Method for continuously producing cellulose ether

Patent metadata

Field	Value
Publication number	US-10508155-B2
Application number	US-201514858575-A
Country	US
Kind code	B2
Filing date	Sep 18, 2015
Priority date	Sep 22, 2014
Publication date	Dec 17, 2019
Grant date	Dec 17, 2019

Abstract

Provided is a method for efficiently and continuously producing a cellulose ether containing a reduced amount of indissoluble component. Specifically, the method includes a contact step of bringing pulp into contact with an alkali metal hydroxide solution in the presence of a heat removal solvent to obtain alkali cellulose; a reaction step of subjecting the alkali cellulose to a reaction with an etherifying agent; a partial condensation step, after completion of the reaction, of partially condensing a gas present in a reaction vessel used for the reaction to separate the gas into gas and liquid components for returning some or all of the gas component to the contact step for reuse as some or all of the heat removal solvent; and a step of incinerating the liquid component and, when all of the gas component is not returned to the contact step, the remainder of the gas component.

First claim

The invention claimed is:

1. A method for continuously producing a cellulose ether, the method comprising:
a contact step of bringing pulp into contact with an alkali metal hydroxide solution in the presence of dimethyl ether as a heat removal solvent to obtain alkali cellulose;
a reaction step of subjecting the alkali cellulose to a reaction with an etherifying agent to obtain cellulose ether;
a partial condensation step, after completion of the reaction, of partially condensing a gas present in a reaction vessel used for the reaction with a partial condenser to separate the gas into a gas component and a liquid component containing 20 to 60% by weight of water for returning some or all of the gas component to the contact step for reuse as some or all of the heat removal solvent; and
an incineration step of incinerating the liquid component and any remainder of the gas component that has not been returned to the contact step.

2. The method for continuously producing a cellulose ether according to claim 1 , further comprising a storage step of storing the liquid component before incinerating the liquid component.

3. The method for continuously producing a cellulose ether according to claim 1 , wherein the cellulose ether is selected from the group consisting of an alkyl cellulose, a hydroxyalkyl cellulose and a hydroxyalkyl alkyl cellulose.

4. The method for continuously producing a cellulose ether according to claim 1 , wherein the liquid component is selected from the group consisting of methanol and alkylene glycols.

5. The method for continuously producing a cellulose ether according to claim 1 , wherein the gas component comprises dimethyl ether and at least one compound selected from the group consisting of methyl chloride, propylene oxide and ethylene oxide.

6. The method for continuously producing a cellulose ether according to claim 1 , wherein a weight ratio of alkali metal hydroxide to solid component in the pulp (alkali metal hydroxide/solid component in pulp) is about 0.3 to 3.0.

7. The method for continuously producing a cellulose ether according to claim 1 , further comprising washing the cellulose ether with hot water at 80 to 100° C.

8. The method for continuously producing a cellulose ether according to claim 7 , further comprising drying the cellulose ether after washing.

9. The method for continuously producing a cellulose ether according to claim 8 , further comprising pulverizing the cellulose ether after drying.

10. The method for continuously producing a cellulose ether according to claim 1 , wherein the partial condensation step is performed at a pressure from about 0 to 2.0 MPa and a temperature from about 10 to 40° C.

Assignees

• Shinetsu Chemical Co

Inventors

• Yamamoto Atsushi
• Kurotani Shinichi
• Yonemochi Atsuhiko
• Narita Mitsuo

Classifications

• C08B1/08

  Alkali cellulose · CPC title

• C08H8/00

  Macromolecular compounds derived from lignocellulosic materials {(pretreatment thereof B27N)} · CPC title

• Y02P20/582

  Recycling of unreacted starting or intermediate materials · CPC title

• C08B11/02 Primary

  Alkyl or cycloalkyl ethers · CPC title

• C08B11/08

  with hydroxylated hydrocarbon radicals; Esters, ethers, or acetals thereof · CPC title