Sulfonate-modified polyamide having improved barrier properties

Patent metadata

Field	Value
Publication number	US-10513581-B2
Application number	US-201113700629-A
Country	US
Kind code	B2
Filing date	May 19, 2011
Priority date	May 28, 2010
Publication date	Dec 24, 2019
Grant date	Dec 24, 2019

Abstract

The use of a polyamide modified by sulfonate functions which has improved barrier properties is described. Further described is the use of a sulfonate, aliphatic or aromatic compound for manufacturing a modified polyamide having improved fluid-barrier properties. The composition as described includes a modified polyamide, which is optionally a composition in the form of granules or powder used in manufacturing articles by an injection or extrusion blow-molding method.

First claim

The invention claimed is:

1. A method of improving fluid barrier properties of a fluid container, the method comprising reducing the fluid permeability of the fluid container by fabricating the fluid container from a polyamide composition comprising:
a (co)polyamide comprising at least one aliphatic monomer and optionally at least one aromatic monomer in a polymer chain, and
at least one novolac resin,
wherein the reduced fluid permeability reduces permeability of a gasoline comprising 10 volume percent ethanol, 45% iso-octane, and 45% toluene,
wherein the fluid container is a tube, pipe, or tank intended to contain or transport a fluid,
wherein said (co)polyamide is modified by a sulfonate compound, in an amount of from 5 to 10 mol percent sulfonate unit relative to the total number of moles of units constituting the polymer chain,
wherein the resulting fluid container has reduced fluid permeability to the gasoline when compared with a corresponding fluid container made with a (co)polyamide which is not modified with the sulfonate compound,
wherein the (co)polyamide is a semi-crystalline (co)polyamide,
wherein the modified (co)polyamide is in a composition comprising 30% to 95% by weight of said (co)polyamide, relative to the total weight of the composition, and
wherein the modified (co)polyamide comprises a polyamide selected from the group consisting of a polyamide 6, a polyamide 66, a polyamide 10, a polyamide 11, a polyamide 610, a polyamide 1010, a polyamide 12, a polyamide 6I, a copolyamide 66/6T, a copolyamide 66/6I, a copolyamide 6T/MT, and a copolyamide 6T/6I.

2. The method as described in claim 1 , wherein the sulfonate compound comprises as least one SO 3 X function, wherein SO 3 X represents SO 3 H or SO 3 M; M being a substituent that replaces the SO 3 H proton H + to form an inactive salified group.

3. The method as described in claim 1 , wherein the sulfonate compound is an aromatic sulfonate compound.

4. The method as described in claim 1 , wherein the sulfonate compound is bound chemically to a polyamide chain to form a covalent bond through a function of said sulfonate compound that can react with the amine or carboxylic functions in the polyamide monomers, wherein the function of the sulfonate compound is selected from the group consisting of an amine, a carboxylic acid, an aldehyde, an anhydride, a hydroxyl, a ketone function and their derivatives.

5. The method as described in claim 1 , wherein the sulfonate compound is placed in a polymer chain of the (co)polyamide or at the end of the polyamide chain.

6. The method as described in claim 1 , wherein the sulfonate compound is represented by the general formula (I):
(Z) n —Y—(SO 3 X) m   (I)

in which:
SO 3 X represents SO 3 H or SO 3 M, M being a substituent that replaces the SO 3 H proton H + to form an inactive salified group;
m is from 1 to 10;
Y is a hydrogen substituent comprising from 2 to 100 carbon atoms, linear or cyclic, aromatic or aliphatic and that can comprise heteroatoms;
Z is a function that can react with amine or carboxylic acid functions in the polyamide monomers; and
n is from 1 to 10.

7. The method as described in claim 1 , wherein the sulfonate compound is selected from the group consisting of: a sodium 5-sulfoisophthalic acid, a lithium 5-sulfoisophthalic acid, a sodium-4-carboxybenzene sulfonate, a sodium-3-carboxybenzene sulfonate, a sodium-2-carboxybenzene sulfonate, a lithium-3-carboxybenzene sulfonate, a potassium-3-carboxybenzene sulfonate, a sodium-3-carbomethoxybenzene sulfonate, a potassium-2-carbopropoxybenezene sulfonate, a sodium-2-carbomethoxyethylbenzene sulfonate, a potassium-3-aminomethylbenzene sulfonate, a sodium-2-aminoethylbenzene sulfonate and a potassium-3-aminopropylbenzene sulfonate.

