Shear-stable oil compositions and processes for making the same

Patent metadata

Field	Value
Publication number	US-10501700-B2
Application number	US-201715464518-A
Country	US
Kind code	B2
Filing date	Mar 21, 2017
Priority date	Jul 20, 2016
Publication date	Dec 10, 2019
Grant date	Dec 10, 2019

Abstract

An oil composition comprising a first component having pendant groups, a second component having two or more terminal carbon chains, and optionally a third component, where a single molecule of the second component can form shearable stable structure with two molecules of the first component via van der Waals force between pendant groups and the terminal carbon chains. Shear stability of the oil can be improved if the total concentration of the heavy fraction of the shearable stable structure is controlled at a low concentration.

First claim

The invention claimed is:

1. An oil composition comprising a first component and a second component different from the first component, wherein:
the first component is a base stock comprising multiple molecules of a first type each having multiple pendant groups, where (i) the average pendant group length of the longest 5%, by mole, of the pendant groups of all of the molecules of the first type have an average pendant group length of Lpg(5%), where Lpg(5%)≥5.0; and (ii) a portion of the molecules of the first type have a number-average molecular weight greater than or equal to 20,000;
the second component comprises multiple molecules of a second type each comprising two terminal carbon chains, where (i) the number-average molecular weight of the second component is no greater than 2,000; and (ii) the two terminal carbon chains have chain lengths equal to or greater than 5.0 and do not share a common carbon atom;
a single molecule of the second type is capable of adjoining two molecules of the first type via van der Waals force between the pendant groups of the molecules of the first type and the two terminal carbon chains in the single molecule of the second type to form a first complex structure, the first complex structures comprising a first heavy fraction thereof having an equivalent number-average molecular weight of at least 45,000;
wherein the molecules of the first type comprise polyalpha-olefin (“PAO”) molecules having an average isotacticity of at least 60 mol %;
wherein the first component has a Kv(100° C.) of less than 400 cSt; and
wherein the oil composition comprises from 5 to 35 weight percent of the second component relative to the total weight of the first and second components and from 65 to 95 weight percent of the first component relative to the total weight of the first and second components.

2. The oil composition of claim 1 , wherein Lpg(5%)≥8.0.

3. The oil composition of claim 1 , wherein:
with respect to the molecules of the second type, at least two of the terminal carbon chains have chain length equal to or greater than 0.80*Lpg(5%).

4. The oil composition of claim 1 , wherein:
with respect to the molecules of the second type, at least two of the terminal carbon chains have chain length equal to or greater than 12.

5. The oil composition of claim 1 , wherein:
the molecules of the first type comprise PAO molecules having an average isotacticity of at least 90 mol %.

6. The oil composition of claim 1 , wherein:
the second component comprises an alkylated aromatic hydrocarbon base stock.

7. The oil composition of claim 1 , wherein the total maximum theoretical concentration of the first heavy fraction of the first complex structure, based on the total weight of the first component and the second component, is C11(max) wt %; and C11(max)≤20.

8. The oil composition of claim 1 , wherein the second component is selected from: esters of long-chain alkyl carboxylic acid and polyols; and esters of long-chain alkyl alcohols with polycarboxylic acid; phosphoric acid; sulfuric acids; or sulphonic acids.

9. The oil composition of claim 1 , having shear stability performances as follows:
SS20≤10%;
SS100≤5%;
SS192≤10%; and
SS192>SS100.

10. The oil composition of claim 1 , further comprising a third component differing from the first component and the second component, wherein the third component comprises multiple molecules of a third type, and individual molecules of the third type are capable of adjoining no more than one molecule of the first type via van der Waals force to form a stable complex structure.

11. The oil composition of claim 6 , wherein multiple molecules of the second type comprise two alkyl groups connected to aromatic ring(s) extending in directions that form an angle theta in the range from 120° to 180°, such that each is capable of attaching to a pendant group of two differing molecules of the first type via van der Waals force simultaneously.

12. The oil composition of claim 10 , wherein:
the molecules of the third type comprise only one or zero terminal carbon chain having a chain length equal to or greater than 5.0.

13. The oil composition of claim 10 , wherein:
the molecules of the third type comprise two carbon chains that extend in directions that form an angle theta in the range from 0° to 45° and that are incapable of attaching to pendant groups of two differing molecules of the first type via van der Waals force simultaneously substantially free of steric hindrance.

14. The oil composition of claim 10 , wherein:
the third component is an alkylated aromatic hydrocarbon base stock.

15. The oil composition of claim 10 , wherein multiple molecules of the third type comprise two alkyl groups connected to aromatic ring(s) extending in directions that form an angle theta in the range from 0° to 45°, and are incapable of attaching to pendant groups of two differing molecules of the first type simultaneously substantially free of steric hindrance.

16. The oil composition of claim 10 , wherein the third component is a lubricant additive component.

17. The oil composition of claim 10 , wherein the molecules of the third type have a number-average molecular weight of at most 2000.

18. A process for forming an oil composition having a high shear stability performance, comprising the following steps:
(I) providing a first component in an amount ranging from 65 to 95 weight percent of the oil composition relative to the total weight of the first and second components comprising multiple molecules of the first type each having multiple pendant groups, where the average pendant group length of the longest 5%, by mole, of the pendant groups of all of the molecules of the first type have an average pendant group length of Lpg(5%), where Lpg(5%)≥5.0;
wherein the first component has a Kv(100° C.) of less than 400 cSt; and
(II) providing a second component in an amount ranging from 5 to 35 weight percent of the oil composition relative to the total weight of the first and second components comprising multiple molecules of the second type each comprising at least two terminal carbon chains that do not share a common carbon atom, wherein at least two of the terminal carbon chains have chain lengths equal to or greater than 5.0; a single molecule of the second type is capable of adjoining two molecules of the first type via van der Waals force to form a first complex structure, the first complex structures comprising a first heavy fraction thereof having equivalent number-average molecular weight of at least 45,000.

19. The process of claim 18 , further comprising:
(III) mixing the first component in a first quantity and the second component in a second quantity such that the total maximum theoretical concentration of the first heavy fraction of the first complex structure, based on the total weight of the first component and the second component, is C11(max) wt %; and C11(max)≤20.

20. The process of claim 19 , wherein the two terminal carbon chains in the molecules of the second type extend in directions that form an angle theta no greater than 180° when the molecules of the second type are in lowest energy state at 25° C., and C11(max)×tan(theta/4)≤10.

21. The process of claim 19 , further comprising:
(IV) providing a third component differing from the first component, wherein the third component comprises multiple molecules of the third type, and an individual molecule of the third type is capable of adjoining no more than one molecule of the first t

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Han Wenning W
• Pafford Bernie J

Classifications

• C10N2030/68

  Shear stability · CPC title

• C10N2020/04

  Molecular weight; Molecular weight distribution · CPC title

• C10N2040/04

  Oil-bath; Gear-boxes; Automatic transmissions; Traction drives · CPC title

• C10M2205/028

  containing aliphatic monomers having more than four carbon atoms · CPC title

• C10M2207/283

  of polyhydroxy compounds · CPC title