Two-component mortar mass and use thereof

Patent metadata

Field	Value
Publication number	US-10501372-B2
Application number	US-201515323318-A
Country	US
Kind code	B2
Filing date	Jul 30, 2015
Priority date	Jul 31, 2014
Publication date	Dec 10, 2019
Grant date	Dec 10, 2019

Abstract

A two-component mortar mass comprises a resin component (A), which contains at least one radically curable resin as a curable constituent, and a curing component (B), which contains a curing agent for the radically curable resin of the resin component (A). The radically curable resin can be obtained by reaction of an at least difunctional isocyanate with a hydroxy-functional silane and a hydroxy-functional, ethylenically unsaturated compound. The hydroxy-functional silane is the reaction product of a cyclic compound from the group of cyclic carbonates, lactones, and carbamates with a silane compound selected from the group of amino-functional, hydroxy-functional or mercapto-functional silanes.

First claim

The invention claimed is:

1. A two-component mortar mass, comprising:
a resin component (A), which contains at least one radically curable resin as a curable constituent; and
a curing component (B), which contains a curing agent for the radically curable resin of the resin component (A);
wherein the radically curable resin is obtained by reaction of
an at least difunctional component, which has two or more reactive groups (RG-A),
with a silane intermediate compound and
an ethylenically unsaturated compound,

wherein the silane intermediate compound and the ethylenically unsaturated compound each have active functional groups (AG) that react with the reactive groups (RG-A), causing the formation of a covalent bond,
wherein the silane intermediate compound is the reaction product of a cyclic organic compound selected from the group consisting of a cyclic anhydride, a cyclic carbonate, a cyclic thiocarbonate, a cyclic carbamate, a cyclic thiocarbamate, a cyclic urea, a lactone, a lactam and combinations thereof with a functionalized silane compound, which has at least one reactive group (RG-B),
wherein the cyclic organic compound reacts with the reactive group (RG-B) of the functionalized silane compound, causing the formation of the silane intermediate compound having at least one functional active group selected from the group consisting of a carboxyl group, a hydroxy group and an amino group, and
wherein the silane intermediate compound is reacted in a proportion of at least about 2 wt. % of the resin component (A), with reference to organic constituents of the resin component (A).

2. The two-component mortar mass according to claim 1 , wherein the reactive groups (RG-A) are present at most in a stoichiometric ratio relative to the active groups (AG).

3. The two-component mortar mass according to claim 1 , wherein the reactive groups (RG-A) are selected from the group consisting of carboxyl groups, isocyanate groups, oxirane groups, imido groups and combinations thereof.

4. The two-component mortar mass according to claim 1 wherein the active groups (AG) are selected from the group consisting of carboxyl groups, hydroxy groups, amino groups, thio groups and combinations thereof.

5. The two-component mortar mass according to claim 1 , wherein the functionalized silane compound is a hydroxy silane, mercapto silane, an aminosilane or a mixture thereof.

6. The two-component mortar mass according to claim 1 , wherein the functionalized silane compound carries a Si-bound hydrolyzable group.

7. The two-component mortar mass according to claim 1 , comprising:
the resin component (A), which contains at least one radically curable resin as the curable constituent; and
the curing component (B), which contains a curing agent for the radically curable resin of the resin component (A);
wherein the radically curable resin is obtained by reaction of an at least difunctional isocyanate with a hydroxy-functional silane and a hydroxy-functional, ethylenically unsaturated compound,
wherein the hydroxy-functional silane is the reaction product of at least one cyclic compound selected from the group consisting of cyclic carbonates, lactones, and carbamates, with at least one silane compound selected from the group consisting of amino-functional, hydroxy-functional and mercapto-functional silanes, and
wherein the proportion of the hydroxy-functional silane compound reacted in the resin component (A) amounts to at least 2 wt. %, with reference to the total weight of organic constituents of the resin component (A).

