Lubricating composition containing an oxyalkylated aromatic polyol compound

Patent metadata

Field	Value
Publication number	US-10501701-B2
Application number	US-201515532574-A
Country	US
Kind code	B2
Filing date	Dec 3, 2015
Priority date	Dec 3, 2014
Publication date	Dec 10, 2019
Grant date	Dec 10, 2019

Abstract

The disclosed technology provides a lubricating composition comprising an oil of lubricating viscosity and 0.01 wt % to 10 wt % of an oxyalkylated aromatic polyol compound, wherein the aromatic compound has at least one alkoxy group represented by —OR 1 group, R 1 is hydroxyalkyl, or a (poly)ether group, and either: at least one hydroxyl group, or at least one alkoxy group represented by OR 1 group, where R 1 is alkyl, or a (poly)ether group, or at least one oxyalkyl group represented by —OR 1 , where R 1 is hydroxyalkyl or a (poly)ether group. The disclosed technology further relates to a method of lubricating a mechanical device (such as an internal combustion engine) with the lubricating composition. The disclosed technology further relates to the use of the oxyalkylated aromatic polyol compound in the lubricating composition to a passenger car internal combustion engine at least one of (i) control of fuel economy, (ii) control of corrosion, (iii) cleanliness, and (iv) control of bore wear.

First claim

What is claimed is:

1. A lubricating composition comprising an oil of lubricating viscosity and 0.01 wt % to 10 wt % of an oxyalkylated aromatic polyol compound represented by the formula:

wherein
R 1 is —(CH 2 CHR 5 —O—) m R 6 ,
R 2 is hydrogen, a hydrocarbyl group, or —(C═O)R 4 , —(CH 2 CHR 5 —O—) m R 6 ,
n is 1 or 2,
R 3 is a hydrocarbyl group, or —(C═O)OR 4 , or —(CH 2 CHR 5 —O—) m R 6 ,
x is 1,
R 4 is a hydrocarbyl group,
R 5 is hydrogen or a hydrocarbyl group containing 1 to 32 carbon atoms, or CH 2 OR 8 ,
R 6 is hydrogen or a hydrocarbyl group, or —(C═O)R 7 ,
R 7 is a hydrocarbyl group,
R 8 is a hydrogen or a hydrocarbyl group containing 1 to 24 carbon atoms, and
m=1 to 20.

2. The composition of claim 1 , wherein R 3 is a polyisobutenyl or polyisobutylene group.

3. The composition of claim 1 , wherein R 3 is an olefin group having 6 to 36 carbon atoms.

4. The composition of claim 1 , wherein the oxyalkylated aromatic polyol compound is present in an amount ranging from 0.01 wt % to 5 wt % of the lubricating composition.

5. The composition of claim 1 , further comprising an overbased detergent is chosen from of non-sulfur containing phenates, sulfur containing phenates, sulfonates, salixarates, salicylates, and mixtures thereof.

6. The composition of claim 5 , wherein the overbased detergent is present at 3 wt % to 8 wt % of the lubricating composition.

7. The composition of claim 1 , wherein the lubricating composition is characterised as having at least one of (i) a sulfur content of 0.2 wt % to 0.4 wt % or less, (ii) a phosphorus content of 0.08 wt % to 0.15 wt %, and (iii) a sulphated ash content of 0.5 wt % to 1.5 wt % or less.

8. The composition of claim 1 , wherein the lubricating composition is characterized as having a total base number (TBN) content of at least 5 mg KOH/g.

9. A method of lubricating an internal combustion engine comprising supplying to the internal combustion engine a lubricating composition of claim 1 .

10. The method of claim 9 , wherein the internal combustion engine has a steel surface on a cylinder bore, a cylinder block, or a piston ring.

11. The method of claim 9 , wherein the internal combustion engine is a heavy duty diesel internal combustion engine.

12. The method of claim 9 , wherein the heavy duty diesel internal combustion engine has a technically permissible maximum laden mass over 3,500 kg, wherein the engine is a compression ignition engine or a positive ignition natural gas (NG) or LPG engine.

13. The method of claim 9 , wherein the internal combustion engine is a passenger car internal combustion engine (typically a gasoline or diesel passenger car internal combustion engine).

Assignees

• Lubrizol Corp

Inventors

• Salem Kamalakumari Kunchithapatham
• Moreton David J
• Fahmy Mohamed G
• Walker Gary M
• Roski James P
• Zhang Yanshi
• Cox Adam
• Barnes W Preston
• Delbridge Ewan E

Classifications

• C10N2030/45

  Ash-less or low ash content · CPC title

• C10N2030/43

  Sulfur free or low sulfur content compositions · CPC title

• C10N2030/42

  Phosphor free or low phosphor content compositions · CPC title

• C10N2030/10

  Inhibition of oxidation, e.g. anti-oxidants · CPC title

• C10N2040/255

  Gasoline engines · CPC title