Production method of alpha-olefin low polymer and production apparatus

Patent metadata

Field	Value
Publication number	US-10501566-B2
Application number	US-201715715545-A
Country	US
Kind code	B2
Filing date	Sep 26, 2017
Priority date	Sep 28, 2015
Publication date	Dec 10, 2019
Grant date	Dec 10, 2019

Abstract

The present invention relates to a method and an apparatus for producing an α-olefin low polymer by subjecting an α-olefin to low polymerization reaction in the presence of a catalyst in a liquid phase part within a reactor, and the present invention relates to a method and an apparatus for producing an α-olefin low polymer, such as 1-hexene, etc., by subjecting an α-olefin, such as ethylene, etc., to low polymerization reaction, in which the formation of a polymer on an upper tube plate surface of a shell and tube type heat exchanger that is used for heat removal is suppressed, thereby performing a continuous operation stably over a long period of time.

First claim

The invention claimed is:

1. A method for oligomerizing at least one α-olefin and concurrently spraying atomized droplets in a shell and tube heat exchanger that is operatively coupled with the oligomerizing, the method comprising:
oligomerizing the α-olefin in an oligomerization reactor in the presence of a catalyst to produce at least one α-olefin oligomer, wherein the reactor comprises a gas phase and a liquid phase;
withdrawing a portion of the gas from the gas phase of the oligomerization reactor;
introducing the withdrawn gas through a gas supply port into the shell and tube heat exchanger, wherein the introduced gas has a density of 20 kg/m 3 or more, and the gas flow rate of the introduced gas from the gas supply port is 1 m/s or more;
cooling the introduced gas in the shell and tube heat exchanger to obtain a condensed liquid;
recycling a portion of the condensed liquid into the reactor; and
supplying into the shell and tube heat exchanger atomized droplets of a portion of the condensed liquid, of a liquefied α-olefin, and/or of a circulation solvent from the bottom of a downstream separation column,
wherein:
the shell and tube heat exchanger comprises jet nozzles for supplying the atomized droplets between the gas supply port and a tube plate disposed in a horizontally opposite direction to the gas supply port in the shell and tube heat exchanger;
five or more of the jet nozzles are provided per 1.00 m 2 of an area of the tube plate; and
the jet nozzles include at least one nozzle that is inclined toward the gas supply port from the horizontal direction.

2. The method according to claim 1 , wherein the atomized droplets comprise the condensed liquid.

3. The method according to claim 1 , wherein a Sauter mean diameter of the atomized droplets is 3 mm or less.

4. The method according to claim 1 , wherein the jet nozzles comprise a spray nozzle.

5. The method according to claim 1 , wherein the α-olefin is ethylene.

6. The method according to claim 1 , wherein the jet nozzles comprise a full cone spray nozzle.

7. The method according to claim 6 , wherein a spray angle of the full cone spray nozzle is 15° to 170°.

8. The method according to claim 1 , wherein the jet nozzles also include at least one radially obliquely upward nozzle, in which radially obliquely upward is relative to an axis of the tube plate.

9. The method according to claim 1 , wherein the jet nozzles include at least one vertically downward central nozzle and at least one radially obliquely downward nozzle, in which vertically downward and radially obliquely downward are relative to an axis of the tube plate.

10. The apparatus according to claim 1 , wherein the jet nozzles protrude from the top cover of the heat exchanger.

11. A method for oligomerizing at least one α-olefin and concurrently spraying atomized droplets in a heat exchanger that is operatively coupled with the oligomerizing, the method comprising:
oligomerizing the α-olefin in an oligomerization reactor in the presence of a catalyst to produce at least one α-olefin oligomer, wherein the reactor comprises a gas phase and a liquid phase;
withdrawing a portion of the gas from the gas phase of the oligomerization reactor;
introducing the withdrawn gas through a gas supply nozzle into the heat exchanger, wherein the introduced gas has a density of 20 kg/m 3 or more, and the gas flow rate of the introduced gas from the gas supply port is 1 m/s or more;
cooling the introduced gas in the heat exchanger to obtain a condensed liquid;
recycling a portion of the condensed liquid into the reactor; and
supplying into the heat exchanger atomized droplets of a portion of the condensed liquid, of a liquefied α-olefin, and/or of a circulation solvent from the bottom of a downstream separation column,
wherein:
i) the heat exchanger comprises:
a cylindrical shell;
an upper tube plate and a lower tube plate disposed on an upper end side and a lower end side of the shell, respectively;
a plurality of tubes installed between the upper tube plate and the lower tube plate;
a top cover disposed on the upper side of the upper tube plate wherein the gas supply nozzle is provided in the top cover;
a bottom cover disposed on the lower side of the lower tube plate;
and
a takeout port provided in the bottom of the bottom cover for removing the condensed liquid;

