Polyphase biodegradable compositions containing at least one polymer of vegetable origin

Patent metadata

Field	Value
Publication number	US-10501607-B2
Application number	US-201815866917-A
Country	US
Kind code	B2
Filing date	Jan 10, 2018
Priority date	Aug 6, 2010
Publication date	Dec 10, 2019
Grant date	Dec 10, 2019

Abstract

Polyphase biodegradable compositions having a good resistance to ageing comprising a continuous phase comprising at least one hydrophobic polyester and at least one dispersed phase of polymer of vegetable origin. The hydrophobic polyester constituting the continuous phase is incompatible with the polymer of vegetable origin. The compositions comprise a plasticiser comprising at least 75% of a mixture of diglycerol, triglycerol and tetraglycerol.

First claim

The invention claimed is:

1. A film produced from a polyphase biodegradable composition having good resistance to ageing comprising:
a) 45-98% by weight, with respect to the sum of components (a) and (b), of a continuous phase comprising at least one hydrophobic polyester,
b) 2-55% by weight, with respect to the sum of components (a) and (b), of at least one dispersed phase comprising at least one polymer of vegetable origin,
said composition further comprising a further dispersed phase comprising 1-40% by weight, with respect to the total weight of the composition, of at least a polylactic acid which is rigid in comparison with the hydrophobic polyester forming the continuous phase, with a Young's modulus of more than at least 300%,
wherein:
the hydrophobic polyester is an aliphatic-aromatic polyester of the diacids-diol type having an aromatic part comprising polyfunctional aromatic acids selected from dicarboxylic aromatic compounds of the phthalic acid type and their esters and heterocyclic dicarboxylic aromatic acids, and an aliphatic part consisting of aliphatic dicarboxylic acids and aliphatic diols, said polyester having an aromatic acids content of from 30% to 90% by moles, with respect to the acid component, and
the polymer of vegetable origin is starch,

the composition exhibits an Elmendorf tear strength of more than 60 N/mm in the transverse direction upon filming,
said composition comprising 5-50% by weight, with respect to the weight of the polymer of vegetable origin, of a plasticizer comprising at least 75% by weight, with respect to the total weight of said plasticizer, of a mixture of diglycerol, triglycerol and tetraglycerol.

2. The film according to claim 1 , wherein said hydrophobic polyester is biodegradable according to standard EN 13432.

3. The film according to claim 1 , wherein said starch is flour, natural starch, chemically and/or physically modified starch, hydrolysed starch, destructured starch, gelatinised starch, plasticised starch, thermoplastic starch or mixtures thereof.

4. The film according to claim 1 , wherein said polylactic acid contains at least 75% of L-lactic or D-lactic acid or combinations thereof having a molecular weight Mw of more than 70,000 and a Young's modulus of more than 1,500 MPa.

5. The film according to claim 1 , wherein said plasticizer comprises at least 90% of a mixture of diglycerol, triglycerol and tetraglycerol.

6. The film according to claim 5 , wherein said mixture comprises more than 50% by weight of diglycerol with respect to the sum of the di-, tri- and tetraglycerol.

7. The film according to claim 5 , wherein said diglycerol comprises at least 70% by weight of alpha-alpha diglycerol.

8. A bag or envelope produced using the film according to claim 1 , selected from the group consisting of extruded and thermoformed bags and envelopes, laminated with board, aluminium, plastics or bioplastics, and multiply perforated bags and envelopes.

Assignees

• Novamont Spa

Inventors

• Capuzzi Luigi

Classifications

• C08K2201/014

  Additives containing two or more different additives of the same subgroup in C08K · CPC title

• C08L67/03

  the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings · CPC title

• C08L67/04

  Polyesters derived from hydroxycarboxylic acids, e.g. lactones (C08L67/06 takes precedence) · CPC title

• C08L3/02 Primary

  Starch; Degradation products thereof, e.g. dextrin · CPC title

• C08K5/06

  Ethers; Acetals; Ketals; Ortho-esters · CPC title