants, lubricants, charge control additives, anti-caking additives, mar resistance additives, texturizing additives, gloss control additives, catalysts, tougheners, antibacterial additives, adhesion promoters, sealants, anti-condensation additives, IR reflectors, organic pigments, inorganic pigments, tillers, and combinations thereof.

19. A method for making a powder coating composition comprising mixing the pigment pellet preparation of claim 1 with a crosslinker and resin, wherein the mixing step is selected from extrusion, grinding, dry blending, bonding, and combinations thereof.

Assignees

• Sun Chemical Corp

Inventors

• Doll Jonathan
• Johnson Steven
• Miller Christopher

Classifications

• C09C1/646

  concomitant with mechanical comminution, shaping or abrasion of the particles · CPC title

• C09C1/64

  Aluminium · CPC title

• C09C1/0015

  Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings · CPC title

• C08J2375/04

  Polyurethanes · CPC title

• C09D5/032

  characterised by a special effect of the produced film, e.g. wrinkle, pearlescence, matt finish · CPC title