ii) the heat exchanger comprises jet nozzles for supplying the atomized droplets between the gas supply port and the upper tube plate;
iii) five or more jet nozzles are provided per 1.00 m 2 of a surface area of the upper tube plate; and
iv) the jet nozzles include at least one nozzle that is inclined toward the gas supply nozzle from the horizontal direction.

12. The method according to claim 11 , wherein the jet nozzles also include at least one radially obliquely upward nozzle, in which radially obliquely upward is relative to an axis of the upper tube plate.

13. The method according to claim 11 , wherein the jet nozzles include at least one vertically downward central nozzle and at least one radially obliquely downward nozzle, in which vertically downward and radially obliquely downward are relative to an axis of the upper tube plate.

14. The apparatus according to claim 11 , wherein the jet nozzles protrude from the top cover of the heat exchanger.

15. An apparatus, comprising:
an oligomerization reactor in which a catalyst and at least one α-olefin are supplied to oligomerize the α-olefin wherein the oligomerization reactor comprises a gas phase and a liquid phase;
a piping connected to the gas phase of the reactor on one end;
a shell and tube heat exchanger comprising a gas supply nozzle that is connected to the other end of the piping wherein a gas withdrawn from the gas phase from the reactor is cooled in the shell and tube heat exchanger to obtain a condensed liquid; and
a takeout port piping connecting the heat exchanger and the reactor for recycling of the condensed liquid into the oligomerization reactor,
wherein:
i) the heat exchanger further comprises:
a cylindrical shell;
an upper tube plate and a lower tube plate disposed on an upper end side and a lower end side of the shell, respectively;
a plurality of tubes installed between the upper tube plate and the lower tube plate;
a top cover disposed on the upper side of the upper tube plate wherein the gas supply nozzle is provided in the top cover; and
a bottom cover disposed on the lower side of the lower tube plate wherein the takeout port is provided in the bottom of the bottom cover;

ii) the gas supply nozzle is adapted to function such that the gas is introduced into the heat exchanger at a density of 20 kg/m 3 or more and at a gas flow rate of 1 m/s or more;
iii) the top cover further comprises jet nozzles for supplying atomized droplets onto the surface of the upper tube plate;
iv) five or more of the jet nozzles are provided per 1.00 m 2 of an area of the upper tube plate; and
v) the jet nozzles include at least one nozzle that is inclined toward the gas supply nozzle from the horizontal direction.

16. The apparatus according to claim 15 , wherein the jet nozzles comprise a spray nozzle.

17. The apparatus according to claim 15 , wherein:
the jet nozzles protrude from the top cover; and
a direction of the atomized droplets supplied from the jet nozzles is inclined relative to a direction of the gas introduced from the gas supply nozzle from the horizontal direction.

18. The apparatus according to claim 15 , wherein the jet nozzles comprise a full cone s

Assignees

• Mitsubishi Chem Corp

Inventors

• Emoto Hiroki

Classifications

• F28G9/00

  Cleaning by flushing or washing, e.g. with chemical solvents (appliances using jets of fluid for removing debris F28G1/16, F28G3/16) · CPC title

• F28G1/16

  using jets of fluid for removing debris (F28G1/12 takes precedence) · CPC title

• F28F9/027

  in the form of distribution pipes · CPC title

• F28F9/0265

  by using guiding means or impingement means inside the header box · CPC title

• F28D2021/0063

  Condensers · CPC title