8. The method as described in claim 1 , wherein the modified (co)polyamide is in a composition comprising 40% to 80% by weight of said (co)polyamide, relative to the total weight of the composition.

9. The method as described in claim 1 , wherein the modified (co)polyamide is comprised of a composition comprising an agent modifying impact strength.

10. The method as described in claim 1 , wherein the modified (co)polyamide is comprised of a deposited composition or is associated with another substrate.

11. The method as described in claim 1 , wherein the fluid container having reduced fluid permeability is a multilayer article.

12. A method of improving gasoline barrier properties of a gasoline container, the method comprising reducing the gasoline permeability of the gasoline container by fabricating the gasoline container from a (co)polyamide comprising at least one aliphatic monomer and optionally at least one aromatic monomer in a polymer chain, and at least one novolac resin,
wherein the reduced gasoline permeability reduces permeability of a gasoline comprising 10 volume percent ethanol, 45% iso-octane, and 45% toluene,
wherein the gasoline container is a tube, pipe, or tank intended to contain or transport a gasoline intended to contain or transport a fluid,
wherein the (co)polyamide is modified by a sulfonate compound, in an amount of from 5 to 10 mol percent sulfonate unit relative to the total number of moles of units constituting the polymer chain,
wherein the (co)polyamide is semi-crystalline (co)polyamide,
wherein the modified (co)polyamide is in a composition comprising 30% to 95% by weight of said (co)polyamide, relative to the total weight of the composition,
wherein the modified (co)polyamide comprises a polyamide selected form the group consisting of a polyamide 6, a polyamide 66, a polyamide 10, a polyamide 11, a polyamide 610, a polyamide 1010, a polyamide 12, a polyamide 6I, a copolyamide 66/6T, a copolyamide 66/6I, a copolyamide 6T/MT, and a copolyamide 6T/6I, and
wherein the resulting gasoline container has reduced gasoline permeability to wherein the gasoline when compared with a corresponding gasoline container made with a (co)polyamide which is not modified with the sulfonate compound.

13. A method of fabricating a gasoline container with improved gasoline barrier properties, the method comprising:
modifying a (co)polyamide with a sulfonate compound;
wherein the modified (co)polyamide is in a composition comprising 30% to 95% by weight of said (co)polyamide, relative to the total weight of the composition;
wherein the modified (co)polyamide comprises a polyamide selected form the group consisting of a polyamide 6, a polyamide 66, a polyamide 10, a polyamide 11, a polyamide 610, a polyamide 1010, a polyamide 12, a polyamide 6I, a copolyamide 66/6T, a copolyamide 66/6I, a copolyamide 6T/MT, and a copolyamide 6T/6I, and
molding the modified (co)polyamide into an article selected from the group consisting of a tube, a pipe, and a tank intended to contain or transport a fluid;
wherein the container comprises at least one novolac resin;
wherein the (co)polyamide is a semi-crystalline (co)polyamide;
wherein the (co)polyamide comprises at least one aliphatic monomer and optionally at least one aromatic monomer in a polymer chain;
wherein said (co) polyamide is modified by the sulfonate compound in an amount of from 5 to 10 mol percent sulfonate unit relative to the total number of moles of units constituting the polymer chain;
wherein the improved gasoline barrier properties reduces permeability of a gasoline comprising 10 volume percent ethanol, 45% iso-octane, and 45% toluene; and
wherein the resulting container has reduced fluid permeability to the gasoline when compared with a corresponding container made with a (co)polyamide which is not modified with the sulfonate compound.

Assignees

• Jeol Stephane
• Fillot Louise Anne
• Rhodia Operations

Inventors

• Jeol Stéphane
• Fillot Louise-Anne

Classifications

• F16L9/12

  of plastics with or without reinforcement (F16L9/16 - F16L9/22 take precedence) · CPC title

• C08L61/04

  Condensation polymers of aldehydes or ketones with phenols only · CPC title

• F16L11/04

  made of rubber or flexible plastics · CPC title

• C08L23/26

  modified by chemical after-treatment (saponified copolymers C08L23/0861; unsaturated acid salts C08L23/0876) · CPC title

• C08L77/06

  Polyamides derived from polyamines and polycarboxylic acids (C08L77/10 takes precedence) · CPC title