Curable composition for sound barrier film

Patent metadata

Field	Value
Publication number	US-10501612-B2
Application number	US-201615571086-A
Country	US
Kind code	B2
Filing date	May 3, 2016
Priority date	May 5, 2015
Publication date	Dec 10, 2019
Grant date	Dec 10, 2019

Abstract

A curable composition is provided comprising a curable rubber comprising: a) 80.0-99.9 wt % of a chloroprene resin; b) 0.06-13 wt % of trimethyl thiourea; and c) 0.06-13 wt % of a benzothiazolesulfenamide, such as N-cyclohexyl-2-benzothiazoles-ulfenamide. The present disclosure additionally provides cured compositions comprising a rubber comprising a crosslinked chloroprene resin and a fire retardant particle system comprising: d) 5-95 wt % particulate magnesium hydroxide (Mg(OH) 2 ); and e) 5-95 wt % particulate aluminum trihydrate (Al(OH) 3 ). In some embodiments the particulate aluminum trihydrate (Al(OH) 3 ) has a mean particle size of greater than 30 microns and less than 400 microns, and more typically a mean particle size of greater than 82 microns. The present disclosure additionally provides sound barrier films comprising the cured compositions according to the present disclosure, in particular fire resistant sound barrier films.

First claim

We claim:

1. A curable composition comprising a curable rubber comprising:
a) 80.0-99.9 wt % of a chloroprene resin;
b) 0.06-13 wt % of trimethyl thiourea; and
c) 0.06-13 wt % of a benzothiazolesulfenamide, based on the overall weight of the curable rubber, the curable composition additionally comprising a fire retardant particle system comprising:
d) 5-95 wt % particulate magnesium hydroxide (Mg(OH) 2 ); and
e) 5-95 wt % particulate aluminum trihydrate (Al(OH) 3 ), based on the overall weight of the fire retardant particle system, wherein the particulate aluminum trihydrate (Al(OH) 3 ) has a mean particle size of greater than 30 microns.

2. The curable composition according to claim 1 wherein the benzothiazolesulfenamide is N-alkyl-2-benzothiazolesulfenamide, wherein the alkyl group contains 2-10 carbon atoms and is straight, branched, or cyclic.

3. The curable composition according to claim 1 wherein the benzothiazolesulfenamide is N-cyclohexyl-2-benzothiazolesulfenamide.

4. The curable composition according to claim 1 wherein the particulate aluminum trihydrate (Al(OH) 3 ) has a mean particle size of less than 400 microns.

5. The curable composition according to claim 1 wherein the particulate aluminum trihydrate (Al(OH) 3 ) has a mean particle size of greater than 82 microns.

6. A film comprising the curable composition according to claim 1 having a thickness of less than 1300 microns and greater than 135 microns.

7. A lined film comprising the film according to claim 6 borne on a liner, wherein the liner comprises high density paper having an areal density of more than 100 g/m 2 , a clay coating on a film-supporting face of the paper, and a silicone top coating on a reverse face of the paper.

8. A cured composition resulting from the cure of the curable composition according to claim 1 .

9. A method of making a sound barrier film comprising the step of curing the lined film according to claim 7 while the film is borne on said liner.

10. A cured composition comprising a rubber comprising a crosslinked chloroprene resin and a fire retardant particle system comprising:
d) 5-95 wt % particulate magnesium hydroxide (Mg(OH) 2 ); and
e) 5-95 wt % particulate aluminum trihydrate (Al(OH) 3 ), wherein the particulate aluminum trihydrate (Al(OH)) has a mean particle size of greater than 30 microns.

11. The cured composition according to claim 10 wherein the particulate aluminum trihydrate (Al(OH) 3 ) has a mean particle size of less than 400 microns.

12. The cured composition according to claim 10 wherein the particulate aluminum trihydrate (Al(OH) 3 ) has a mean particle size of greater than 82 microns.

13. A sound barrier film comprising the cured composition according to claim 9 having a thickness of less than 1300 microns and greater than 135 microns.

14. The sound barrier film according to claim 13 which is fire resistant to the extent that it passes the test specified on the filing date of this application in Appendix F, part VI, of US Federal Aviation Regulations § 25.856(a).

Assignees

• 3M Innovative Properties Co

Inventors

• Wu Pingfan
• Chen Lianzhou
• Vance Fredrick W
• Cole Edward E
• Hedley Charles W
• Simon Gregory L
• Martin Michael C

Classifications

• C08J5/18

  Manufacture of films or sheets · CPC title

• C08K2201/005

  Additives being defined by their particle size in general · CPC title

• C08K2003/2224

  Magnesium hydroxide · CPC title

• G10K11/162

  Selection of materials · CPC title

• C08K5/44

  Sulfenamides · CPC title