8. The two-component mortar mass according to claim 7 , wherein the at least difunctional isocyanate reacted is selected from the group consisting of aliphatic and aromatic isocyanates, isocyanate prepolymers and mixtures thereof.

9. The two-component mortar mass according to claim 7 , wherein the hydroxy-functional, ethylenically unsaturated compound reacted is a (meth)acrylic acid ester, containing hydroxyl groups, of two or more multivalent alcohols.

10. The two-component mortar mass according to claim 7 , wherein the cyclic compound is reacted with an amino-functional silane compound that contains a primary or secondary amino group.

11. The two-component mortar mass according to claim 7 , wherein the cyclic compound is a cyclic carbonate.

12. The two-component mortar mass according to claim 7 , wherein the hydroxy-functional silane corresponds to the following Formula (I):

in which m is 0, 1 or 2,
R 1 is an alkyl radical with 1 to 4 carbon atoms,
R 2 is an alkyl radical with 1 to 4 carbon atoms,
R 3 is a divalent organic radical with 1 to 10 atoms, selected from C, N, S and/or O in the chain,
X means O, NR 4 or S,
wherein R 4 is a hydrogen atom or an alkyl radical with 1 to 10 carbon atoms, and
R is a difunctional organic group.

13. The two-component mortar mass according to claim 12 , wherein R 3 possesses a meaning indicated in the following Formula (II):

in which n is a whole number between 1 and 6,
Q stands for a covalent bond, 0 or NR 4 , and
R 4 and R 5 , independently of one another, are a hydrogen atom or an alkyl radical with 1 to 10 carbon atoms.

14. The two-component mortar mass according to claim 7 , wherein the molar ratio of the isocyanate groups to the hydroxy groups of the hydroxy-functional silane is in the range of 23:1 to 3.5:1.

15. The two-component mortar mass according to claim 7 , wherein the proportion of the hydroxy-functional silane compound reacted in the resin component (A) amounts to 2 to 7 wt. %, with reference to a total weight of the organic constituents of the resin component (A).

16. The two-component mortar mass according to claim 1 , wherein the radically curable resin is obtained by reaction of an at least difunctional epoxy with the silane intermediate compound and a carboxy-functional ethylenically unsaturated compound.

17. The two-component mortar mass according to claim 1 , wherein the resin component (A) contains at least one reactive diluent as a further constituent.

18. The two-component mortar mass according to claim 1 , wherein the resin component (A) contains at least one accelerator as a further constituent.

19. The two-component mortar mass according to claim 1 , wherein the resin component (A) and/or the curing component (B) contains at least one inorganic filler as a further constituent.

20. The two-component mortar mass according to claim 1 , wherein the resin component (A) contains a hydraulically binding or polycondensable inorganic compound as a further constituent.

21. The two-component mortar mass according to claim 1 , wherein the curing component (B) contains at least one organic peroxide as a curing agent.

22. The two-component mortar mass according claim 1 wherein at least one component of said two-component mortar mass is located in at least one of a shell, a cartridge or a film bag, wherein the resin component (A) and the curing component (B) are disposed in chambers separated from one another.

23. A method for fastening a part, said method comprising:
chemically fastening of said part in a drilled hole which is present in a mineral substrate with the two-component mortar mass according

Assignees

• Hilti Ag

Inventors

• Sharmak Anna
• Pfeil Armin
• Gnass Beate
• Kumru Memet-Emin
• Bunzen Jens

Classifications

• E21D20/02

  with provisions for grouting · CPC title

• E21D9/04

  Driving tunnels or galleries through loose materials; Apparatus therefor not otherwise provided for {(E21D9/005, E21D9/06 take precedence; soil improvement E21D9/001; provisional protective covers E21D19/04)} · CPC title

• C04B28/06 Primary

  Aluminous cements (monolithic refractories or refractory mortars C04B35/66) · CPC title

• C04B28/02

  containing hydraulic cements other than calcium sulfates · CPC title

• C04B26/16

  Polyurethanes · CPC title