Hydrotreating catalyst and process for preparing the same

Patent metadata

Field	Value
Publication number	US-10507458-B2
Application number	US-201314417290-A
Country	US
Kind code	B2
Filing date	Aug 29, 2013
Priority date	Aug 29, 2012
Publication date	Dec 17, 2019
Grant date	Dec 17, 2019

Abstract

The current invention provides a hydrotreating catalyst comprising of metals of at least one each from Group VIB, preferably molybdenum and Group VIII, preferably nickel, of the periodic table supported on alumina modified with small amounts of modifying elements well dispersed on the surface so as to retain the physico-chemical characteristics of the support and result in high performance for hydrodesulphurization catalyst, and a commercially viable process for producing such a catalyst. The present invention also discloses a commercially viable method for modifying alumina in the powder form without affecting the porous structure of the support obtained.

First claim

What claimed is:

1. A process for preparing a hydro treatment catalyst comprising an inorganic oxide material based carrier, a group VI B metal and a group VIII metal adsorbed to the carrier, wherein the inorganic oxide material based carrier comprises alumina matrix and a modifying element grafted to the alumina matrix, and the modifying element being present in an amount in the range of 0.01 to 2% of a total weight of the inorganic oxide material based carrier, said process comprising the steps of:
a. preparing a solution comprising a modifying element additive;
b. adding alumina powder to the aforesaid solution to obtain alumina matrix comprising modifying element grafted to surface of alumina;
c. filtering the alumina matrix and washing the same to remove non-grafted modifying element additive;
d. mixing the alumina matrix with a binder to obtain a homogenous dough;
e. extruding the dough to form a solid material;
f. drying, ageing and calcining the solid material to obtain the inorganic oxide material based carrier comprising alumina matrix and the modifying element grafted to the alumina matrix; and
g. impregnating a solution of group VI B metal and a group VIII metal to the inorganic oxide material based carrier to obtain the hydro treatment catalyst;
wherein the group VI B metal is an oxide of molybdenum and the group VIII metal is an oxide of nickel or cobalt or mixture thereof;
wherein the modifying element is selected from a group consisting of boron, aluminium, silicon, titanium, cerium and mixtures thereof; and
wherein said impregnating solution is reacted with 0.01-1 moles of a suitable amine compound per mole of Mo selected from the group of compounds consisting of monoethanol amine, diethanol amine and diethyl amine.

2. The process as claimed in claim 1 , wherein the modifying element additive is an organic compound having an organic moiety and the modifying element, the organic moiety having affinity to hydroxyl groups.

3. The process as claimed in claim 1 , wherein the modifying element being present in an amount in the range of 0.05 to 1% the percentage being on the basis of a total weight of the inorganic oxide material based carrier.

4. The process as claimed in claim 1 , wherein the group VIII metal is present in an amount in the range of 1 to 5%.

5. The process as claimed in claim 1 , wherein the group VI B metal is present in an amount in the range of 10 to 25%.

6. The method of claim 1 , wherein the hydro treatment catalyst obtained is incorporated with additional organic additive from the group of compounds consisting of diethylene glycol, triethylene glycol, polyethylene glycol as stabilizer to an impregnating solution of group VI B metal and a group VIII metal on the modified support.

7. The method of claim 1 , wherein the hydro treatment catalyst further comprising formation of nano-scale dispersion of MoS2 clusters having cluster length of less than 5 nm.

8. The method of claim 1 , wherein the hydro treatment catalyst obtained exhibits hydrodesulfurization activity suitable for desulfurization of gas oil feeds with more than 1.0% wt S to ultra-low sulfur levels (<50 ppmw).

Assignees

• Indian Oil Corp Ltd

Inventors

• Xavier Kochappilly Ouseph
• Pulikottil Alex Cheru
• Kuvettu Mohan Prabhu
• Kumar Brijesh
• Rajagopal Santanam
• Malhotra Ravinder Kumar

Classifications

• B01J37/0207

  Pretreatment of the support · CPC title

• B01J27/051

  Molybdenum · CPC title

• B01J37/009

  Preparation by separation, e.g. by filtration, decantation, screening · CPC title

• B01J27/19 Primary

  Molybdenum · CPC title

• B01J21/063

  Titanium; Oxides or hydroxides thereof · CPC title