Flame-retardant polycarbonate-polyester compositions

Patent metadata

Field	Value
Publication number	US-10501624-B2
Application number	US-201515736136-A
Country	US
Kind code	B2
Filing date	Jun 18, 2015
Priority date	Jun 18, 2015
Publication date	Dec 10, 2019
Grant date	Dec 10, 2019

Abstract

Compositions comprising
A) at least one polymer selected from the group consisting of aromatic polycarbonate and aromatic polyestercarbonate, B) at least one polyester, wherein the polyester is derived from succinic acid and optionally further dicarboxylic acids and aliphatic, cycloaliphatic, araliphatic diols or aromatic diols, C) at least one cyclic phosphazene of structure (IV)

wherein
R is in each case identical or different and represents
an amine radical, in each case optionally halogenated C 1 - to C 8 -alkyl, C 1 - to C 8 -alkoxy in each case optionally alkyl- and/or halogen-substituted C 5 - to C 6 -cycloalkyl, in each case optionally alkyl- and/or halogen- and/or hydroxyl-substituted C 6 - to C 20 -aryloxy, in each case optionally alkyl- and/or halogen- and/or bromine-substituted C 7 - to C 12 -aralkyl, a halogen radical or an OH radical,

k is a whole number from 1 to 10

D) optionally graft polymer,
E) optionally vinyl (co)polymer and/or polyalkylene terephthalate,
F) optionally additives

and also the use of these flame-retarded polycarbonate/polyester compositions for producing molded articles and the molded articles themselves, wherein the polyester in the composition can be obtained or prepared preferably from renewable raw materials.

First claim

The invention claimed is:

1. A composition comprising
A) at least one polymer selected from the group consisting of aromatic polycarbonate and aromatic polyestercarbonate,
B) at least one polyester, wherein the polyester is derived from succinic acid and butanediol,
C) at least one cyclic phosphazene of structure (IV)

wherein
R is in each case identical or different and represents
an amine radical,
in each case optionally halogenated C 1 - to C 8 -alkyl,
C 1 - to C 8 -alkoxy
in each case optionally alkyl- and/or halogen-substituted C 5 - to C 6 -cycloalkyl,
in each case optionally alkyl- and/or halogen- and/or hydroxyl-substituted C 6 - to C 20 -aryloxy,
in each case optionally alkyl- and/or halogen- and/or bromine-substituted C 7 - to C 12 -aralkyl,
a halogen radical or
an OH radical,
k is a whole number from 1 to 10,

D) optionally graft polymer,
E) optionally vinyl (co)polymer and/or polyalkylene terephthalate, and
F) optionally additives.

2. The composition as claimed in claim 1 , wherein the proportions of the components are as follows
A) 40 to 98 parts by weight,
B) 1 to 60 parts by weight,
C) 1 to 20 parts by weight,
D) 0 to 20 parts by weight,
E) 0 to 20 parts by weight,
F) 0 to 30 parts by weight,
and wherein the sum of the parts by weight of the composition is normalized to 100.

3. The composition as claimed in claim 1 , wherein the proportions of the components are as follows
A) 50 to 85 parts by weight,
B) 5 to 45 parts by weight,
C) 3 to 12 parts by weight,
D) 0 to 10 parts by weight,
E) 0 to 10 parts by weight,
F) 0.2 to 10 parts by weight,
and wherein the sum of the parts by weight of the composition is normalized to 100.

4. The composition as claimed in claim 1 , wherein k is a whole number from 1 to 5.

5. The composition as claimed in claim 1 , wherein the proportion of the trimers (k=1) is from 50 to 98 mol % of the component C.

6. The composition as claimed in claim 1 , wherein the proportion of the trimers (k=1) is from 70 to 85 mol % of the component C.

7. The composition as claimed in claim 1 , wherein the component C is selected from the group consisting of propoxyphosphazenes, phenoxyphosphazenes, methylphenoxyphosphazenes, aminophosphazenes and fluoroalkylphosphazenes.

8. The composition as claimed in claim 1 , wherein the weight-average molecular weights Mw of component B are between 40 and 500 kg/mol, determined by gel permeation chromatography against a polystyrene reference.

9. The composition as claimed in claim 1 , wherein component F is at least one additive selected from the group consisting of flame retardant synergists, anti-dripping agents, lubricants and mold release agents, nucleating agents, stabilizers, antistats, dyes, pigments, fillers and reinforcing agents.

10. The composition as claimed in claim 1 , wherein the acid component of the polyester originates from renewable raw materials.

11. A process for producing injection-molded or thermoformed molded articles which comprises utilizing the composition as claimed in claim 1 .

12. A molded article obtainable from the composition as claimed in claim 1 .

13. A composition consisting of
A) 50 to 85 parts by weight of at least one polymer selected from the group consisting of aromatic polycarbonate and aromatic polyestercarbonate,
B) 5 to 45 parts by weight of at least one polyester, wherein the polyester is derived from succinic acid and butanediol, and optionally contains a coupling agent,
C) 3 to 12 parts by weight of a compound selected from the group consisting of propoxyphosphazenes, phenoxyphosphazenes, methylphenoxyphosphazenes, aminophosphazenes and fluoroalkylphosphazenes,
D) 0 to 10 parts by weight of graft polymer,
E) 0 to 10 parts by weight of vinyl (co)polymer and/or polyalkylene terephthalate, and
F) 0.2 to 10 parts by weight of additives.

14. The composition of claim 13 , wherein component C is phenoxyphosphazene having a trimer proportion (k=1) of 65 to 85 mol %, a tetramer proportion (k=2) of 10 to 20 mol %, a proportion of higher oligomeric phosphazenes (k=3, 4, 5, 6 and 7) of 5 to 20 mol % and phosphazene oligomers with k>=8 of 0 to 2 mol % based on component C.

15. The composition of claim 14 , wherein the molecular weight of component B is between 80 and 400 kg/mol.

16. The composition of claim 13 , wherein the composition is free from vinyl (co)polymers and polyalkylene terephthalates.

17. The composition of claim 14 , wherein the coupling agent is hexamethylene diisocyanate os isophorone diisocyanate.

Assignees

• Covestro Deutschland Ag

Inventors

• Jung Mathieu
• Hufen Ralf
• Eckel Thomas

Classifications

• C08L27/12

  containing fluorine atoms · CPC title

• C08L51/04

  grafted on to rubbers · CPC title

• C08L69/00 Primary

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title

• C08L67/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds (C08L67/06 takes precedence) · CPC title

• C08K5/0075

  Antistatics · CPC title