Process for oligomerizing gasoline without further upgrading

Patent metadata

Field	Value
Publication number	US-10508064-B2
Application number	US-201314074747-A
Country	US
Kind code	B2
Filing date	Nov 8, 2013
Priority date	Nov 12, 2012
Publication date	Dec 17, 2019
Grant date	Dec 17, 2019

Abstract

Oligomerizing C 4 and C 5 olefins over a SPA catalyst provides an oligomerate product stream comprising C 6 + olefins that meets a gasoline T-90 specification of 380° F. The oligomerate product stream can be taken to the gasoline pool without further upgrading.

First claim

The invention claimed is:

1. A process for making gasoline from light olefins comprising:
oligomerizing C 4 and C 5 olefins in an olefinic oligomerization feed stream comprising C 4 and C 5 hydrocarbons in an oligomerization reactor operating in a liquid phase over a solid phosphoric acid catalyst at a temperature between 170° C. and about 250° C. to produce an oligomerate stream comprising heavier olefins;
separating said oligomerate stream in a debutanizer column to provide an overhead light stream comprising C 4 hydrocarbons and an oligomerate bottom stream comprising C 5+ hydrocarbons, the overhead pressure in the debutanizer column being between about 300 and about 350 kPa (gauge) and the bottom temperature being between about 250° C. and about 300° C.;
separating said oligomerate bottom stream in a depentanizer column into an overhead intermediate stream comprising C 5 hydrocarbons and a liquid oligomerate bottom stream comprising C 6+ hydrocarbons wherein said liquid oligomerate bottom stream comprises less than 20 wt % C 12+ olefins and wherein over 85 wt % of said C 4 and C 5 olefins in said olefinic oligomerization feed stream oligomerize, the overhead pressure in the depentanzier column being between about 10 and about 60 kPa (gauge) and the bottom temperature being between about 225° C. and about 275° C.;
recycling said overhead intermediate stream to the oligomerization reactor; and
sending said liquid oligomerate bottom stream to a gasoline tank or a gasoline blending line without further separation, wherein said liquid oligomerate bottom stream meets the T90 gasoline specification without further separation.

2. The process of claim 1 further comprising purging said overhead light stream from the process.

3. The process of claim 1 further comprising separating a portion of said overhead intermediate stream into a purge stream and purging said purge stream from the process.

4. The process of claim 1 wherein over about 90 wt % of the C 5 olefins in the oligomerization feed oligomerize.

5. The process of claim 1 wherein over about 90 wt % of the C 4 olefins in the oligomerization feed oligomerize.

6. The process of claim 1 further comprising subjecting said olefinic oligomerization feed stream to a selective hydrogenation process prior to the step of oligomerizing C 4 and C 5 olefins.

7. The process of claim 1 further comprising passing the liquid oligomerate bottom stream to a saturation unit to saturate the C 6 + hydrocarbons prior to sending said liquid oligomerate bottom stream to the gasoline tank or the gasoline blending line.

8. The process of claim 1 further comprising:
condensing said overhead intermediate stream before recycling said overhead intermediate stream.

9. A process for making gasoline from light olefins comprising:
oligomerizing C 4 and C 5 olefins in an olefinic oligomerization feed stream comprising C 4 and C 5 hydrocarbons in an oligomerization reactor operating in a liquid phase with a solid phosphoric acid catalyst at a temperature between 170° C. and about 250° C. to produce an oligomerate stream comprising heavier olefins;
separating said oligomerate stream in a debutanizer column to provide an overhead light stream comprising C 4 hydrocarbons and an oligomerate bottom stream comprising C 5+ hydrocarbons, the overhead pressure in the debutanizer column being between about 300 and about 350 kPa (gauge) and the bottom temperature being between about 250° C. and about 300° C.;
separting said oligomerate bottom stream in a depentanizer column into an overhead intermediate stream comprising C 5 hydrocarbons and a liquid oligomerate bottom stream comprising C 6 + hydrocarbons wherein said liquid oligomerate bottom stream comprises less than 20 wt % C 12+ olefins and wherein over 85 wt % of said C 4 and C 5 olefins in said olefinic oligomerization feed stream oligomerize, the overhead pressure in the depentanizer column being between about 10 and about 60 kPa (gauge) and the bottom temperature being between about 225° C. and about 275° C.;
sending said liquid oligomerate bottom stream to a gasoline tank or a gasoline blending line without further separation, wherein said liquid oligomerate bottom stream meets the T90 gasoline specification without further sepraration;
separating said overhead intermediate stream into a C 5 purge stream and a C 5 recycle stream and purging said C 5 purge stream from the process and recycling said C 5 recycle stream to the oligomerization reactor; and
condensing said overhead intermediate stream before separating said overhead intermediate stream or condensing said C 5 recycle stream.

