High aspect ratio nanoscale multifunctional materials

Patent metadata

Field	Value
Publication number	US-10501317-B2
Application number	US-201113065540-A
Country	US
Kind code	B2
Filing date	Mar 24, 2011
Priority date	Mar 24, 2011
Publication date	Dec 10, 2019
Grant date	Dec 10, 2019

Abstract

The present invention discloses high aspect ratio multifunctional nanocomposite of CNF/polymer comprising of functionalized CNF incorporated with metal nanoparticles and phosphoric acid doped polybenzimidazole (PBI) along the inner and outer surfaces of hollow carbon nanofiber and to a process for fabrication of the same thereof.

First claim

We claim:

1. A high aspect ratio multifunctional material comprising functionalized hollow carbon nanofibers (CNF) coated with metal nanoparticles in phosphoric acid doped polybenzimidazole (PBI) along the inner and outer surfaces of the hollow carbon nanofibers;
wherein the metal nanoparticles have a size of 3-4 nm.

2. The material as claimed in claim 1 wherein said carbon nanofibers are 80-120 nm in diameter and 5-10 micrometers in length.

3. The material as claimed in claim 2 wherein said carbon nanofibers are 100 nm in diameter.

4. The material as claimed in claim 1 wherein said carbon nanofibers are of high aspect ratio of greater than 10.

5. The material as claimed in claim 4 wherein said carbon nanofibers are of high aspect ratio of 10-15.

6. The material as claimed in claim 1 , wherein the phosphoric acid doped PBI has inherent viscosity in the range of 0.1-0.5 dLg −1 .

7. The material as claimed in claim 1 , wherein the metal nanoparticles is loaded in the range of 2-60 weight %.

8. A process for the fabrication of the high aspect ratio multifunctional material as claimed in claim 1 , wherein the said process comprising the steps of;
a) preparing phosphoric acid doped polybenzimidazole polymer by a solution polycondensation method;
b) dispersing Pt or Rh nanoparticles into the tubular region of carbon nanofibers by a simultaneous dispersion and reduction through polyol process;
c) encapsulating the phosphoric acid doped PBI in a solvent as obtained in step (a) with metal dispersed carbon nanofibers as obtained in step (b) to obtain high aspect ratio multifunctional material.

9. The process as claimed in claim 8 , wherein phosphoric acid doped PBI and the metal nanoparticles are incorporated on both the inner and outer walls of carbon nanofibers by a process based on the wetting and capillary action of solvent medium.

10. The process as claimed in claim 8 , wherein step (a) or (c) uses a dipolar aprotic solvent.

11. The process as claimed in claim 10 , wherein the dipolar aprotic solvent is selected from the group consisting of acetone, methyl ethyl ketone, ethylacetate and N,N dimethyl acetamide (DMAc).

12. An article comprising the high aspect ratio multifunctional material according to any of claims 1 - 7 , wherein the article is a fuel cell, a solar cell, a supercapacitor, a sensor, or a drug delivery system.

13. The material of claim 1 , wherein the metal nanoparticles is loaded in the range of 15-25 weight %.

14. The material as claimed in claim 1 , wherein the metal nanoparticles is loaded in the range of 2-20 weight %.

15. The material of claim 1 , wherein the phosphoric acid doped PBI has inherent viscosity in the range of 0.47-0.5 dLg −1 .

Assignees

• Kurungot Sreekumar
• Balan Beena Kalasaparambil
• Kharul Ulhas Kanhaiyalal
• Pillai Vijayamohanan Kunjuukrishna
• Council Scient Ind Res

Inventors

• Kurungot Sreekumar
• Balan Beena Kalasaparambil
• Kharul Ulhas Kanhaiyalal
• Pillai Vijayamohanan Kunjuukrishna

Classifications

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• H01M4/96 Primary

  Carbon-based electrodes · CPC title

• B82Y30/00 Primary

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• Y02E60/50

  Fuel cells · CPC title