Method for producing an alloy for a reforming tube

Patent metadata

Field	Value
Publication number	US-10501831-B2
Application number	US-201515517405-A
Country	US
Kind code	B2
Filing date	Sep 16, 2015
Priority date	Oct 8, 2014
Publication date	Dec 10, 2019
Grant date	Dec 10, 2019

Abstract

The invention relates to a microstructure of an alloy for a tube for reformers, having an austenitic matrix structure, characterised in that: i) primary micrometric precipitates in the form of M 23 C 6 -type carbides, where M=Fe, Ni or Cr, and/or M(C,N)-type carbides, where M==Nb or Ti, are formed during the solidification of the alloy; ii) secondary nanometric precipitates in the form of M 23 C 6 -type carbides, where M=Fe, Ni or Cr and/or M(C,N)-type carbides, where M==Nb or Ti, are formed during the activation of the tube; and iii) between 0.1 and 0.3% of Ni 16 Si7Nb 6 -type intermetallic precipitates is formed during the use of the tube.

First claim

The invention claimed is:

1. A process for the manufacture of an alloy of iron, nickel and chromium, for a tube of reformers, comprising from 22 to 30% by weight of Cr, from 20 to 45% by weight of Ni and from 0.3 to 0.6% by weight of C and exhibiting a microstructure with an austenitic matrix such that:
i) micrometric primary precipitates in the form of carbides of M 23 C 6 type with M=Fe, Ni or Cr and/or of M(C,N) type with M=Nb or Ti are formed during the solidification of the alloy;
ii) nanometric secondary precipitates in the form of carbides of M 23 C 6 type with M=Fe, Ni or Cr and of M(C,N) type with M=Nb or Ti are formed during the bringing into service of the tube; and
iii) an amount of intermetallic precipitates of Ni 16 Si 7 Nb 6 type of between 0.1 and 0.3% is formed during the use of the tube,
the process comprising a heat treatment of said alloy carried out in two stages:
a) a first stage of heat treatment at temperatures between 700° C. and 800° C. with a stationary phase of 10 h to 100 h, and
b) a second stage of heat treatment under operating conditions of the furnace of the reforming having as source a source of hydrocarbons and being subjected to a pressure varying between 1 and 4 MPa and a temperature between 900° C. and 1000° C.

2. The process of claim 1 , wherein the secondary precipitates form dislocation clusters.

3. The process of claim 1 , wherien the primary precipitates are micrometric.

4. The process of claim 1 , wherein the secondary precipitates are nanometric.

5. The process of claim 4 , wherein the secondary precipitates are between 5 nm and 50 nm.

6. The process of claim 1 , wherein the primary precipitates of M 23 C 6 type represents from 3 to 8% of the chemical composition of the alloy and the M(C,N) precipitates represents from 0.5 to 2.5% of the chemical composition of the alloy.

7. The process of claim 1 , wherein the secondary precipitates of M 23 C 6 type represents from 1 to 3% of the chemical composition of the alloy and the M(C,N) precipitates represents from 0.1 to 0.5% of the chemical composition of the alloy.

Assignees

• Lair Liquide Soc Pour Letude Et Lexploitation Des Procedes Georges Claude
• Air Liquide

Inventors

• Fraczkiewicz Anna
• Maminska Karolina
• Del-Gallo Pascal
• Furtado Jader
• Gary Daniel

Classifications

• C21D9/08

  for tubular bodies or pipes · CPC title

• C21D6/004

  containing Cr and Ni · CPC title

• C22C1/02 Primary

  by melting {(C22C1/1036 takes precedence)} · CPC title

• C22C38/02

  containing silicon · CPC title

• C22C30/00

  Alloys containing less than 50% by weight of each constituent · CPC title