10. The process of claim 9 further comprising purging said overhead light stream from the process.

11. The process of claim 9 wherein over about 90 wt % of the C 5 olefins in the oligomerization feed oligomerize.

12. The process of claim 9 wherein over about 90 wt % of the C 4 olefins in the oligomerization feed oligomerize.

13. The process of claim 9 further comprising subjecting said olefinic oligomerization feed stream to a selective hydrogenation process prior to the oligomerization step.

14. The process of claim 9 further comprising passing the liquid oligomerate bottom stream to a saturation unit to saturate the C 6 + hydrocarbons prior to sending said liquid oligomerate bottom stream to the gasoline tank or the gasoline blending line.

15. A process for making gasoline from light olefins comprising:
oligomerizing C 4 and C 5 olefins with an olefinic oligomerization feed stream comprising C 4 and C 5 hydrocarbons hydrocarbons in an oligomerization reactor operating in a liquid phase with a solid phosphoric acid catalyst at a temperature between 170° C. and about 250° C. to produce an oligomerate stream comprising heavier olefins; wherein at least about 40 wt-% of the pentene in the oligomerization feed stream is normal pentene;
separating said oligomerate stream in a debutanizer column to provide an overhead light stream comprising C 4 hydrocarbons and an oligomerate bottom stream comprising C 5+ hydrocarbons, the overhead pressure in the debutanizer column being between about 300 and about 350 kPa (gauge) and the bottom temperature being between about 250° C. and about 300° C.;
separating said oligomerate bottom stream in a depentanizer column into an overhead intermediate stream comprising C 5 hydrocarbons and a liquid oligomerate bottom stream comprising C 6+ hydrocarbons wherein said liquid oligomerate bottom stream comprises less than 20 wt % C 12+ olefins and wherein over 85 wt % of said C 4 and C 5 olefins in said olefinic oligomerization feed stream oligomerizer, the overhead pressure in the depentanizer column being between about 10 and about 60 kPa (gauge) and the bottom temperature being between about 225° C. and about 275° C.;
recycling said overhead intermediate stream to the oligomerization reactor; and
sending said liquid oligomerate bottom stream to a gasoline tank or a gasoline blending line without further separation; wherein said liquid oligomerate bottom stream meets the T90 gasoline specification without further separation.

16. The process of claim 15 further comprising purging said overhead light stream from the process.

17. The process of claim 15 further comprising separating a portion of said intermediate stream into a C 5 purge stream and purging said C 5 purge stream from the process.

18. The process of claim 15 further comprising passing the liquid oligomerate bottom stream to a saturation unit to saturate the C 6

Assignees

• Uop Llc

Inventors

• Nicholas Christopher P
• Freet Christian D
• Krupa Steven L
• Vanden Bussche Kurt M
• Kruse Todd M

Classifications

• C10L1/04

  essentially based on blends of hydrocarbons · CPC title

• C07C2529/70

  of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 · CPC title

• C07C2/12

  with crystalline alumino-silicates {or with catalysts comprising} molecular sieves · CPC title

• C07C2/18 Primary

  Acids of phosphorus; Salts thereof; Phosphorus oxides · CPC title

• C07C5/03

  of non-aromatic carbon-to-carbon double bonds · CPC title