Process for the preparation of perfluoroalkylcyano- or perfluoroalkylcyanofluoroborates
US-9175021-B2 · Nov 3, 2015 · US
US10508068B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10508068-B2 |
| Application number | US-201615540135-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 13, 2016 |
| Priority date | Jan 19, 2015 |
| Publication date | Dec 17, 2019 |
| Grant date | Dec 17, 2019 |
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A method for producing a thermodynamically more stable clathrate compound including at least one compound selected from the group consisting of 1,1,2,2-tetrakis(4-hydroxyphenyl)ethane, 5-hydroxyisophthalic acid, and 5-nitroisophthalic acid as a host compound and an imidazole compound as a guest compound. The method for producing a clathrate compound includes: a mixing step of mixing a mixed solvent including a protic solvent, at least one compound selected from the group consisting of 1,1,2,2-tetrakis(4-hydroxyphenyl)ethane, 5-hydroxyisophthalic acid and 5-nitroisophthalic acid, and an imidazole compound; and a heating step.
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The invention claimed is: 1. A method for producing a thermodynamically stable crystal of a clathrate compound, comprising a mixing step of mixing the following component (A), component (B), and component (C); and a heating step: (A): a mixed solvent comprising a first solvent which is at least one solvent selected from the group consisting of water and methanol; and a second solvent which is at least one solvent selected from the group consisting of ethyl acetate, hexane, methyl ethyl ketone, and methanol, the second solvent being a solvent different from the first solvent, (B): at least one compound selected from the group consisting of 1,1,2,2-tetrakis(4-hydroxyphenyl)ethane and 5-hydroxyisophthalic acid, (C): at least one compound selected from the group consisting of 2-phenyl-4-methyl-5-hydroxymethylimidazole and 2-ethyl-4-methylimidazole. 2. A method for producing a thermodynamically stable crystal of a clathrate compound which is different from (D) by crystal transformation comprising a mixing step of mixing the following component (A) and component (D); and a heating step: (A): a mixed solvent comprising a first solvent which is at least one solvent selected from the group consisting of water and methanol; and a second solvent which is at least one solvent selected from the group consisting of ethyl acetate, hexane, methyl ethyl ketone, and methanol, the second solvent being a solvent different from the first solvent, (D): a clathrate compound comprising at least one compound selected from the group consisting of 1,1,2,2-tetrakis(4-hydroxyphenyl)ethane, and 5-hydroxyisophthalic acid and at least one compound selected from the group consisting of 2-phenyl-4-methyl-5-hydroxymethylimidazole and 2-ethyl-4-methylimidazole.
Phenols · CPC title
Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring · CPC title
with substituted hydrocarbon radicals attached to ring carbon atoms, e.g. histidine · CPC title
with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring nitrogen atoms · CPC title
with all hydroxy groups on non-condensed rings {, e.g. phenylphenol} · CPC title
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