Plastic film and a method for manufacturing same

Patent metadata

Field	Value
Publication number	US-10508183-B2
Application number	US-201515508862-A
Country	US
Kind code	B2
Filing date	Sep 16, 2015
Priority date	Sep 18, 2014
Publication date	Dec 17, 2019
Grant date	Dec 17, 2019

Abstract

The present invention relates to a plastic film and a method for manufacturing same. A plastic film, which is formed such that at least one part has a curved shape, can have high hardness, impact resistance, scratch resistance and high transparency. The plastic film is light and will not be easily damaged by external pressure and thus can substitute for the existing glass and is expected to be used for various electronic products such as a display and the like. In particular, the plastic film has at least one part in a curved shape and thereby is expected to be used for products in various shapes which cannot be manufactured by means of the existing glass. Moreover, a method for manufacturing a plastic film enables manufacturing of a plastic film having at least one part in a curved shape without curls or cracks as well as simultaneous performing of heat molding and heat curing, thereby increasing the productivity of a plastic film.

First claim

The invention claimed is:

1. A plastic film of at least partially curved shape, comprising:
a substrate,
a coating layer formed on one side of the substrate, said coating layer comprising (i) cationically curable resin, which is a cured product of cationically curable compounds comprising, based on the total weight of the cationically curable compounds, 60 wt % to 100 wt % of 3,4,3′,4′-diepoxybicyclohexyl, and (ii) radically curable resin, and
a coating layer formed on the other side of the substrate, said coating layer comprising (i) cationically curable resin, which is a cured product of cationically curable compounds comprising, based on the total weight of the cationically curable compounds, 20 wt % to 100 wt % of 3,4,3′,4′-diepoxybicyclohexyl, (ii) radically curable resin, and (iii) elastic polymer.

2. The plastic film according to claim 1 , wherein the glass transition temperature of the substrate is 80 to 250° C.

3. The plastic film according to claim 1 , wherein the cationically curable resin is a cured product obtained by heat curing of cationically curable compounds by a cationic polymerization initiator comprising a cation of Chemical Formula 1:
R 1 -A 1 R 2 ] k   [Chemical Formula 1]

in Chemical Formula 1,
A 1 is N, P or S,
R 1 is a C1-20 alkyl or a C2-20 alkenyl radical,
R 2 is a C1-20 alkyl, a C2-20 alkenyl, a C6-30 aryl, a C7-35 alkylaryl or a C7-35 arylalkyl, or a radical in which a hydroxyl, a C1-20 alkyl, a C2-20 alkenyl, a C6-30 aryl, a C7-35 alkylaryl, or a C7-35 arylalkyl is linked to the above radical by a single bond, —O—, —S—, —CO—, —COO— or —OCO—, and
k is 2 or 3.

4. The plastic film according to claim 1 , wherein the radically curable resin is a cured product of multifunctional acrylate.

5. The plastic film according to claim 4 , wherein the multifunctional acrylate comprises one or more selected from the group consisting of hexanediol diacrylate, hexanediol dimethacrylate, tripropyleneglycol diacrylate, tripropyleneglycol dimethacrylate, ethyleneglycol diacrylate, ethyleneglycol dimethacrylate, trimethylolpropane triacrylate, trimethylolpropane trimethacrylate, trimethylolpropane ethoxylate triacrylate, glycerin propoxylate triacrylate, pentaerythritol triacrylate, pentaerythritol trimethacrylate, pentaerythritol tetraacrylate, pentaerythritol tetramethacrylate, dipentaerythritol hexaacrylate and dipentaerythritol hexamethacrylate.

6. The plastic film according to claim 1 , wherein pencil hardness of the coating layer under a load of 1.0 kg is 4H or more, when the thickness of the coating layer is 100 μm.

7. The plastic film according to claim 1 , wherein haze of the coating layer is 1% or less, when the thickness of the coating layer is 100 μm.

8. The plastic film according to claim 1 , wherein the plastic film has a shape in which, among four edges, two facing edges are curved, a shape in which all four edges are curved, or a generally curved shape.

9. The plastic film according to claim 1 , wherein the plastic film is used instead of glass.

Assignees

• Lg Chemical Ltd

Inventors

• Lee Han Na
• Kim Young Suk
• Chang Yeong Rae
• Kim Heon
• Jung Soon Hwa
• Byun Jin Seok

Classifications

• C08F222/104

  of tetraalcohols, e.g. pentaerythritol tetra(meth)acrylate · CPC title

• C08J7/0427

  with only one layer of a composition containing a polymer binder (with more layers C08J7/042) · CPC title

• C08L63/00

  Compositions of epoxy resins; Compositions of derivatives of epoxy resins · CPC title

• B05D2701/00

  Coatings being able to withstand changes in the shape of the substrate or to withstand welding · CPC title

• C09D4/00

  Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond {; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16} · CPC title